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6 个结果
  • 简介:Terreneuvian时代(541-521妈)也是为在华南的metallogenesis的一个重要时期,作为被Ni瞬间polymetallic层的普遍出现在更深的斜坡盆背景在先前的浅站台边缘和充实V的黑页岩上代表。在这研究,我们测量了Ni瞬间polymetallic层的Re-Osisochron年龄(Songlin,Niuchang,Sancha,Chuanpengwan),V富有的黑页岩(Bahuang),和在在贵州和湖南省的基础Niutitang形成的非产金属的黑页岩(Shuidong),华南。Ni瞬间polymetallic层和充实V的黑页岩有类似的Re-Osisochron年龄,建议产金属的矿石的这二种类型的并发的免职。这个建议与由使用直接作为一个stratigraphic标记位于这些产金属的层下面的榴状的磷钙土床的传统的stratigraphic关联一致。而且,产金属的矿石和非产金属的黑页岩有类似的起始的187Os/1880.8-0.9的O比率,与热水的活动的次要的贡献为主导的海水起源争论。而且,Re-Os同位素的数据也暗示那Ni瞬间和V矿石可能源于一样的来源。我们建议产金属的矿石的空间分发能被non-sulfidicanoxic-suboxic楔(NSASW)的开发在以前的平台边缘在斜坡盆和sulfidic楔解释。深水的Upwelling温和地减少的、器官的富有的NSASW,在V,(V)优先地被归结为V(IV),并且是由有机金属的复杂形成从海水移开的第一横断。作为结果,V富有的黑页岩在Yangtze站台的斜坡盆扔。进sulfidic站台边缘的深水的进一步的运动导致Ni瞬间polymetallic层形成。

  • 标签: RE-OS同位素 金属矿床 牛蹄塘组 下寒武统 中国南方地区 金属有机络合物
  • 简介:通过对白山斑岩型钼矿床深部钻孔的7件辉钼矿进行Re-Os同位素测年分析,获得辉钼矿模式年龄为(223.5±3.2)Ma~(227.5±3.1)Ma,辉钼矿等时线年龄数据为(223.2±2.7)Ma(MSWD=0.64),成矿时代为晚三叠世早期。结合对已有年龄资料的归纳和分析认为,白山钼矿的成矿作用与东天山觉罗塔格地区印支期花岗质岩浆活动有关,该矿床测年结果代表了东天山地区印支期一次成矿作用的高峰。

  • 标签: 白山钼矿床 RE-OS测年 印支期 花岗斑岩
  • 简介:Thermalmaturationandpetroleumgenerationmodelingofshalesisessentialforsuccessfulexplorationandexploitationofconventionalandunconventionaloilandgasplays.Forbasinwideunconventionalresourceplayssuchmodeling,whenwellcalibratedwithdirectmaturitymeasurementsfromwells,cancharacterizeandlocateproductionsweetspotsforoil,wetgasanddrygas.Thetransformationofkerogentopetroleumisassociatedwithmanychemicalreactions,butmodelstypicallyfocusonfirst-orderreactionswithratesdeterminedbytheArrheniusEquation.AmisconceptionhasbeenperpetuatedformanyyearsthataccuratethermalmaturitymodelingofvitrinitereflectanceusingtheArrheniusEquationandasingleactivationenergy,toderiveatime-temperatureindex(∑TTIARR),asproposedbyWood(1988),isflawed.ThisclaimwasinitiallymadebySweeneyandBurnham(1990)inpromotingtheir'EasyRo'method,andrepeatedbyothers.Thispaperdemonstratesthroughdetailedmulti-dimensionalburialandthermalmodelinganddirectcomparisonofthe∑TTIARRand'EasyRo'methodsthatthisisnotthecase.The∑TTIARRmethodnotonlyprovidesaveryusefulandsensitivematurityindex,itcanreproducethecalculatedvitrinitereflectancevaluesderivedfrommodelsbasedonmultipleactivationenergies(e.g.,'EasyRo').Throughsimpleexpressionsthe∑TTIARRmethodcanalsoprovideoilandgastransformationfactorsthatcanbeflexiblyscaledandcalibratedtomatchtheoil,wetgasanddrygasgenerationwindows.Thisisachievedinamore-computationally-efficient,flexibleandtransparentwaybythe∑TTIARRmethodthanthe'EasyRo'method.Analysisindicatesthatthe'EasyRo'method,usingtwentyactivationenergiesandaconstantfrequencyfactor,generatesreactionratesandtransformationfactorsthatdonotrealisticallymodelobservedkerogenbehaviourandtransformationfactorsovergeologictimescales.

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  • 简介:TheoccurrencesofassociatedelementsandtheirgeneticfactorsintheNo.30coalseamintheZhijinCoalfieldwerestudiedusinginstrumentalneutronactivationanalysis,inductivelycoupledplasma-atomicemissionspectroscopy,andascanningelectronmicroscopeequippedwithanenergy-dispersiveX-rayanalyzer.And,amicroscopephotometersystem(LeitzMPV-Ⅲ)wasusedtoobservethecharacteristicsofcoalpetrology.Accordingtotheinfluencedegreebythesiliceouslow-temperaturehydrothermalfluids,theorganicmatterisdividedintofourtypes:A,B,C,andDofthehydrothermally-alteredorganicmatter(HAOM).ThestudyshowsthatthehighcontentofFe(2.31%)isnotfrompyrite,butmostlyfromthesiliceouslow-temperaturehydrothermalfluids.Theoccurrencesoftheassociatedelementsinthefourorganicmattertypesaredifferent.ThecontentsofFe,Si,andAlaredecreasing,butSandCuareincreasingintheorderoftheHAOM-A,HAOM-B,HAOM-C,andHAOM-D.Thelosingrateofsulfurinorganicmatteris0.35%andthecontentofFetakenfromthelow-temperaturehydrothermalfluidsintotheorganicmatteris0.794%duringthesiliceouslow-temperaturehydrothermalfluidsinvadingthecoalseam.Theabovefactsindicatethatthelow-temperaturehydrothermalfluidsplayacrucialroleinthere-distributionsandoccurrencesofassociatedelementsincoal.

  • 标签: LOW-TEMPERATURE hydrothermal fluid hydrothermally-altered organic matter
  • 简介:Themulti-stageintrusionsofintermediate-acidmagmaoccurintheBangpuminingdistrict,thepetrogenicagesofwhichhavebeenidentified.Thetimesandsequencesoftheiremplacementhavebeencollatedandstipulatedindetailinthispaperbyusingthelaserablation-inductivelycoupledplasma-massspectrometry(LA-ICP-MS)zirconU-Pbdatingmethod.Theagesofbiotitemonzogranitethatwereformedbeforemineralizationinthesouthwestofthisminingdistrictare70±1Ma(meansquareofweighteddeviates(MSWD)=9.5,n=8)and60.60±0.31Ma(MSWD=3.8,n=16),whichbelongtothelateCretaceous-earlyPaleoceneinage.Thatmeans,theyareproductsofanearlytectonicmagmaticeventofthecollisionbetweentheIndianandAsiancontinentals.Theagesofore-bearingmonzograniteporphyryandore-bearingdioriteporphyriteare16.23±0.19Ma(MSWD=2.0,n=26)and15.16±0.09Ma(MSWD=3.9,n=5)separately,whichbelongtothemiddleMioceneinage;namely,theyareproductsoftheGangdesepost-collisionextensionalstagewhencrust-mantlematerialsmeltedandmixedaswellasmagmaticintrusionsimultaneouslyoccurred.Somezirconswithagesof203.6±2.2Ma(MSWD=1.18,n=7)werecapturedintheore-bearingdioriteporphyrite,whichshowsthattherehadbeentectono-magmaticeventsinthelateTriassic-earlyJurassic.Molybdenum(copper)ore-bodiesproducedinthemonzograniteporphyryandcopper(molybdenum)ore-bodiesproducedinthedioriteporphyritearethemainoretypesinthisoredeposit.ThemodelagesofRe-Osisotopicdatingforthe11molybdeniteare13.97-15.84Ma,whileisochronagesare14.09±0.49Ma(MSWD=26).Theisochronagesofsevenmolybdenitefrommolybdenum(copper)orewithmonzograniteporphyrytypeare14.11±0.31Ma(MSWD=5.2).Thereisgreaterrorintheisochronagesoffourmolybdenitefromcopper(molybdenum)orewithdioriteporphyritetype,andtheirweightedaveragemodelagesof14.6±1.2Ma(MSWD=41),whichgenerallyrepresentthemineralizationage.TheresultsabouttheR

  • 标签: LA-ICP-MS 锆石U-Pb定年 矽卡岩型矿床 中酸性侵入岩 RE-OS同位素 辉钼矿