A novel formula for location of double bond in alkenyl acetates and alcohols based on mass spectral data of dimethyl disulfide derivatives

(整期优先)网络出版时间:1997-06-16
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Anewformulawaspresentedforlocatingdoublebondpositionindodecenols,tetrade-cenols,hexadecenolsandtheiracetates,basedonmassspectraldataofdimethyldisulfidederivatives.Inthisprocedure,molecularionandbasepeakionwereutilizedascharacteristicparameterstoidentifythepositionalisomers.Themethodwastestedwithmassspectraof25dimethyldisulfldederivativesofmono-unsaturatedacetatesandalcohols,andtheoriginaldouble-bondpositionineachisomerwaslocatedunambiguously.