简介:Twoalkylsubstitutedpolythiophenederivatives:poly(3-hexylthiophene)(P3HT)andpoly(3-decylthiophene)(P3DT),havesynthesizedbyoxidationcouplingpolymerizationof3-alkylthiopheneusingiron(III)chlorideascatalystinchloroform.Whilebothpolymersinpurechloroformsolutionhavemaximumabsorptionatapproximatelysamewavelengthof440nm,theybehavedifferentlywithrespecttochangesobservedontheirUV-visibleandphotoluminescencespectrawhenthequalityofthepoorsolventischangedingoodsolvent(chloroform)/poorsolvent(methanol)mixtures.Withincreasingvolumefractionofmethanolinmixtures,theabsorptionspectraofP3HTandP3DTred-shift,peakingatmaximumwavelengthof495nm(P3HT)and510nm(P3DT).Furthermore,theabsorptionspectraofthetwopolymersinchloroformblue-shiftasthetemperaturerises.P3HTshows4.73nmblue-shiftsat50℃incontrasttothecaseat20℃,whileP3DTblue-shiftsabout5.04nm.Thephotoluminescencespectraofthetwopolymersinmixedsolutionarealsoinvestigated,whichshowthattheluminescencespectrashifttolongerwavelengthwithanaccompanyingdropinthePLintensityasmethanolisincreased.Theabsorptionandemissionspectraofthetwopolymersinapoorsolventandathinfilmaresimilar,whichindicatethatasimilarlongerconjugationlengthinthetwocases.Itcouldconcludethatthepolymersexistalmostthesameconformationsandaggregationsinbothapoorsolventandathinfilm.P3DTexhibitsmoresensitivespectraproperties(bigred-shiftsinbothabsorptionandluminescencespectrainpoorsolventsandlargeblue-shiftsathightemperature)withcontrasttoP3HT,whichimplythatlongsidealkylmayimprovethechromicpropertiesofthepolymer.
简介:据外电报道,本周末,北方电讯(Nextel)发言人称该公司在FLASH-OFDM标准上进行的3G外场实验将于今年的6月30日结束。
简介:Inthiswork,Bi2Te3films(250nm)arefabricatedonSiO2/Sisubstratesbyradiofrequency(RF)magnetronsputteringatroomtemperature,andthepreparedfilmsareannealedoverthetemperaturerangeof200°Cto400°C.Crystallinityandelectricalpropertiesofthefilmscanbetunedcorrespondingly.ThepowerfactorsofBi2Te3filmsof0.85μW/K2cmto11.43μW/K2cmwereachievedafterannealing.Theinfraredreflectancemeasurementsfrom2.5μmto5.0μmdemonstratethatthereisalsoaslightred-shiftoftheplasmaoscillationfrequencyintheBi2Te3films.Bymeansofplasmoniccalculations,weattributethered-shiftofabsorptionpeakstothereductionofcarrierconcentrationandthechangeofeffectivemassofBi2Te3filmswiththeincreasedannealingtemperature.
简介:Waveletde-noisinghasbeenwellknownasanimportantmethodofsignalde-noising.Recently,mostoftheresearcheffortsaboutwaveletde-noisingfocusonhowtoselectthethreshold,whereDonohomethodisappliedwidely.Comparedwithtraditional2-bandwavelet,3-bandwavelethasadvantagesinmanyaspects.Accordingtothistheory,anadaptivesignalde-noisingmethodin3-bandwaveletdomainbasedonnonparametricadaptiveestimationisproposed.Theexperimentalresultsshowthatin3-bandwaveletdomain,theproposedmethodrepresentsbettercharacteristicsthanDonohomethodinprotectingdetailandimprovingthesignal-to-noiseratioofreconstructionsignal.
简介:四川长虹公告称,该公司旗下的等离子(PDP)显示屏及模组项目一期工程建设已全部完成,2009年1月进入批量试产,计划3月份正式量产。受去年四川汶川地震等综合因素影响,四川长虹推迟了PDP屏项目的量产时间。公告还表示,四川长虹去年发行分离交易的可转换公司债券募资之后,两次向负责运营PDP屏项目的四川虹欧显示器件有限公司(下“四川虹欧”)增资共4亿元,目前四川虹欧的注册资本约为3.5亿美元、实收资本为2.75亿美元,四川长虹控股50.94%。现在四川虹欧PDP项目设备安装已全部结束,已小批量试产多品种的高清屏模组和全高清屏模组。