简介：HighresolutionmassspectrometryincombinationwithdistillationandSARAfractionationprovidesusanopportunityforin-depthunderstandingaboutthehydrotreatingprocessatthemolecularlevel.Inthisstudy,theatmosphericresiduederivedfromArabianheavycrudeanditshydrotreatedproductswereinitiallysubjectedtodistillationandSARAfractionation.ThesaturateswerecharacterizedbyGCFI/FDTOFMS.ThearomaticsandresinswerecharacterizedbyAPPIFT-ICRMS.Compositionalchangesofdifferentcompounds(paraffins,naphthenes,aromatichydrocarbons,andheteroatomiccompounds)containedindifferentdistillates(vacuumgasoil,vacuumresidue)wereobtained.Moredetailedknowledgeaboutthehydrotreatingprocesswasachieved.

简介：采用GC／MS法测定作为化工原料的石脑油中含量小于0．1％的MTBE，将汽油直接进样，简便快速，方法具有很高的选择性和准确性，检测灵敏度高，测定结果令人满意。

简介：随着我国汽车发动机向轻、微型、高转速和大功率的发展，对内燃机油的质量要求越来越高。为配合我国高档内燃机油的研究与开发及我们研发中心MS程序ⅢE台架的引进，降低试验费用，缩短开发周期，提高台架试验的通过率，我们在四球摩擦磨损试验机上研究和建立了一种试验方法，它能够较好的区分不同质量级别的汽油机油，在高档汽油机油研究中得到了应用。

简介：MS程序VE是评定汽油机油在低温、轻负荷条件下的油泥生成性能台架，其油泥的形成主要基于硝化反应，且与发动机运转条件有关。

简介：三维定量荧光分析在区分真假油气显示、识别井内污染、随钻检测地层含烃量变化、判断含油性质方面具有良好的应用效果。由于该技术中判断油质的关键参数——油性指数依然沿用二维算法,并不能真正反映前后主次峰的峰高变化。通过对三维定量荧光分析中波长的研究,建立了一项新的参数——MS指数,应用该参数评价显示层的原油性质效果显著,并以MS指数建立新的解释评价图板,该图板在华北油田冀中勘探重点区带取得了较好的应用成效。现场应用结果表明,MS指数的建立弥补了现有三维定量荧光技术对油质判断的局限性,新方法科学、准确,是对现有三维定量荧光技术应用的完善和补充。

简介：ThemoleculartransformationsofcarboxylicacidsinheavyacidicSLcrudebeforeandaftertrueboilingpointdistillationwereexaminedbyultra-highresolutionnegative-ionelectrosprayionization(ESI)Fouriertransformioncyclotronresonancemassspectrometry(FT-ICRMS).Theacidclass(heteroatomnumber),type(znumbers)andcarbonnumberdistributionswerepositivelycharacterized.Itwasfoundoutthatthetotalacidnumber(TAN)ofSLcrudedecreasedaftertrueboilingpointdistillation,andtheabundanceofO2classinmassspectrawasalsofoundtobereducedfrom67.6%to34.5%inSLTBPmixedcrudeasmeasuredbyMSspectra,indicatingtoapotentialcarboxylicaciddecomposition.However,itwasinterestingthatthecarboxylicacidstypedistributioninbothoilswasalmostthesamealthoughtheirrelativeabundanceinSLTBPmixedcrudeturnedtobemuchlower,suggestingthatvariouspetroleumcarboxylicacidtypeshavethesimilarthermaldecompositionreactionbehavior.Furthermore,foreachO2typeofacidsinSLTBPmixedcrude,theabundanceofcarboxylicacidswithcarbonnumberhigherthan35wasreducedgreatly,especiallyforthosewithcarbonnumberhigherthan60,themasspeaksofwhichwerenearlytotallyremoved,indicatingthatthelargecarboxylicacidmoleculesinheavyfractionsdecomposedmoresignificantlybecauseoflongerheatingtimeduringthetrueboilingpointdistillationprocess.Asaresult,thereductionofTANmaybecausedbythethermaldecompositionofcarboxylicacidsespeciallythosewithhighcarbonnumber,suggestingthatquickdistillationormuchlowerpressureisrequiredtoavoidthethermaldecomposition.