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500 个结果
  • 简介:Theinsertionof1,1-bis(1′-naphthyl)ethylenemonomerunitintotheactivepolystyrenechainendgreatlydecreasedthereactivityoftheactivechainendtothecarbonylgroup,andallowedthepolymericchainendtoreactonlywiththedoublebondinN-methacryloylcaprolactam,resultinginN-acylcaprolactamfunctionalizedpolystyrenein100%conversion.Newdiblockcopolymerofpolystyrenewithpolycaprolactamwassynthesizedbydirectreactionofthefunctionalizedpolymerwithcaprolactamwithoutaddingadditionalalkalimetalortheircaprolactamsalts.

  • 标签: 1 1-bis (1’ -naphthyl) ETHYLENE N-methacryloylcaprolactam
  • 简介:Aseriesofnovel1H-benzimidazol-1-ylacetatesand1H-benzimidazol-1-ylpropionatescontaining1H-1,2,4-triazolemoietyweresynthesizedundermicrowaveirradiationbymulti-stepreactions,inyieldsof87-94%.TheirinvitroantifungalactivitiesagainstBotrytiscinereaandSclerotiniasclerotiorumwereevaluatedbymycelialgrowthratemethod.AllthetargetcompoundsexhibithighactivitiesagainstB.cinereawiththeEC50valuesof7.96-21.74μg/mL,higherthanthatofcarbendazim.

  • 标签: 抗真菌活性 苯并咪唑 乙酸酯 体外 合成 基团
  • 简介:<正>Inthispaper,weapplythesolitontheorytothecaseofisometricimmersionindifferentialgeometryandobtainafamilyofisometricimmersionsfromMn1(c1)×Mn2(c2)tospaceformsMn(c)byintroducing2-parameterloopalgebra.

  • 标签: SOLITON THEORY ISOMETRIC immersion Riemaniann product
  • 简介:Thehydrolysisreactionof(±)-2-acetamido-3-hydroxy-1-(4-nitrophenyl)-1-propanone[(±)-1],anintermediateofchloramphenicol,wasstudiedandthreedifferentproductswereobtainedrespectivelyunderdifferentreactionconditions.Theresolutionofhydrolysisproduct(±)-2-amino-3-hydroxy-1-(4-nitrophenyl)-1-propanone[(±)-3]wascarriedout.Aprocessofcrystallization-inducedasymmetrictransformationwasobservedandupto76%oftheopticallypureenantiomerwasobtainedintheresolutionof(±)-3.

  • 标签: Hydrolysis Resolution EPIMERIZATION
  • 简介:Therelativisticproblemofspin-1/2fermionssubjecttovectorhyperbolic(kink-like)potential(~tanhkx)isinvestigatedbyusingtheparametricNikiforov-Uvarovmethod.TheenergyeigenvalueequationandthecorrespondingnormalizedwavefunctionsareobtainedintermsoftheJacobipolynomialsintwocases.

  • 标签: 狄拉克方程 相互作用 向量 束缚态 三角 三维
  • 简介:本文研究E^n+1的中闭超曲面上的Lr(0≤r≤n)算子,得到其第一非零特征值心的两个上界估计,改进和推广了Alias等人的相应结论。

  • 标签: 第一非零特征值 闭超曲面 r-平均曲率
  • 简介:Onassumingthatweaksubstructurehasadynamicswhichissimilartoquantumchromodynamicsbutmuchstronger,weconcludethatunquenchingisindispensableforpredictionsonthespectrumofweak-substructureresonances[1].

  • 标签: Unquenching WEAK SUBSTRUCTURE
  • 简介:1-Ethoxycarbonylalkyldiphenylpolystyrylphosphoniumtriflatescanbeeasilypreparedbyquaternizingdiphenylpolystyrylphosphinewithethyl2-trifloxyalkanoates;basetreatmentofthesepolymer-supportedphosphoniumtriflatesaffords1-ethoxycarbonylalkylidenephosphoraneswhicharestableandundergosatisfactoryWittigreactions.

  • 标签: 制备 三苯基磷化氢 1-乙氧甲酰次烷基二苯基多苯乙烯基正膦
  • 简介:1.IntroductionLetRbethecollectionofallrealnumbers,andZthecollectionofallintegers.Iff1(x)andf2(x)aretwofunctionsinL2(R),theinnerproduct1,f2>isgivenbyWesayf1(x)andf2(x)arebiorthogonal,ifFirstletusdescribeaclassoffunctions(x)and(2)inL2(R)asfollows.Thr...

  • 标签: Biorthogonality
  • 简介:InthispaperitturnsoutthataBanachlatticeXisorderisomorphictol~1(Γ)forsomenonemptysetΓiffitisaSchurspaceandalltheinfinitelydimensional,separableandclosedidealsofXareorderisomorphic.

  • 标签: ISOMORPHIC nonempty INFINITELY SEPARABLE proof TURNS
  • 简介:Apracticalprotocoltoobtain1,1'-binaphthyl-2,2'-diaminewasdevelopedfrom2-naphtholand2-naphthylhydrazineundermildconditions:solvent-free,125-130℃,atmosphericpressure.Theconvenientproceduremakestheprocessamenableforlarge-scalesynthesisoftheversatilecompound.

  • 标签: 联萘 合成 萘酚 压下 氨基 功能化合物
  • 简介:WeuseamodifiedBecke-JohnsonexchangeplusalocaldensityapproximationcorrelationpotentialwithinthedensityfunctionaltheorytoinvestigatetheelectronicstructuresofHg1-xCdxTeandIn1-xGaxAswithxbeing0,0.25,0.5,0.75,and1.Forbothofthetwoseries,ourcalculatedenergygapsanddielectricfunctions(realpartε1andimaginarypartε2)areinagreementwiththecorrespondingexperimentalresultswithxbeingbetween0and1.Thecalculatedzero-frequencyrefractiveindexvariesgreatlywithxforHg1-xCdxTe,butchangeslittlewithxforIn1-xGaxAs,whichisconsistentwiththerealpartsoftheirdielectricfunctions.Therefore,thisnewapproachissatisfactorytodescribetheelectronicstructuresandtheopticalpropertiesofthesemiconductors.

  • 标签: HG1-XCDXTE 密度泛函理论 光学性质 能隙 HG1-XCDXTE 局域密度近似
  • 简介:New[1+1]and62-membered[2+2]Schiffbasemacrocyclescontaininga2,6-diamidopyridinesubunithavebeensynthesizedbycondensationreactionoftheprecursorspyridine-2,6-dicarboxamideand1,10-bis(20-formylphenyloxy)decaneinthepresenceofphosphoricacidviaaone-potprocess.Thecyclocondensedproductswereeffectivelyisolatedbygelcolumnchromatographyandcharacterizedby~1HNMR,FTIR,massspectrometryandX-rayanalysis.Thetwomacrocycleshaveatwistedstructure,andnotanopen‘circular’conformationinthesolidstate.

  • 标签: 大环化合物 一锅法合成 凝胶柱层析 X射线分析 反应合成 FTIR
  • 简介:The1,1'-binaphtholbasedoligomers3and7with3,3'-acetylene-phenylene-acetylenespacerwerepreparedfromBINOL1.ThehighopticalrotationvalueandCDspectrademonstratedthemainchainchiralityoftheoligomermolecule.TheUV-VISandfluorescentspectraevidencethecharacteristicsofconjugatedstructure.Incomparisonwitholigomer2bearing3,3'-acetylenespacer,theoligomers3and7havelongerefficientconjugationsegment,andtheirfluorescentquantumyields(φ)increased(0.60-0.65versus0.14).Extendingtheeffectiveconjugationsegmentwouldimprovethephotophysicalpropertiesofchiralconjugatedpolymers.``

  • 标签: CHIRAL CONJUGATED oligomer BINOL 3 3'-Acetylene-phenylene-acetylene SPACER
  • 简介:数列{(1+1/n)~2}的极限是数学上最重要的极限之一,关于它的存在性的证明方法已有多种,参见文[1]、[2]、[3],本文提供这个极限存在性的两种证法,并且给出用常用对数的工具计算e的近似值及进行误差估计的初等方法。

  • 标签: 证明方法 误差估计 证法 近似计算 初等方法 算术平均