简介：建立了液液萃取-气相色谱质谱联用法测定水中34种有机氯农药和氯苯类化合物的方法,实验考察了样品前处理过程中盐析剂用量、色谱柱比对等条件并优化选择。实验结果表明:加入10g氯化钠作为盐析剂时回收率最高;VF-1701msUI色谱柱比HP-5msUI色谱柱对化合物分离效果更好,用时更短,线性更好。本方法检出限为0.003~0.044μg/L,所得各组分的精密度为1.2%~7.9%,平均回收率为70.2%~114%。

简介：Inmarineseismicexploration,ocean-bottomcabletechniquesaccuratelyrecordthemulticomponentseismicwavefield;however,theseismicwavepropagationinfluid–solidmediacannotbesimulatedbyasinglewaveequation.Inaddition,whentheseabedinterfaceisirregular,traditionalfinite-differenceschemescannotsimulatetheseismicwavepropagationacrosstheirregularseabedinterface.Therefore,anacoustic–elasticforwardmodelingandvector-basedP-andS-waveseparationmethodisproposed.Inthismethod,wedividethefluid–solidelasticmediawithirregularinterfaceintoorthogonalgridsandmaptheirregularinterfaceintheCartesiancoordinatessystemintoahorizontalinterfaceinthecurvilinearcoordinatessystemofthecomputationaldomainusingcoordinatestransformation.Theacousticandelasticwaveequationsinthecurvilinearcoordinatessystemareappliedtothefluidandsolidmedium,respectively.Attheirregularinterface,thetwoequationsarecombinedintoanacoustic–elasticequationinthecurvilinearcoordinatessystem.Wenextintroduceafullstaggered-gridschemetoimprovethestabilityofthenumericalsimulation.Thus,separateP-andS-waveequationsinthecurvilinearcoordinatessystemarederivedtorealizetheP-andS-waveseparationmethod.