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简介：MesoporousLiFePO4/Ccompositescontaining80wt%ofhighlydispersedLiFePO4nanoparticles(4-6nm)werefabricatedusingbimodalmesoporouscarbon(BMC)ascontinuousconductivenetworks.TheuniqueporestructureofBMCnotonlypromisesgoodparticleconnectivityforLiFePO4,butalsoactsasarigidnano-confinementsupportthatcontrolstheparticlesize.Furthermore,thecapacitieswereinvestigatedrespectivelybasedontheweightofLiFePO4andthewholecomposite.Whencalculatedbasedontheweightofthewholecomposite,itis120mAh·g-1at0.1Cofthehighloadingelectrodeand42mAh·g-1at10Cofthelowloadingelectrode.TheelectrochemicalperformanceshowsthathighLiFePO4loadingbenefitslargetapdensityandcontributestotheenergystorageatlowrates,whiletheelectrodewithlowcontentofLiFePO4displayssuperiorhighrateperformance,whichcanmainlybeduetothesmallparticlesize,gooddispersionandhighutilizationoftheactivematerial,thusleadingtoafastionandelectrondiffusion.

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简介：Directconversionoffructose-basedcarbohydratesto5-ethoxymethylfurfural(EMF)catalyzedbyLewisacidinethanolwasinvestigated.ItwasfoundthatBF3(Et)2Owasfavorablefor5-hydroxymethylfurfural(HMF)etherificationtoEMF.BF3(Et)2OcombinationwithAlCl36H2Owiththemolarratioof1wasaneffectivecatalystsystemforsynthesisofEMFfromfructose-basedcarbohydrates.55.0%,45.4%and23.9%ofEMFyieldswereobtainedfromfructose,inulinandsucroseunderoptimizedconditions,respectively.

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简介：Ultrafastfiberlasersareingreatdemandforvariousapplications,suchasopticalcommunication,spectroscopy,biomedicaldiagnosis,andindustrialfabrication.Here,wereportthehighlystablefemtosecondpulsegenerationfromaMXenemode-lockedfiberlaser.Wehavepreparedthehigh-qualityTi3C2Txnanosheetsviatheetchingmethod,andcharacterizedtheirultrafastdynamicsandbroadbandnonlinearopticalresponses.Theobviousintensity-andwavelength-dependentnonlinearresponseshavebeenobservedandinvestigated.Inaddition,ahighlystablefemtosecondfiberlaserwithsignal-to-noiseratioupto70.7dBandcentralwavelengthof1567.3nmhasbeendelivered.Thestudymayprovidesomevaluabledesignguidelinesforthedevelopmentofultrafast,broadbandnonlinearopticalmodulators,andopennewavenuestowardadvancedphotonicdevicesbasedonMXenes.

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简介：Theresultsonadissociationbehaviorofpropanehydratespreparedfrom'drywater'andcontainedunreactedresidualwaterintheformoficeinclusionsorsupercooledliquidwater(watersolutionofgas)werepresentedfortemperaturesbelow273K.Thetemperaturerampingorpressurereleasemethodwasusedforthedissociationofpropanehydratesamples.Itwasfoundthatthemechanismofgashydratedissociationattemperaturesbelow273Kdependedonthephasestateofunreactedwaterinthehydratesample.Gashydratesdissociatedintoiceandgasiftheiceinclusionswereinthehydratesample.Thesamplesofpropanehydrateswithinclusionsofunreactedsupercooledwateronly(withouticeinclusions)dissociatedintosupercooledwaterandgasbelowthepressureofthesupercooledwater-hydrate-gasmetastableequilibrium.

简介：氧化铝弥散强化铜合金是国际热核实验堆（ITER）的备选热沉材料之一,氘在其中的渗透滞留行为关系到ITER运行的安全性。通过气体驱动渗透平台测定了实验温度621~803K时氘气在氧化铝弥散强化铜合金中的渗透参数;通过热脱附谱实验平台记录了2种氧化铝弥散强化铜合金以及CuCrZr的热脱附曲线。结果表明：在相同温度区间内,氘气在氧化铝弥散强化铜合金中的渗透系数与纯铜及CuCrZr接近,说明氧化铝弥散相对氘气在氧化铝弥散强化铜合金中的渗透系数基本没有影响,而扩散系数比在纯铜和CuCrZr中都低,且在低温时显著降低;2种氧化铝弥散强化铜合金均有3个脱附峰,而CuCrZr合金只有1个脱附峰。

简介：Thesuppressionoftherecombinationofelectronsandholes(e–h)andtheenhancementofthelightabsorptionofsemiconductorsaretwokeypointstowardefficientphotocatalyticdegradation.Here,wereportafew-layerg-C3N4/α-MoO3nanoneedles(flg-C3N4/α-MoO3NNs)all-solid-stateZ-schememechanismphotocatalystsynthesizedviaatypicalhydrothermalmethodinacontrolledmanner.Therecombinationofthephoto-inducede–hpairscouldbeeffectivelyrestrainedbytheZ-schemepassagewaybetweentheflg-C3N4andα-MoO3NNsinthecomposite,whichcouldalsopromiseahighredoxabilitytodegradepollutants.Anditbecamepossibleforthepreparedphotocatalysttoabsorblightinawiderangeofwavelengths.Thedetailedmechanismwasstudiedbyelectronspin-resonancespectroscopy(ESR).Thelow-dimensionalnanostructureofthetwoconstituents(α-MoO3NNswithone-dimensionalstructureandflg-C3N4withtwo-dimensionalstructure)endowedthecompositewithvarietiesofexcellentphysicochemicalproperties,whichfacilitatedthetransferanddiffusionofthephotoelectronsandincreasedthespecificsurfaceareaandtheactivesites.The10wt%flg-C3N4/α-MoO3NNsshowedthebestphotocatalyticperformancetowardRhBdegradation,therateofwhichwas71.86%,~2.6timeshigherthanthatofα-MoO3NNs.

简介：Throughournewly-developed'chemicalvapordepositionintegratedprocess(CVD-IP)'usingcarbondioxide(CO2)astherawmaterialandonlycarbonsourceintroduced,CO2couldbecatalyticallyactivatedandconvertedtoanewsolid-formproduct,i.e.,carbonnanotubes(CO2-derived)ataquitehighyield(thesingle-passcarbonyieldinthesolid-formcarbon-productproducedfromCO2catalyticcaptureandconversionwasmorethan30%atasingle-passcarbon-base).Forcomparison,whenonlypurecarbondioxidewasintroducedusingtheconventionalCVDmethodwithoutintegratedprocess,nosolid-formcarbon-materialproductcouldbeformed.IntheadditionofsaturatedsteamatroomtemperatureinthefeedforCVD,thereweremuchmoreend-openingcarbonnano-tubesproduced,ataslightlyhighercarbonyield.Theseinspiringworksopenedaremarkableandalternativenewapproachforcarbondioxidecatalyticcapturetosolid-formproduct,comparingwiththatofCO2sequestration(CCS)orCO2mineralization(solidification),etc.Asaresult,therewasmuchlessbodyvolumeandalmostnogreenhouseeffectforthissolid-formcarbon-materialthanthoseofprimitivecarbondioxide.

简介：在未采取预电离措施的情况下，研究了纯sf6气体及sf6/h29sf6/c2h6两种混合气体激光介质脉冲放电特性。实验结果表明，无预电离时SF68其混合气体介质可以实现自引发体放电，气体介质体放电维持电压主要由SF,;含量决定，C2H6具有抑制电弧的作用，可以有效延长体放电维持时间。分析认为，sf66体高折合场强E/P导致的放电通道电流密度受限和高电负度■引起的放电通道中负离子分解产生二次电子，是介质实现自引发体放电的重要机理。