Crystallization Behavior and Mechanical Properties of Poly(vinylidene fluoride)/multi-walled Carbon Nanotube Nanocomposites

(整期优先)网络出版时间:2010-03-13
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Poly(vinylidenefluoride)(PVDF)/multi-walledcarbonnanotube(MWCNT)nanocompositeswerepreparedbymeansofultrasonicdispersionmethod.X-raydiffraction(XRD)resultsindicatethatincorporatingMWCNTsintoPVDFcausedtheformationofβphase.Athermalannealingat130°Cconfirmedthattheβphasewasstableinthenanocomposites.Differentialscanningcalorimetry(DSC)resultsindicatethatthemeltingtemperatureslightlyincreasedwhiletheheatoffusionmarkedlydecreasedwithincreasingMWCNTcontent.ThetensilestrengthandmodulusofPVDFwereimprovedbyloadingtheMWCNTs.Thescanningelectronmicroscopy(SEM)observationsshowedthatMWCNTswereuniformlydispersedinthePVDFmatrixandaninterfacialadhesionbetweenMWCNTandPVDFwasachieved,whichwasresponsiblefortheenhancementinthetensilestrengthandmodulusofPVDF.