High Accuracy Calculation for Excited-State Energies of H Atoms in a Magnetic Field

(整期优先)网络出版时间:2009-08-18
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Usingtherecentlydevelopedfinite-basis-setmethodwithBsplines,excitedstatesofHatomsinamagneticfieldhavebeencalculated.Energylevelsarepresentedforthetenexcitedstates,2s_0,3d′_0,3p_0,3d_(-1),3d_(-1),4d_(-1),3d_(-2),4d_(-2),4f_(-2),and5f_(-2)asafunctionofmagneticfieldstrengthswitharangefromzeroupto2.35×10~6T.Theobtainedresultsarecomparedwithavailablehighaccuracytheoreticaldatareportedintheliteratureandfoundtobeinexcellentagreement.Thecomparisonalsoshowsthatthecurrentmethodcanproduceenergylevelswithanaccuracyhigherthantheexistinghighaccuracymethod[Phys.Rev.A54(1996)287].Herehighaccuracyenergylevelsareforthefirsttimereportedforthe3d′_0,4d_(-1),4d_(-2),4f_(-2),and5f_(-2)states.