One pot synthesis of a soluble polymer for zirconium carbide

(整期优先)网络出版时间:2010-05-15
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Anewpolymer,polyzirconoxanesal(PZS),issynthesizedfromthereactionofzirconiumoxychlorideoctahydrate(ZrOCl2-8H2O)withacetylacetone(Hacac)andsalicylalcohol(SA)byone-potprotocol.Thepolymerissolubleincommonorganicsolvents,suchasethanol,methanol,acetone,tetrahydrofuranandchloroform,andexhibitsrheologywithviscosityof100-300mpasat25℃.Thesepropertiesaresuitableforusesinfabricationofceramicmatrixfibercomposites.Pyrolysisofthispolymerat1300℃inargonprovidesnanosizedZrCwithsphericalmorphologyandsizeof20-100nm.