SEPARATION AND PURIFICATION OF LIGNIN BY MEANS OF ION EXCHANGE PROCESS

(整期优先)网络出版时间:1993-01-11
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Theeffectofresinstructureondesalinationofligninsolutionwasinvestigated,theoptimalstructureofresinisasfollows;crosslinkingdegreeas4%,ratioofcationogentoanionogenisnear1.withsuchresinthedesalinationofligninwasproducedverywellbecausetheresinhasbothmoleculesievingandionretardationproperties.Thesulfonationdegressofligninandtotalsaltcontentofligninsolutionweredeterminredwithionexchangetechnique,therelativeerrorlessthan1%.Thesaltcontentofsmallmoleculeintheligninsolutionwascalculatedfromsulfonationdegreeofligninandtotalsalt.Amonggelandmacroporousresinsthebestseparationofligninfromreducingsugarwasachievedwithinterpenetratingsulfonatedresin2×1.5×1.Theseparationofligninwithinterpenetratingresinwascarriedoutsimultaneouslywithfractionationoflignin,theeffectoffractionationwithmacroporoussulfonatedresinisbetterthanthatwithinterpenetratingresin,buttheformerhasadefinitesorptionofligninwhichdecreasedtherecoveryoflignin.