简介:Akindofdryrefractorysealingmaterialhasbeendevelopedtorepairthefinecracksincokeovenchamber.Withsilicasandasthemainrawmaterial,thesealingmaterialisblownintocokeovenchamberbycompressedairwhilebeingapplied,andbondedtobricksurfaceorfilledinfinecracksofchamberunderrightpressure.Thephysicalpropertiesofthematerialaresimilartothoseofsilicabricksduringitsapplication.Soitcanbeadaptedtoconditionsofcokeovenandhasgoodservicelife.Thestudyandapplicationresultsofthesealingmaterialaredescribedinthispaper.
简介:ThepaperdescribestheeffectofadditivesAl,Si,SiCandB4ContheexpansionofMgO-ZrO2-Cmaterialafterbeingcoked.TheresultsindicatethatAlandSicannotincreaseitshotandcoldstrength.AlandSiwereoxidizedtoformAl2O3andSiO2respectively,andthenreactedwithCaZrO3orstabilizerinc-ZrO2toformcalciumaluminate,spinel(MA),dicalciumsilicate(C2S)andforsterite(M2S).Meanwhile,α-C2Swastransformedtoγ-C2Sandc-ZrO2tom-ZrO2whentemperaturechanged.AlltheabovereactionsresultedinthedecreaseoftheamountofAl4C3andSiCandtheincreaseinbulkvolume,whichcausedthestructureofMgO-ZrO2-Cmaterialdestroyed.Hence,contrarytotheMgO-Cmaterial,whenaddingAl.andSi,theMgO-ZrO2-Cmaterialwouldbestructurallydeterioratedafterheat-treatmentanditsstrengthandcorrosionresistancedecreased.
简介:OnthebaseofMgO-CaOcoatingmaterialTD-CA12fortundish,anewTD-CA32withhighCaOcontentwasdeveloped,ItsCaOcontentis30%-36%andMgOcontentis45%-55%,TheapplicationresultinBaosteelshowsthatTD-CA32notonlyhasthesamepropertiesasTD-CA12butalaohastheimprovedpropertiesofdisintegrationandsteelpurifing.
简介:TherearemanyprocessestoproduceCr2O3fromchrome-ores,DifferentparticlesizerangesofCr2O3powder,finepinmentgradegreenCr2O3andcoarsemetallurgygradeblackCr2O3,aremadebydifferentprocessesinChina,GreenCr2O3assuperfineandadditionandmetallurgygradeblackCr2O3usedtosynthesizeCr2O3graincanbeappliedtorefractories.ItisverydifficultforhighpurityCr2O3tosintertodensificationandTiO2additioniscontributedtodensificationofCr2O3sinteredathightemperature,Cr2O3grainswithrelativedensityof91%-95%aregainedbysinteringCr2O3withTiO2additionandelectrofusingCr2O3rawmaterials.
简介:AkindofZrO2ceramicmaterialforporousmediaburnerwaspreparedbypolymericspongeprocesswithstartingmaterialsofzircon,zirconiapowder,microsilica,andballclay,andbinderofsilicasolthroughreaction-sintering.Theeffectsofmicrosilicaadditiononcoldcrushingstrengthandzirconia/zirconaddingratioonthermalshockresistancewerestudied.Theresultsshowthattheporousmediamaterialhasproperporosity,highstrength,andexcellentthermalshockresistancewhenzirconiaadditionis85%andzirconadditionis5%.Theperformanceindexesare:porosity82%,coldcrushingstrength3.1MPa,thermalshockresistancemorethan10cycles,andgoodthermalshockresistanceto1500℃flame.
简介:Functionalrefractories,includingsubmergedentrynozzle(SEN),ladleshroudandmonolithicstopper,arethekeyrefractoriesforcontinuouscasting.Drivenbythedemandofhigh-speedcontinuouscasting,traditionalfunctionalrefractoriesfailtomeettheneedsoflongspanlife,andhighperformancefunctionalrefractoriesforcontinuouscastingareincreasinglyrequired.Throughstructureandmaterialdesign,theperformanceoffunctionalrefractoriesissignificantlyimproved.Inthispaper,someresearchadvancesonfunctionalrefractoriesforcontinuouscastingwerementioned.Throughnumericalmodelingandhotsimulation,theservicelifeofnon-preheatingladleshroudwasincreasedfrom8htomorethan12h.Throughthewatermodeling,theflowpatternsinthemoldweresignificantlyimprovedandthroughhotsimulationandmaterialdesign,theservicelifeandreliabilityofSENwerealsosignificantlyimproved.
简介:Micro-poredCA6-MAlightweightmaterialwithCA6:MAmassratioof7:3waspreparedusingAl(OH)3.MgCO3andCaCO3asstartingmaterials,andanthracite.sweetpotatostarchandanthracite+sweetpotatostarchasporeformingagent(PFA)withanadditionof10mass%.20mass%and30mass%.respectively.Thestartingmaterialsweredrymixed.wetco-milledinaballmillfor1h.slipcastintocylindricalspecimenswithadiameterof60mm.andthencalcinedat1450℃for3h.WiththeincreaseofPFAaddition.apparentporosityincreases,andbulkdensitydecreases.TheinfluenceofdifferentPFAsonpropertiesofthemicro-poredLWCA6-MAaggregatewasinvestigated.TheachievedCA6-MA.byadding30%sweetpotatostarch.hasaporosityof76.8%.bulkdensityof0.78g·cm-3andmedianporesizeof1.90μm.
简介:ThispapertestifiesthataluminiumandsiliconaswellastheircarbidexandnitridescanreactwithCOincarbon-containingzonetoformAl2O3andSiOgasthroughexperimentandthermodyanmicanalysis,ThegasesdiffusetooxidizedzoneandreactwithoxidizerssuchasCO2,Asaresult,Al2O3andSiO2aredepositedfromthegases,wihichblockthepores,thusreducetheamountofgasdiffusionandincreaseoxidationresistnaceofcarbon-containingmaterials.
简介:MgO-Al2O3-Cr2O3rammingmixesmadeofdifferentrawmaterialshavedifferentmineralstructureanddifferentphysicalpropertiesthoughwiththeidenticalparticlesizedistribution,thesameamountofbinderandchemicalcomposition.Theresidualcarboncontentofthefusedmagnesia-chromematerialmadeinreducingatmosphereisveryhigh,ifthismaterialsisusedintheMgO-Al2O3-Cr2O3rammingmix,itwouldcausespallingofthefurnaceliningduringdrying-out.