Investigation of Structure and Hydriding Properties of La0.6 Nd0.4 Ni4.s Mn0.2 Cux Alloys

(整期优先)网络出版时间:2004-07-10
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ThestructureandhydridingperformanceofLa0.6Nd0.4Ni4.8Mn0.2Cux(x=0~0.4)alloyswereinvestigatedinordertodevelopsuitablematerialsformetalhydrideairconditioner.TheeffectofCuadditiononthecrystalstructure,equilibriumpressure,hydrogencapacityandhysteresisaswellashydrogenabsorption/desorptionkineticsweresystematicallystudiedbyusingthemeasurementofP-Cisotherms,X-raydiffractionandscanningelectronmicroscopy.AstheamountofCuincreases,theplateaupressureincreasesandhydrogenabsorption/desorptionkineticsisimproved,buttheeffectivehydrogenstoragecapacitydecreases.Itisshownthatvariationsinthebasalplaneparameteracanbeusedasanindicationfortheplateaupressurechanges.Withtheincreaseofparametera,theplateaupressuredecreases.ForLa0.6Nd0.4Ni4.8Mn0.2Cux(x=0~0.4)alloysthereisarelationshipbetweentheeffectivehydrogenstoragecapacitiesandtheratiosoftheirunitcellparameterscanda.Theeffectivehydrogenstoragecapacitydecreaseswithincreaseofa/c.