简介:ThelocalstructuresoftheimmiscibleFe100-xCuxalloys(x=0,10,20,40,60,80and100)producedbymechanicalalloyinghavebeeninvestigatedbyXAFS.FortheFe100-xCux(x≥40)solidsolutions,thelocalstructuresaroundFeatomschangefrombccstructuretofcconeandtheCuatomsmaintaintheoriginalcoordinationgeometryaftermillingfor160hours.Onthecontrary,thelocalstructuresaroundCuatomsinbothofFe80Cu20andFe90Cu10alloysappearatransitionfromfcctobccstructure.WefoundthattheDebye-wallerfactorσoffccFe-CuphaseislargerthanthatofbccF-Cuphase,andtheσ(0.099A°)aroundFeatomsislargerthanthat(0.089A°)ofCuintheFe100-xCux(x≥40)solidsolutions,ThissuggeststhatthemechanicallyalloyedFe100-xCuxsupersaturatedsolidsolutionisnotahomogeneousalloy,andconsistsofFe-richandCu-richregionsforvariouscompositions.Apossiblemechanismforbcc-to-fccandfcc-to-bccchangesinFe100-xCuxsolidsolutionsisdiscussedinrelationtotheinterdiffusionandtransitioninducedbytheballmilling.
简介:Zr1-xTixCo(x=0,0.1,0.2,0.3)alloyswerepreparedbyarc-meltingmethodandtheeffectofTisubstitutiononhydrogenstoragepropertieswasstudiedsystematically.Hydrogendesorptionpressure-composition-temperature(PCT)measurementswerecarriedoutusingSievert’stypevolumetricapparatusforZrCo(at473K,573Kand673K)andZr1-xTixCoalloys(at673K),respectively.ProductsafterdehydrogenationwerecharacterizedbyX-raydiffraction(XRD).Inaddition,thekineticsofZr1-xTixCohydridewasinvestigatedat473Kand673K,respectively,underhydrogenpressureof5MPa.ResultsshowedthatTisubstitutionforZrdidnotchangethecrystalstructureofZrCophase.Withtheincreaseoftemperaturefrom473Kto673K,theextentofdisproportionationforZrCoalloyincreased.WithTicontentincreasingat673K,thedesorptionequilibriumpressureofZr1-xTixCo-H2systemselevatedandthedisproportionationreactionofZr1-xTixCoalloyswasinhibitedeffectively.TisubstitutiondecreasedthekineticsrateandtheeffectivehydrogenstoragecapacityofZr1-xTixCoalloysslightly.Generallyspeaking,itwasfoundthatZr0.8Ti0.2Coalloyhadbetteranti-disproportionationpropertywithlessdecreaseofeffectivehydrogenstoragecapacitywhichwasbeneficialtotritiumapplicationintheInternationalThermonuclearExperimentalReactor(ITER).
简介:Fe_(3–x)O_4raspberryshapednanostructures/graphenenanocompositesweresynthesizedbyaone-steppolyol-solvothermalmethodtobetestedaselectrodematerialsforLi-ionbattery(LIB).Indeed,Fe_(3–x)O_4raspberryshapednanostructuresconsistoforiginalorientedaggregatesofFe_(3–x)O_4magnetitenanocrystals,ensuringalowoxidationstateofmagnetiteandahollowandporousstructure,whichhasbeeneasilycombinedwithgraphenesheets.TheresultingnanocompositepowderdisplaysaveryhomogeneousspatialdistributionofFe_(3–x)O_4nanostructuresatthesurfaceofthegraphenesheets.TheseoriginalnanostructuresandtheirstronginteractionwiththegraphenesheetsresultedinverysmallcapacityfadinguponLi+ionintercalation.Reversiblecapacity,ashighas660mAh/g,makesthismaterialpromisingforanodeinLi-ionbatteriesapplication.
简介:WehavestudiedtheangularmagnetoresistanceofironpnictidesBaFe2-xNixAs2,whichshowsclear180degreeperiodicityasfittedbyacosinefunction.Inthex=0.065sample,thephaseofthetwo-foldsymmetrychanges90degreesabovethetetragonal-to-orthorhombicstructuraltransitiontemperatureTs.Sincethephaseatlowtemperatureisassociatedwiththerotationoforthorhombicdomainsbymagneticfield,weshowthatevenvacuumgreasecanpushthepresenceoforthorhombicdomainsattemperaturesmuchhigherthanTs.Ourresultssuggestthatresidualstressmayhavesignificanteffectsinstudyingthenematicordersanditsfluctuationsinironpnictides.
简介:WeinvestigateindetailtheeffectsofR-parityleptonnumberviolationonthedecay~↑b1→b~↑x1^0intheR-parityviolatingminimalsupersymmetricstandardmodel(Rp-MSSM)underthepresentexperimentalconstraintsonRpparameters.Inournumericalcalculationsweconsidertwocasesofinputparametersofthesquarkandsleptonsectors,MsquarkMslepton,forcomparison.TheresultsshowthattherelativeR-parityviolatingcorrectionisnotverysensitivetothemassofthelightestneutralino-0↑x1andthedegenerateR-parityviolatingcouplingparameterλ2′,butstronglydependsonMsquark,Mslepton,tanβandthedegenerateR-parityviolatingcouplingparameterλ1′.Therelativecorrectionisabout-4~3%andcanexceed-6%insomeregionofparameterspace.Therefore,preciseexperimentanalysesonthedecay~↑b1→b~↑x1^0mayprovideaprobeoftheR-parityviolation.
简介:TodepictthedetailsthatCHOP(C/EBPhomologousprotein)regulatesautophagyandapoptosisinbreastcancercells,theexpressionofCHOPwasinhibitedbytransfectionwithsiRNAsequence.AsshowninFig.1,radiati-Fig.1CHOPinhibitionbysiRNAatmRNAandproteinlevelsafterradiation.onelicitedahigherexpressionofCHOPintheNCgroupcomparedwithcontrol.However,thishigherexpressionwassignificantlyinhibitedinthesiRNAgroup.
简介:Twotransmissioncurvedcrystalspectrometersaredesignedtomeasurethehardx-rayemissioninthelaserfusionexperimentofComptonradiographyofimplosiontargetonShenGuang-IIIlaserfacilityinChina.Cylindricallycurvedα-quartz(10–11)crystalswithcurvatureradiiof150and300mmareusedtocoverspectralrangesof10–56and17–100keV,respectively.Thedistancebetweenthecrystalandthex-raysourcecanbechangedoverabroaddistancefrom200to1500mm.Theopticaldesign,includingtheintegralreflectivityofthecurvedcrystal,thesensitivity,andthespectralresolutionofthespectrometers,isdiscussed.WealsoprovidemechanicdesigndetailsandexperimentalresultsusingaMoanodex-raysource.High-qualityspectrawereobtained.Weconfirmedthatthespectralresolutioncanbeimprovedbyincreasingtheworkingdistance,whichisthedistancebetweentherecordingmediumandtheRowlandcircle.