Microstructure and Properties of Low Temperature Composite Chromized Layer on H13 Tool Steel

(整期优先)网络出版时间:2005-02-12
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Lowtemperaturecompositechromizingisaprocesscomposedofaplainion-carbonitridingorion-nitridingat550~580℃,followedbyalow-temperaturechromizinginasalt-bathof590℃.ThemicrostructureandpropertiesofthelowtemperaturecompositechromizedlayeronH13toolsteelwereinvestigatedusingmetallography,X-raydiffraction,microanalysis,hardnessandweartests.Itwasfoundthatthislowtemperatureprocesswasthermodynamicallyandkineticallypossible,andthecompositechromizedlayeronH13steel,withathicknessof3~6μm,consistedofthreesub-layers(bands),viz.theouterCr-richone,theintermediate(black)one,andtheinner,originalwhitelayer.Afterchromizing,theformerdiffusionlayerwasthickened.TheresultsofX-raydiffractionshowedthatthecompositechromizedlayercontainedsuchnitridesandcarbidesofchromiumasCrN,Cr2N,(Cr,Fe)23C6,and(Cr,Fe)7C3,aswellasplainα-(Fe,Cr).Ahighsurfacemicrohardnessof1450~1550HV0.025,whichismuchhigherthanthatobtainedbytheconventionalioncarbonitridingandionnitriding,wasobtained.Inaddition,anexcellentwearresistancewasgainedonthecompositechromizedlayer.