简介:Theenzymaticresolutionofracemicmethyl3-phenylglycidatewasinvestigated.Itwasfoundthatthehydrolysisrateof(2S,3R)-enantiomerwasfasterthanthatof(2R,3S)-enantiomerbyanewlipase.Atoptimalcondition96%of(2R,3S)-methylphenylglycidatewitheeof100%wasrecoveredfromtheracemicmixture.
简介:<正>LetCbeann-dimensionalspherewithdiameter1andcenterattheorigininEn.Theview-obstructionproblemforn-dimensionalspheresistodetermineaconstantv(n)tobethelowerboundofthoseαforwhichanyhalf-lineL,givenbyxi=ait(i=1,2,...,n)whereparametert≥0andai(i=1,2,...,n)arepositiverealnumbers,intersectsΔ(C,α)={αC+(m1+(1/2),m2+(1/2),…,mn+(1/2)):m1,m2,…mnnonnegativeintegers}.Inthispaper,forn=3,thefollowingresultisproved.Forα>1/51/2wehavethatanyhalf-lineL,givenbyxi=ait(i=1,2,3),intersectsΔ(C,α),whereparametert≥0andai(i=1,2,3)arepositiverealnumberssuchthat|a|+|b|+|c|≠3wheneveraa1+ba2+ca3=0forthreeintegersa,b,c.
简介:<正>Inthisnote.wewillshowthatnononuniformlatticeofSO(3,1)canbethefundamentalgroupofaquasi-compactKhlermanifold.Thus,combiningwiththeresultin[1].onegetsthatanonuniformlatticeinSO(n,1)(n≥3)cannotbeπ1ofanyquasi-compactKhlerianmanifold.
简介:Tris)(η5-cyclopentadienyl-μ-carbonyl-iron)-μ3-nitrosylclusterwasobtainedfromthereactionofcyclopentadienyldicarbonylirondimerwithnitrogenmonoxideinxylene.Theclusterwascharacterizedbyelementalanalyses,IR,MSand1HNMR.Thecrystalstructureof[(η5-C5H5)(μ-CO)Fe]3(μ3-NO).C4H8OwasdeterminedbyX-raydiffractionanalysis.ItcrystallizesintheorthorhombicspacegroupPnma,a=9.053(2),6=10.545(2),c=22.525(4)A,V=2150.3(7)A3,Z=4,Dc=1.68g.cm-3;structuresolutionandrefinementbasedon1141reflectionswithI>3.0(I)(MoKa,A=0.71073A)convergedatR=0.0540.Theinfraredabsorptionbandat1325cm-1oftheμ3-NOinthecluster,whichisredshifted,showsthatμ3-NOisactivated.
简介:Thetetranuclearalkyltin(Ⅳ)compounds{[R2Sn(C9H8N3O3)O]SnR3}2[R=n-Bu(1),4-CNC6H4CH2(2),C6H5CH2(3),4-ClC6H4CH2(4)]werepreparedbythereactionofSchiffbaseligandpyruvicacidisonicotinylhydrazonewith(R3Sn)2Ointhecorrespondingmolarratioof1:1.Allcompoundshavebeencharacterizedbyelementalanalysis,IRand^1HNMRspectra.Thecrystalstructureofcompound1wasdeterminedbyX-raysinglecrystaldiffractionalanalysis.Thiscompoundexhibitsadimericstructurecontainingdistannoxaneunitswithtwotypesofthetinatoms.Forthefirsttinatom,itappearstobeseven-coordinatedwithadistortedpentagonalbipyramidgeometry,andtheotherisfive-coordinatedwithadistortedtrigonalbipyramidalgeometry.Themoleculesarepackedintheunitcellintwo-dimensionalnetworkstructurethroughaninteractionbetweentheNatomsofthepyridineandthetinatomsofanadjacentmolecule.
简介:Blendsofpoly(3-hydroxybutyrate-co-3-hydroxyhexanoate)(PHBHHx)andpoly(butylenesuccinate-adipate)(PBSA),bothbiodegradablesemicrystallinepolyesters,werepreparedwiththeratioofPHBHHx/PBSArangingfrom80/20to20/80bymeltmixingmethod.Differentialscanningcalorimetry(DSC),thermogravimetryanalysis(TGA),dynamicmechanicalthermalanalysis(DMA),polarizingopticalmicroscopy(POM)andwideangleX-raydiffractometer(WAXD)wereusedtostudythemiscibilityandcrystallizationbehaviorofPHBHHx/PBSAblends.ExperimentalresultsindicatethatPHBHHxisimmisciblewithPBSAasshownbythealmostunchangedglasstransitiontemperatureandthebiphasicmelt.
简介:对[0,1]上的L—可积函数ф及α>0定义下列B—D—B算子;本文研究了Mna(ф,x)当α>0时,在LP(0,1](1≤p<+∞)的一致逼近;当α≥1时在LP[O,1]及L1P[0,1]逼近度的量化估计。作者在文[4]中定义了B—D—B算子:其中fnk(X)称为Bézeief基函数文[4]研究的是B—D—B称子在C[0,1]空间中的逼近性质,本文继续[4]的工作,专研究这个算子在LP[0,1](1≤P<+∞)的逼近性质,证明了Mna(фX)当α>0时在LP[0,1]中为一致逼近,并得到了当α≥1时在LP[0,1]及L1P[0,1]中逼近度的量化估计。
简介:与浸透的土壤存款的由一条半球的冲积山谷的三维的散布和飞机P波浪的衍射的一个分析解决方案被采用Fourier-Bessel系列扩大技术开发。不同于以前的研究,浸透的土壤存款与单相的有弹性的理论在被模仿,在这篇论文,他们为浸透的多孔的媒介,和一半与Biot的动态理论被模仿空间作为asingle阶段被假定橡皮媒介。更少的频率,发生角度ofP波浪和土壤的孔在半球的冲积山谷的表面排水量放大上扔的尺寸的效果被调查。数字结果证明一条浸透的半球的冲积山谷的存在在表面排水量放大上有许多影响。当与发生ofP波浪评估一条半球的冲积山谷的排水量回答时,与Biot的动态理论模仿土壤存款是更合理的。
简介:Inthispaper,thetwoeffluentsfromPBA(3-phenoxy-benzaldehyde)productionprocessweretreatedbypolymericadsorbentCHA-111.PBAorPBC(3-phenoxy-benzoicacid)wasrecoveredfromthewastewaterintheprocessofneutralization.Asasecondarytreatmentmethod,adsorptionwithCHA-111showedbetterefficiencythanphotocatolyticdecompositionandsolventextraction.Theoptimaltechnologicalparameterswere:adsorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:1.0BV/hr,80℃,8%sodiumhydroxideaqueoussolutions.Inconclusion,99.9%CODintheneutralizingwastewaterand98.4%CODinthehydrolysiswastewaterareremovedsuccessfully.
简介:Thehomoclinicbifurcationsinfourdimensionalvectorfieldsareinvestigatedbysettingupalocalcoordinatesnearthehomoclinicorbit.Thishomoclinicorbitisnonprincipalinthemeaningsthatitspositivesemi-orbittakesorbitflipanditsunstablefoliationtakesinclinationflip.Theexistence,nonexistence,uniquenessandcoexistenceofthe1-homoclinicorbitandthe1-periodicorbitarestudied.Theexistenceofthetwofoldperiodicorbitandthree-foldperiodicorbitarealsoobtained.
简介:Wastewaterfromproductionprocessof2,3-acidwastreatedbyadsorptionusingmacroporousresinNDA-708.Afteronlyone-steptreatmentbyresinadsorption,removalefficiencyofthreekindsofnaphthalenechemicalswasabove99%;removaleficiencyofCODcrwasabove96%.Underproperoperatingcondition,desorptionefficiencywasaround100%.Therunningrecordsoftheindustrialfacilityshowedthatthenaphthlenechemicalsindesorptioneffluentcouldbereusedwithoutobviousinfluenceonthequalityoftheproduct.
简介:Sixnewcompounds,α,β-KaHb[GeW9M3(H2O)3O37].xH2O(M=Al,Ga,In;a+b=7)andα-K9H5[Ge2W18Ga6(H2O)3O74].20H2O,weresynthesizedfromthelacunaryprecursorsαandβ-GeW9O3410-andcharacterizedbyelementalanalysis,spectroscopyandelectrochemistry.Tungsten-183NMRspectraofthetitlecomplexesconsistoftwolineswithintensityratio2:1asexpectedfortrisubstitutedheteropolyanions.Theintensityratioofα-Gacompoundis1:2,whichisdifferentfromothers(2:1).WiththehelpofFABmassspectrum,weconcludedthatitisadimerwithD3h,structureinaqueous,andtheothersexistbymonomerswithC3cstructures.
简介:Thispaperintroducesanimprovednewmethodwhichisusedtorecoversilverassilvernitratebyionexchangefromthewasters.Inthismethod,wecanrecoversilvernitrate,onlybyusingakindofionexchangeresinandtwoionexchangeprocesses.Itcanreplacetheoriginalrecoverymethodinwhichtwokindsofionexchangeresinsandthreeionexchangeprocessesareneeded.Theresultissatisfied