简介:MgO-ZrO2unfiredbrickswithZrO2contentupto8%attheintervalof2%wereprepared,usingfusedmagnesia(MgO:97%)andfusedMgO-ZrO2clinker(ZrO2:14.33%)asstartingmaterialsandphenolicresinasbinder.TheeffectsofZrO2contentonthermalshockresistance(TSR)andotherpropertiessuchascoldandhotmodulusofrupturehavebeeninvestigated.Residualcoldmodulusofruptureratioafterheatingat1000℃andquenchingbyairblowingwasadoptedtocharacterizeTSR.AdditionoftheMgO-ZrO2clinkerimprovesTSR,attributingtothemicrocracktougheningeffectbythermalexpansionmismatchbetweendifferentphases.WhenZrO2contentgoesabove4%,theimprovingeffecttendstobemoderate.TheintroductionofMgO-ZrO2clinkercanalsoimprovetheHMORat1500℃,whiletheincreasedZrO2contentreducesCMORofthebricksprefiredat1600℃,duetothethermalexpansionmismatcheffect.Compromisingtheoverallproperties,theoptimalZrO2contentforsuchmagnesiabasedunfiredbrickissuggestedtobe4%.
简介:Thisworkinvestigatedthethermo-gravimetric(TG)changeandexplosionresistanceofultra-lowcementAl2O3-SiO2castablesaddedwith0,5%,10%,15%and20%of≤74μmrawbauxitepowderscontaining72.8%Al2O3,respectively.Thecastableswerepreparedusingwhitefusedaluminaasaggregate,powdersofwhitefusedalumina,fusedmullite,α-Al2O3ultrafines,3%CAcementand5%microsilicaasthematrixportion.TGchangeofthecastableswasinvestigatedbyathermo-gravimetricanalyzerforlargesizespecimen.Whentherawbauxiteadditionislessthan10%,themass-losingbehaviorofthecastablesissimilartothatwithoutrawbauxite,tendingtoreachaconstantmassaround400℃,beforewhichthemass-lossismildandproducinglittledestructiveinfluence.Withmorethan10%rawbauxiteaddition,however,themass-lossincreasessignificantly,andthetemperaturetoreachaconstantmassincreasesto600℃orhigher,unfavorabletostructuralstabilization.Withtherawbauxiteadditionupto20%,nonegativeinfluenceonexplosionresistanceisfound.
简介:中国化工学会涂料涂装专业委员会、全国涂料工业信息中心、涂料行业生产力促进中心联合《涂料工业》杂志将于2019年4月16-19在常州举办第17届环保型车用涂料与涂装技术研讨会,将以“环保、责任、创新、成长”为主题,解决行业疑问,推动产业发展。现向行业征集优秀论文,征文主要内容涉及:1、绿色车用涂料及其原料:1)水性、粉末、高固体分汽车涂料的技术进展,2)在工程机械、轨道交通上应用的环保涂料技术进展,3)电泳漆技术进展和市场应用状况,4)汽车、工程机械和轨道交通零部件用漆的技术进展,5)环保修补漆技术进展,6)环保型树脂、助剂、颜填料等在车用涂料中的应用,7)车用涂料流行色趋势及配色、调色、测色系统。2、涂装工艺的节能环保:1)环保前处理技术(氧化锆和硅烷)进展和应用,2)环保汽车涂装线改造及应用,3)轨道车辆、商用车和工程机械等涂装工艺进展,3)轻量化涂装,4)环保节能的涂装设备,5)新能源涂装,6)废水、废气、废渣处理技术。3、行业状况及相关标准解读:1)绿色涂料产品认证,2)废气废水废渣排污收费最新动态,3)车用涂料与涂装相关法规解读。
简介:SlagcorrosionresistanceofMgOZrO2refractorieswasinvestigatedinthiswork.Theresultsindicatethatinanon-orientedelectricsteelslagsystemwithahighratioofcalciatosilica,theslagresistanceofMgOZrO2refractoriescanbedescribedasfollows:ZrO2reactswithCaOformingcalciumzirconatecompoundwhichstrengthensthematerialandblocksthechanneloftheslaginfiltration;however,inanorientedelectricsteelslagsystemwithahighconcentrationofsilicaandthelowratioofcalciatosilica,theslagcorrosionresistanceofMgOZrO2refractoriesisdifferent;ZrO2reactswithCaOformingthecalciumzirconateandsimultaneouslyonemoreproductC2Saswell;C2Scanimprovecorrosionresistancebyblindingporeandenhancingslagviscosity;therefore,itisexpectedtobethemajorreasonfortheenhancedcorrosionresistanceobservedforMgOZrO2refractories.
简介:通过介绍全球及我国近年来CO2的排放状况,首先指出了CO2回收的迫切性及资源化利用的优势,并以CCS(碳捕集与封存)和CCU(碳捕集与利用)为例,分别介绍了诸如地质封存、海洋封存、化学转化和生物转化等规模化回收利用技术,阐述了这些技术的回收原理、工艺路线、安全环保性、技术优势和工业化案例。通过分析CCS各技术的封存能力、封存效果、技术瓶颈及其工业化推广的进度和潜力,指出CCS技术的全球化应用目前还存在一定的风险和制约:通过对比CCU各技术研究重点、转化瓶颈以及工业化进度等,指出化学转化法是目前最有效的CO2规模化回收利用技术:还介绍了其它几种具有规模化潜力的CO2利用新技术。