简介:Theeffectofpromotercobaltandthesequencesofaddingcobaltandmolybdenumprecursorsontheperformanceofsulfur-resistantmethanationwereinvestigated.AllthesesampleswerepreparedbyimpregnationmethodandcharacterizedbyN2-adsorption,X-raydiffraction(XRD),temperature-programmedreduction(TPR)andlaserRamanspectroscopy(LRS).TheconversionsofCOforMo-Co/Al,Co-Mo/AlandCoMo/Alcatalystswere59.7%,54.3%and53.9%,respectively.Amongthesecatalysts,theMo-Co/AlcatalystpreparedstepwiselybyimpregnatingMoprecursorfirstlyshowedthebestcatalyticperformance.Meanwhile,theconversionsofCOwere48.9%forMo/Alcatalystand10.5%forCo/Alcatalyst.TheadditionofcobaltspeciescouldimprovethecatalyticactivityofMo/Alcatalyst.TheN2-adsorptionresultsshowedthatCo-Mo/Alcatalysthadthesmallestspecificsurfaceareaamongthesecatalysts.CoMoO4speciesinCoMo/AlcatalystweredetectedwithXRD,TPRandLRS.Moreover,crystalMoS2whichwasreportedtobelessactivethanamorphousMoS2wasfoundinbothCo-Mo/AlandCoMo/Alcatalysts.Mo-Co/Alcatalystshowedthebestcatalyticperformanceasithadanappropriatesurfacestructure,i.e.,nocrystalMoS2andverylittleCoMoO4species.
简介:Inthispaper,wepresenttheluminescentpropertiesofTm3+∕Ho3+co-dopednewglass.Aseriesofsilicategermanateglasswaspreparedbytheconventionalmelt-quenchingmethod.IntheTm3+∕Ho3+co-dopedsilicategermanateglass,astrongemissionof2μmoriginatingfromtheHo3+:5I7→5I8transitioncanbeobservedunderconventional808nmpumping.Thecharacteristictemperatures,structure,andabsorptionspectrahavebeenmeasured.TheradiativepropertiesofHo3+inthepreparedglasswerecalculated.TheemissioncrosssectionofHo3+ionstransitioncanreach4.78×10-21cm2around2μm,andtheFWHMisashighas153nm.TheenergytransferefficiencybetweenHo3+andTm3+hasalargevalue(52%),whichindicatestheTm3+∕Ho3+co-dopedsilicategermanateglassisasuitablecandidateforthe2μmlaser.Moreover,theenergytransfermechanismbetweenTm3+andHo3+ionswasinvestigated.
简介:WeproposeanddemonstrateawidelytunablepassivelyQ-switchedHo^3+∕Pr^3+-codopedZrF4-BaF2-LaF3-AlF3-NaFfiberlaseroperatinginthe2.8μmmid-infrared(MIR)wavebandbasedonasingle-walledcarbonnanotube(SWCNT)saturableabsorber(SA).TheSWCNTshavediametersrangingfrom1.4to1.7nm.ThemodulationdepthandsaturationintensityoftheSWCNTSAmeasuredat2850nmare16.5%and1.66MW∕cm^2,respectively.StableQ-switchedpulseswiththeshortestpulsedurationof1.46μsandthemaximumpulseenergyof0.43μJareachievedatalaunchedpumppowerof445.6mW.ThecombineduseofabroadbandSWCNTSAandaplaneruledgratingensuresabroadcontinuouslytuningrangeof55.0nmfrom2837.6to2892.6nm.Theoutputpowers,emissionspectra,repetitionrates,andpulsedurationsatdifferenttuningwavelengthsarealsocharacterizedandanalyzed.OurresultsindicatethatSWCNTscanbeexcellentbroadbandSAsinthe3μmMIRregion.Totheauthor’sknowledge,thisisthefirstdemonstrationofawidelytunablecarbon-nanotubeenabledpassivelyQ-switchedfiberlaseroperatinginthe2.8μmMIRwaveband.
简介:Inthepresentwork,theLEDchipwasirradiatedbyusing59.6MeVNionsinaterminalchamberoftheSector-focusedcyclotron(SFC)intheNationalLabortaryofHeavy-ionAcceleratorsinLanzhou.The63MeVNionspenetratedthroughagoldfoilandscatteredinalargearea.Theenergyofionwasreducedto59.6MeVafterscatteringofthegoldfoil.TheLEDwasprovidedbytheSemiconductorLightingCenterinInstituteofSemiconductorinBeijing.TheluminencesoftheLEDbefore/afterirradiationweretestedthroughaintegratingsphereinSemiconductorLightingCenterinInstituteofSemiconductorinBeijing.Theluminancewastestedunderacurrentof350mA.Fig.1showstherelationshipbetweentheluminencesandtheirradiationfluences.Theirradiationledto
简介:Grapheneanditsderivativeshaveattractedtremendousresearchinterestbecauseoftheiruniquecompositionandphysicochemicalproperties[1??3].However,thepotentialbiologicaltoxicityofGQDshasbecomeahealthriskbecauseoftheirinherentchemicalcompositionandnanoscaleproperties[4].Zebrafish(Daniorerio)isoneofthemostpromisinginvivomodelsystemsfortoxicitystudies[5].
简介:TheprogressofresearchgoingoninGroupofEnergyMaterials(GEM),MaterialResearchCenter,in2014isinthefollowingthreeaspects.1.FacilitydevelopmentInordertopushforwardourstudyonfusionreactormaterials,weupgradedtheirradiationterminal(128#)ofthesectorfocusedcyclotron(SFC)atHIRFL,bydevelopinganewspecimenstagespecificforirradiationwithlow-fluencescatteredions.Sofartheterminaliscapableofirradiationtobothverylowfluences(106ions/cm2)andveryhighfluences(typically1016ions/cm2)forvariousmaterials.SpecimentemperaturecanbereadilycontrolledusingtheL-N2coolingstageorthethehigh-Tstage(upto600oC).Ourrecentinvestigationwithtransmissionelectronmicroscopy(TEM)ofthedefectsproducedbyhigh-energyNeionsinsteelspecimensprovidesaclearevidencethatdefectswereproduceduniformlyalongthedepthinthespecimen,indicatingthattheenergydegraderoftheterminalworkseffectivelytodispersetheionenergyinawiderange.AphotooftheterminaltogetherwithaSRIMestimateofdepthprofilesofdamageinan8%Crreducedactivationferritic/martensiticsteel(RAFMS)isshowninFig.1.