简介:TheeffectsoftheintroductionofCetoLa_(1-x)Ce_xFe_(11.5)Si_(1.5)alloyson1:13phaseformationmechanism,thefirst-ordermagneticphasetransitionstrengtheningcharacteristics,andmagnetocaloricpropertywerestudied,respectively.Theresultsshowthattheformationmechanismsof1:13andLaFeSiphasesinLa_(1-x)Ce_xFe_(11.5)Si_(1.5)alloysarethesameasthoseofCe_2Fe_(17)andCeFe_2phasesinCe–Febinarysystem,respectively.ThesubstitutionofCein1:13phasewhichislimitedcanmakethefirst-ordermagneticphasetransitioncharacteristicsstrengthen,whichcanmakethermalandmagnetichysteresisincrease,thetemperatureintervaloftemperatureinducedphasetransitiondecrease,andthecriticalmagneticfieldoffield-inducedmagneticphasetransition(HC)increase,respectively.Owingtothelatticeshrinkof1:13phasewiththeincreaseinCecontent,theCurietemperatures(TC)showalineardecrease.Themaximumchangeinmagneticentropygraduallyincreasesduetothedecreaseintemperatureintervaloftemperature-inducedphasetransition,buttherelativecoolingcapacitiesareallabout80Jákg-1atmagneticfieldof2T.
简介:NanostructuredandconventionalAl2O3-13wt%TiO2coatingsweremanufacturedbyairplasmaspray.FrictionandwearbehaviorsofcoatingswereinvestigatedatroomandelevatedtemperaturesusinganSRVweartestmachine.Thenanostructuredcoatinghas"tworegions"microstructure,whiletheconventionalcoatinghastypicallayeredmicrostructurewithobviousinterfacesamongsplats.Thecoefficientoffrictiondecreaseswithrisingoftemperaturebecauseoftheformationoftribo-layeratelevatedtemperatures.Thewearresistanceofthenanostructuredcoatingsishigherthanthatoftheconventionalcoating,andthewearthresholdofappliedloadis30Nforconventionalcoatingand40Nfornanostructurecoating.Thewearresistancedifferenceisrelatedtothe"tworegions"microstructureofnanostructurecoating,whichcouldbluntorbranchthecrackspropagation.Inourtestranges,thewearratesrisingaremoresensitivewiththeappliedwearloadrisingthanwiththetemperaturerising.
简介:为了对高合金异种钢焊接工艺有更多的了解,本文通过对某火力电厂锅炉后屏过热器检修换管过程中涉及到的钢种(SA213-T91马氏体高合金耐热钢与Cr25Ni13奥氏体高合金耐热钢)的现场焊接工艺进行介绍,以给类似工程的施工提供一定的借鉴。
简介:利用高频辅助激光熔覆技术在镍基合金上制备Al2O3-13%TiO2(质量分数)陶瓷涂层。采用SEM、XRD和EDS等方法分析陶瓷涂层的微观结构和陶瓷层与粘结层之间的结合界面。结果表明:陶瓷层出现了完全熔化区和液相烧结区双层结构,其中,完全熔化区颗粒充分烧结长大,而液相烧结区则出现了三维网状结构,该三维网状结构由熔化的TiO2相包裹Al2O3颗粒形成。通过激光熔覆作用下的粉末熔化和扁平化行为解释双层结构形成机理。同时,在陶瓷层与粘结层的结合界面上发现具有尖晶石结构的NiAl2O4和针状结构的Cr2O3,证明在激光熔覆过程中发生的化学反应可以有效增加陶瓷层与粘结层的结合强度。