Inaflowinjectionseparationandpreconcentrationsystemincorporatingamicrocolumn,theadsorptionbehavior(effectofpH,kineticadsorptioncapacity)ofmetalionsCu^2+,Cr^3+,Mn^2+,Ni^2+,La^3+,Eu^3+,Ga^3+,Mo(Ⅵ)andW(Ⅵ)onTiO2owderwithdifferentcrystalstructureandparticlediameterwasstudiedandcompared.Inaddition,theechanismoftheadsorptionofmetalionsonTiO2owderwasexplored.TheresultsshowthatcrystaltructureandparticlediameteroftheTi02powderwillefinitelyaffecttheadsorptioncapacityofmetalsont.