简介:Cr2O3-formingferriticstainlesssteelshavebeenwidelyexploredasintermediatetemperaturesolidoxidefuelcells(SOFCs)interconnects.However,theevaporationofchromiascalemightmigratetoandpoisonthecathode,leadingtodegradationofthecellperformance.Inthisstudy,Ni-Co-Fe-Pcoatingsweredepositedontheferriticstainlesssteelbymeansofacost-effectivetechniqueofelectrolessmethod.Theyareexpectedtobeconvertedinto(Ni,Co,Fe)3O4spinelwithahighelectricalconductivityandCTEmatchwithstainlesssteel,whichcanblocktheevaporationofchromiaformedonsteelsubstrateexposedtothecathodeenvironmentoftheSOFC.TheeffectsofpH,massratioofFeSO4/(FeSO4+NiSO4+CoSO4)andtemperatureofsolutiononthedepositionrate,compositions,surfacemorphologiesandstructuresoftheNi-Co-Fe-Pcoatingswereinvestigated.TheresultsindicatedthatthedepositionrateincreasedwithincreasingpHwhenpHwaslowerthan9andthenreducedwhenpHwashigherthan9.Thedepositionrateincreasedwithincreasingtemperaturewhentemperaturewaslowerthan80℃andthendecreasedwhentemperaturewashigherthan80℃.ThedepositionratedecreasedwiththeincreaseinmassratioofFeSO4/(NiSO4+CoSO4+FeSO4).ThecoatingsconsistedofNi,Co,FeandP.Thephasestructureofthecoatingwasamorphous.
简介:利用扫描电子显微镜、能谱仪、光学显微镜及电子探针等对比分析了Q235B钢板拉伸试验后出现分层和不分层的两组试样,研究引起钢板拉伸分层的原因。试验结果表明:分层试样中心含有大量的MnS、Si02等夹杂,心部存在宽大的铁素体条带,是导致Q235B铜板出现拉伸分层现象的主要原因。根据分析结果提出改进措施以减少和消除此种缺陷。
简介:Traditionally,austeniticstainlesssteels304and316havebeenemployedincoastalregionsasroofingmaterialsunfortunately,theyareexpensiveandnotfullyresistanttopittingcorrosionunderseverecoastalcorrosiveenvironment.AferriticstainlesssteelB445Rwasdeveloped.Comparedwithaustenitic316L,B445Ris①lesscostly;②uperiorcorrosionresistantwithminormaintenanceforlong-termservice;③insusceptibletothermaldistortionintheweldingseam.B445Rsheetshowsahigheryieldstrengthandlowertensilestrength,lowerelongationandlowerwork-hardeningthanaustenitic316L.Itcanbeeasilyfabricatedanddeformedjustlikeplaincarbonsteel.Afterbending180o,thereisnooccurrenceof'cracking'ornoticeable'orangepeel'.Theformabilityoftheweldingseamisalsosatisfactory.ThepittingpotentialofB445Ris650mV,largerthanthatof304and316L,asshowninFig.1.ThecorrosionrateofB445Rsubmergedin6%FeCl,solutionis0.3-0.56g/(m2?h-1),muchlowerthanthatof316L,asshowninFig.2.ThesuperiorpittingcorrosionresistanceofB445RcanbeascribedtosynergeticeffectofhigherCrandMo.Dull-finishedB445RsheetshavebeenemployedastheroofingmaterialsforGuangzhouAsianGamesArena,asshowninFig.3.About380tof1.0mmB445Rwithdullfinishwasusedforroofingpanels.About100tof0.8mmB445Rwithhairlineorfluororesinpaintfinishwasusedforsidewallpanels.Thecompositeroofbuild-up(fromuptobottom)includes:①shinglesofferriticstainlesssteelB445R;②Kalzip-typestandingseamofaustenitic304;③water-proofDFM;④structuralsteel;⑤75mmthickinsulation;⑥secondarypurlinof150mm×100mm×4.5mmofgalvaniziedQ235;⑦0.8mmthickprofiledeckofgalvaniziedQ235;⑧acousticinsulation.Theroofingshinglesorpanelswiththesamewidthbutdifferentlengthwereformedbybendingfoursidesandfixedtoa'L'shapereinforcingframesofstainlesssteelbyfasteners.The'L'frameswasconnectedtoribsofthestandingseambyacl
简介:Basedontheeffectsofseveralcastingparametersonslagentrapmentinthemould(watermodeling),thenumericalmodelingwasresearched.Theresultsshowthattheflowfieldwithasubmergednozzlesectiondimensionof65mm×80mmisbetterthanthatwithasubmergednozzlesectiondimensionof40mm×40mmandisfavorableforavoidingslagentrapment.Inthispaper,lowsurfacevelocity,smalllevelfluctuationandproperimpactdepthcanbeachievedwithanozzleofanoutletangleof25°andanimmersiondepthof150mm,orwithaprototypenozzleofanoutletangleof15°angleandanimmersiondepthof150mm.
简介:Themorphologyandtheevolutionofδ-ferriteexistinginB410Dslabs,hot-rolledplates,annealedplatesandquenchedplateswerestudiedthroughmetallographicobservation.Resultsshowthatδ-ferriteformsduringthesolidificationprocessandthatiteasilygrowsandincreasesinquantityduringhightemperatureannealing.Band-shapedδ-ferriteinhotrolledplatesisdifficulttobeeliminatedbyconventionalheattreatmentandhardtorecrystallize.
简介:Thedull-finishferriticstainlesssteel(FSS)sheetB445RforarchitecturalroofinghasbeendevelopedbyBaosteel.ThissteelproductexhibitsexcellentcorrosionresistancesuperiortothatofSUS316Lwithalowercost.Itcanbeeasilyformedintoroofingpanelsbyordinaryprocesses.Moreover,thethermalstrainofitislessthanSUS316Lbecauseofitslowerthermalexpansioncoefficient,anditsreflectivityislowerduetothedull-finishtreatment.Allofthesefeaturesmakeitcapableofbeingusedasarchitecturalroofingmaterialsincoastalregions.