简介:Thehydrolysisreactionof(±)-2-acetamido-3-hydroxy-1-(4-nitrophenyl)-1-propanone[(±)-1],anintermediateofchloramphenicol,wasstudiedandthreedifferentproductswereobtainedrespectivelyunderdifferentreactionconditions.Theresolutionofhydrolysisproduct(±)-2-amino-3-hydroxy-1-(4-nitrophenyl)-1-propanone[(±)-3]wascarriedout.Aprocessofcrystallization-inducedasymmetrictransformationwasobservedandupto76%oftheopticallypureenantiomerwasobtainedintheresolutionof(±)-3.
简介:Therelativisticproblemofspin-1/2fermionssubjecttovectorhyperbolic(kink-like)potential(~tanhkx)isinvestigatedbyusingtheparametricNikiforov-Uvarovmethod.TheenergyeigenvalueequationandthecorrespondingnormalizedwavefunctionsareobtainedintermsoftheJacobipolynomialsintwocases.
简介:以“闪光二号”加速器硬X射线为辐照源,对腔体内系统电磁脉冲(systemgeneratedelectromagneticpulse,SGEMP)磁场环境的验证方法进行了研究。根据测量的“闪光二号”二极管的电压、电流,模拟了发射电子束能谱参数;结合辐射靶物理设计,建立了二极管阳极靶蒙特卡罗粒子输运计算模型,模拟了轫致辐射X射线场参数;采用时域有限差分(finitedifferencetimedomainmethod,FDTD)和粒子模拟(particleincell,PIC)方法,模拟了该射线环境中的腔体SGEMP磁场环境;将轫致辐射X射线参数及腔体SGEMP磁场环境的模拟结果与实验结果进行了比较。结果表明:从X射线源参数模拟开始的腔体内SGEMP数值模拟计算模型的实验验证方法是合理可行的。
简介:针对嫦娥三号软着陆轨道设计与控制策略问题,在合理假设的前提下,建立动力学模型,求解得到了嫦娥三号着陆准备轨道近月点和远月点的速度。针对软着陆过程的6个阶段,通过受力分析,建立了嫦娥三号运动的微分方程模型,以燃料消耗最小为优化目标,以每个阶段的起止状态为约束条件,将软着陆轨道的优化设计问题转化为主发动机推力的泛函极值问题,并将其控制函数转化为近似的多项式函数优化问题。运用四阶Runge-Kutta差分迭代方法进行求解计算,从而得到各个阶段的最优控制函数和控制策略。结果表明,嫦娥三号软着陆过程耗时695s,消耗燃料1269.1kg。
简介:ThispapershowsthatforΩ∈H1(Sn-1),MarcinkiewiczintegraloperatorμΩisLp(Rn)boundedfor1<p<∞,whichimprovessomeknownresults.
简介:Onassumingthatweaksubstructurehasadynamicswhichissimilartoquantumchromodynamicsbutmuchstronger,weconcludethatunquenchingisindispensableforpredictionsonthespectrumofweak-substructureresonances[1].
简介:1-Ethoxycarbonylalkyldiphenylpolystyrylphosphoniumtriflatescanbeeasilypreparedbyquaternizingdiphenylpolystyrylphosphinewithethyl2-trifloxyalkanoates;basetreatmentofthesepolymer-supportedphosphoniumtriflatesaffords1-ethoxycarbonylalkylidenephosphoraneswhicharestableandundergosatisfactoryWittigreactions.
简介:为第二使用订Dini上面的方向性的衍生物的LC非强迫的优化问题介绍二个算法。方法的简洁使用并且表现;重复功能的相关性质的讨论。
简介:1.IntroductionLetRbethecollectionofallrealnumbers,andZthecollectionofallintegers.Iff1(x)andf2(x)aretwofunctionsinL2(R),theinnerproduct
简介:InthispaperitturnsoutthataBanachlatticeXisorderisomorphictol~1(Γ)forsomenonemptysetΓiffitisaSchurspaceandalltheinfinitelydimensional,separableandclosedidealsofXareorderisomorphic.
简介:WeuseamodifiedBecke-JohnsonexchangeplusalocaldensityapproximationcorrelationpotentialwithinthedensityfunctionaltheorytoinvestigatetheelectronicstructuresofHg1-xCdxTeandIn1-xGaxAswithxbeing0,0.25,0.5,0.75,and1.Forbothofthetwoseries,ourcalculatedenergygapsanddielectricfunctions(realpartε1andimaginarypartε2)areinagreementwiththecorrespondingexperimentalresultswithxbeingbetween0and1.Thecalculatedzero-frequencyrefractiveindexvariesgreatlywithxforHg1-xCdxTe,butchangeslittlewithxforIn1-xGaxAs,whichisconsistentwiththerealpartsoftheirdielectricfunctions.Therefore,thisnewapproachissatisfactorytodescribetheelectronicstructuresandtheopticalpropertiesofthesemiconductors.
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简介:New[1+1]and62-membered[2+2]Schiffbasemacrocyclescontaininga2,6-diamidopyridinesubunithavebeensynthesizedbycondensationreactionoftheprecursorspyridine-2,6-dicarboxamideand1,10-bis(20-formylphenyloxy)decaneinthepresenceofphosphoricacidviaaone-potprocess.Thecyclocondensedproductswereeffectivelyisolatedbygelcolumnchromatographyandcharacterizedby~1HNMR,FTIR,massspectrometryandX-rayanalysis.Thetwomacrocycleshaveatwistedstructure,andnotanopen‘circular’conformationinthesolidstate.
简介:The1,1'-binaphtholbasedoligomers3and7with3,3'-acetylene-phenylene-acetylenespacerwerepreparedfromBINOL1.ThehighopticalrotationvalueandCDspectrademonstratedthemainchainchiralityoftheoligomermolecule.TheUV-VISandfluorescentspectraevidencethecharacteristicsofconjugatedstructure.Incomparisonwitholigomer2bearing3,3'-acetylenespacer,theoligomers3and7havelongerefficientconjugationsegment,andtheirfluorescentquantumyields(φ)increased(0.60-0.65versus0.14).Extendingtheeffectiveconjugationsegmentwouldimprovethephotophysicalpropertiesofchiralconjugatedpolymers.``