Syntheses, characteristics, and fluorescence properties of complexes of europium with benzoic acid and its derivatives

(整期优先)网络出版时间:2004-04-14
/ 1
Thebinarycomplexesofeuropiumwithbenzoicacidanditsderivatives(phthalicacid,m-phthalicacid,o-aminobenzoicacid,salicylicacid,andsulfosalicylicacid)weresynthesizedandtheircompositionswereidentifiedbyelementalanalyses.UVandIRofthecomplexeshavebeeninvestigated.TheUVspectraindicatedthatthecomplexes'ultravioletabsorptionweremainlytheligands'absorption.TheIRspectrashowedthattheIRspectraofcomplexesaredifferentfromthoseoffreeligands.Thefluorescencepropertiesofthemwereinvestigatedbyusingluminescencespectroscopy,theresultsshowedthatonlythreecomplexesappearasbetterluminescence,theywereEu-benzoicacid,Eu-m-phthalicacidandEu-phthalicacid,whiletheothersexhibitedtheligands'widebandemission.