Afugacitymodelwasdevelopedforpredictionofmixedrefrigerantgashydratesformationconditionsbasedonthemoleculecongregationandsolutiontheories.Inthismodel,gashydrateswereregardedasnon-idealsolidsolutioncomposedofwatergroupsandguestmolecules,andtheexpressionsoffugacityofguestmoleculesinhydratephasewasproposedaccordingly.Ithasbeenshownthatthedevelopedmodelcanindicatesuccessfullytheeffectofguest-guestmoleculeinteraction.Theresultsshowedthatthemodelcandescribebetterthecharacteristicsofphaseequilibriumofmixedrefrigerantgashydratesandpredictionsareingoodagreementwithexperimentaldata.
