Platinum-group Mineral (PGM) and Base-metal Sulphide (BMS) Inclusions in Chromitites of the Zedang Ophiolite, Southern Tibet, China and their Petrogenetic Significance

(整期优先)网络出版时间:2016-03-13
/ 1
Voluminousplatinum-groupmineral(PGM)inclusionsincludingerlichmanite(Os,Ru)S2,laurite(Ru,Os)S2,andirarsite(Ir,Os,Ru,Rh)AsS,aswellasnativeosmiumOs(Ir)andinclusionsofbasemetalsulphides(BMS),includingmillerite(NiS),heazlewoodite(Ni3S2),covellite(CuS)anddigenite(Cu3S2),accompaniedbynativeiron,havebeenidentifiedinchromititesoftheZedangophiolite,Tibet.ThePGMsoccurasbothinclusionsinmagnesiochromitegrainsandassmallinterstitialgranulesbetweenthem;mostarelessthan10μminsizeandvaryinshapefromeuhedraltoanhedral.Theyoccureitherassingleorcomposite(biphaseorpolyphase)grainscomposedsolelyofPGM,orPGMassociatedwithsilicategrains.Os-,Ir-,andRu-richPGMsarethecommonspeciesandPt-,Pd-,andRh-richvarietieshavenotbeenidentified.SulfurfugacityandtemperatureappeartobethemainfactorsthatcontrolledthePGEmineralogyduringcrystallizationofthehostchromititeintheuppermantle.Iftheactivityofchalcogenides(suchasS,andAs)islow,PGEclusterswillremainsuspendedinthesilicatemeltuntiltheycancoalescetoformalloys.Underappropriateconditionsof?S2and?O2,PGEalloysmightreactwiththemelttoformsulfides-sulfarsenides.Thus,wesuggestthattheOs,IrandRumetallicclustersandalloysintheZedangchromititescrystallizedfirstunderhightemperatureandlow?S2,followedbycrystallizationofsulphidesofthelaurite-erlichmanite,solid-solutionseriesasthemagmacooledand?S2increased.TheabundanceofprimaryBMSinthechromititessuggeststhat?S2reachedrelativelyhighvaluesduringthefinalstagesofmagnesiochromitecrystallization.ThepersityofthePGEminerals,incombinationwithdifferencesinthepetrologicalcharacteristicsofthemagnesiochromites,suggestdifferentdegreesofpartialmelting,perhapsatdifferentdepthsinthemantle.Theestimatedparentalmagmacompositionsuggestsformationinasuprasubductionzone