简介:Tris)(η5-cyclopentadienyl-μ-carbonyl-iron)-μ3-nitrosylclusterwasobtainedfromthereactionofcyclopentadienyldicarbonylirondimerwithnitrogenmonoxideinxylene.Theclusterwascharacterizedbyelementalanalyses,IR,MSand1HNMR.Thecrystalstructureof[(η5-C5H5)(μ-CO)Fe]3(μ3-NO).C4H8OwasdeterminedbyX-raydiffractionanalysis.ItcrystallizesintheorthorhombicspacegroupPnma,a=9.053(2),6=10.545(2),c=22.525(4)A,V=2150.3(7)A3,Z=4,Dc=1.68g.cm-3;structuresolutionandrefinementbasedon1141reflectionswithI>3.0(I)(MoKa,A=0.71073A)convergedatR=0.0540.Theinfraredabsorptionbandat1325cm-1oftheμ3-NOinthecluster,whichisredshifted,showsthatμ3-NOisactivated.
简介:Thetetranuclearalkyltin(Ⅳ)compounds{[R2Sn(C9H8N3O3)O]SnR3}2[R=n-Bu(1),4-CNC6H4CH2(2),C6H5CH2(3),4-ClC6H4CH2(4)]werepreparedbythereactionofSchiffbaseligandpyruvicacidisonicotinylhydrazonewith(R3Sn)2Ointhecorrespondingmolarratioof1:1.Allcompoundshavebeencharacterizedbyelementalanalysis,IRand^1HNMRspectra.Thecrystalstructureofcompound1wasdeterminedbyX-raysinglecrystaldiffractionalanalysis.Thiscompoundexhibitsadimericstructurecontainingdistannoxaneunitswithtwotypesofthetinatoms.Forthefirsttinatom,itappearstobeseven-coordinatedwithadistortedpentagonalbipyramidgeometry,andtheotherisfive-coordinatedwithadistortedtrigonalbipyramidalgeometry.Themoleculesarepackedintheunitcellintwo-dimensionalnetworkstructurethroughaninteractionbetweentheNatomsofthepyridineandthetinatomsofanadjacentmolecule.
简介:Blendsofpoly(3-hydroxybutyrate-co-3-hydroxyhexanoate)(PHBHHx)andpoly(butylenesuccinate-adipate)(PBSA),bothbiodegradablesemicrystallinepolyesters,werepreparedwiththeratioofPHBHHx/PBSArangingfrom80/20to20/80bymeltmixingmethod.Differentialscanningcalorimetry(DSC),thermogravimetryanalysis(TGA),dynamicmechanicalthermalanalysis(DMA),polarizingopticalmicroscopy(POM)andwideangleX-raydiffractometer(WAXD)wereusedtostudythemiscibilityandcrystallizationbehaviorofPHBHHx/PBSAblends.ExperimentalresultsindicatethatPHBHHxisimmisciblewithPBSAasshownbythealmostunchangedglasstransitiontemperatureandthebiphasicmelt.
简介:Inthispaper,thetwoeffluentsfromPBA(3-phenoxy-benzaldehyde)productionprocessweretreatedbypolymericadsorbentCHA-111.PBAorPBC(3-phenoxy-benzoicacid)wasrecoveredfromthewastewaterintheprocessofneutralization.Asasecondarytreatmentmethod,adsorptionwithCHA-111showedbetterefficiencythanphotocatolyticdecompositionandsolventextraction.Theoptimaltechnologicalparameterswere:adsorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:1.0BV/hr,80℃,8%sodiumhydroxideaqueoussolutions.Inconclusion,99.9%CODintheneutralizingwastewaterand98.4%CODinthehydrolysiswastewaterareremovedsuccessfully.
简介:这笔记学习关上的面向的Riemannian3-manifoldM不变的Chern-Simons。,第一成就是建立公式CS(e)鈥?CS()=degAe并且是二(全球)M的框架,和A:(3)M鈫?那么是鈥渄ifference鈥?地图。有趣的现象是为许多3-manifolds的各种各样的框架的Chern-Simons积分的鈥渏umps鈥?是至少二,而不是一个。第二个目的是给CS(e+)和CS的一个明确的代表(e?),在哪儿e+和e吗?假如M3上的鈥渓e英尺鈥?和鈥渞ight鈥?quaternionic框架分别地从沉浸M3鈫?E4被导致。因而,我们在S3(伯杰范围)上发现许多度量标准以便他们不能保角地在E4被嵌入。关键词Chern-Simons不变-伯杰范围-保角的嵌入先生(2000)题目分类53C42-58A15由NSFC支持了(资助Nos.10531090并且10229101)并且江畅学者编程序
简介:Thehomoclinicbifurcationsinfourdimensionalvectorfieldsareinvestigatedbysettingupalocalcoordinatesnearthehomoclinicorbit.Thishomoclinicorbitisnonprincipalinthemeaningsthatitspositivesemi-orbittakesorbitflipanditsunstablefoliationtakesinclinationflip.Theexistence,nonexistence,uniquenessandcoexistenceofthe1-homoclinicorbitandthe1-periodicorbitarestudied.Theexistenceofthetwofoldperiodicorbitandthree-foldperiodicorbitarealsoobtained.
简介:Wastewaterfromproductionprocessof2,3-acidwastreatedbyadsorptionusingmacroporousresinNDA-708.Afteronlyone-steptreatmentbyresinadsorption,removalefficiencyofthreekindsofnaphthalenechemicalswasabove99%;removaleficiencyofCODcrwasabove96%.Underproperoperatingcondition,desorptionefficiencywasaround100%.Therunningrecordsoftheindustrialfacilityshowedthatthenaphthlenechemicalsindesorptioneffluentcouldbereusedwithoutobviousinfluenceonthequalityoftheproduct.
简介:Sixnewcompounds,α,β-KaHb[GeW9M3(H2O)3O37].xH2O(M=Al,Ga,In;a+b=7)andα-K9H5[Ge2W18Ga6(H2O)3O74].20H2O,weresynthesizedfromthelacunaryprecursorsαandβ-GeW9O3410-andcharacterizedbyelementalanalysis,spectroscopyandelectrochemistry.Tungsten-183NMRspectraofthetitlecomplexesconsistoftwolineswithintensityratio2:1asexpectedfortrisubstitutedheteropolyanions.Theintensityratioofα-Gacompoundis1:2,whichisdifferentfromothers(2:1).WiththehelpofFABmassspectrum,weconcludedthatitisadimerwithD3h,structureinaqueous,andtheothersexistbymonomerswithC3cstructures.
简介:Thispaperintroducesanimprovednewmethodwhichisusedtorecoversilverassilvernitratebyionexchangefromthewasters.Inthismethod,wecanrecoversilvernitrate,onlybyusingakindofionexchangeresinandtwoionexchangeprocesses.Itcanreplacetheoriginalrecoverymethodinwhichtwokindsofionexchangeresinsandthreeionexchangeprocessesareneeded.Theresultissatisfied