简介：Inordertopredictthemechanicalperformanceofthepolyvinylchloride(PVC)atahighoperatingtemperature,aseriesofshort-termtensilecreeptests(onetenthofthephysicalagingtime)ofthePVCarecarriedoutat63Cwithasmallconstantstressbyadynamicmechanicalanalyzer(DMA).TheStruik-Kohlrausch(SK)formulaandStruikshiftingmethodsareusedtodescribethesecreepdataforvariousphysicalagingtime.AnewphenomenologicalmodelbasedonthemultiplerelaxationmechanismsofanamorphouspolymerisdevelopedtoquantitativelycharacterizetheSKparameters(theinitialcreepcompliance,thecharacteristicretardationtime,andtheshapefactor)determinedbytheagingtime.ItisshownthatthemomentarycreepcompliancecurveofthePVCat63CcanbeverywellfittedbytheSKformulaforeachagingtime.However,theSKparametersforthecreepcurvesarenotconstantduringtheagingprocessattheelevatedtemperatures,andtheevolutionoftheseparametersandthecreeprateversusagingtimecurvesatthedoublelogarithmiccoordinateshaveshownanonlinearphenomenon.Moreover,thecreepmastercurvesobtainedbythesuperpositionwiththeStruikshiftingmethodsareunsatisfactoryinsuchacase.Finally,thepredictedresultscalculatedfromthepresentmodelincorporatingwiththeSKformulaareinexcellentagreementwiththecreepexperimentaldataforthePVCisothermallyagedatthetemperaturerelativelyclosetotheglasstransitiontemperature.

简介：U-shapedmicro-nanochannelscangeneratesignificantflowdisturbanceaswellaslocallyamplifiedelectricfield,whichgivesitselfpotentialtobemicrofluidicmixers,electrokineticpumps,andevencelllysisprocess.NumericalsimulationisutilizedinthisworktostudythehiddencharacteristicsoftheU-shapedmicro-nanochannelsystem,andtheeffectsofkeycontrollingparameters(theexternalvoltageandpressure)onthedeviceoutputmetrics(current,maximumvaluesofelectricfield,shearstressandflowvelocity)wereevaluated.Alargeportionofcurrentflowingthroughthewholesystemgoesthroughthenanochannels,ratherthanthemiddlepartofthemicrochannel,withitsvalueincreasinglinearlywiththeincreaseofvoltage.Duetothelocaliondepletionnearmicro-nanofluidicjunction,significantlyenhancedelectricfield(asmuchas15foldatV=1VandP0=0)aswellasstrongshearstress(leadingtoelectrokineticflow)isgenerated.Withincreasingexternalpressure,bothelectricfieldandshearstresscanbeincreasedinitially(duetoshorteningofdepletionregionlength),butaresuppressedeventuallyathigherpressureduetothedestructionofiondepletionlayer.Insightsgainedfromthisstudycouldbeusefulfordesigningnonlinearelectrokineticpumpsandothersystems.

简介：ThisisoneoftheapplicationsofPart(Ⅰ),inwhichtheangularstiffness,andthecorrespondingstressdistributionsofU-shapedbellowswerediscussed.Thebellowswasdividedintoprotrudingsections,concavesectionsandringplatesforthecalculationthatthegeneralsolution(Ⅰ)withitsreducedformtoringplateswereusedrespectively,butthecontinuityofthesurfacestressesandthemeridianrotationsateachjointofthesectionswereentirelysatisfied.Thepresentresultswerecomparedwiththoseoftheslenderringshellsolutionproposedearlierbytheauthors,thestandardsoftheExpansionJointManufacturersAssociation(EJMA),theexperimentandthefiniteelementmethod.Itisshownthatthegoverningequationandthegeneralsolution(Ⅰ)areveryeffective.

简介：Thispaperfollowstheworkof[1,2].Therearesomeprogressindealingwithmoderatelysmallrotations(thesquaresofrotationanglesaretheorderofmagnitudeofstrains)ofmiddlesurfacenormalsofinsideandoutsideringshellsandcompressedangleofbellows.Calculationresultsagreewithexperimentswell.Tobellowdesign,themethodgiveninthispaperisofpracticalvalueandthediscussionoftheinfluenceofcompressedangleoncharacteristicrelationishelpful.

简介：可调谐二极管激光吸收光谱技术是一种非接触的光谱诊断技术,已经广泛应用于高温气动研究中.文章对吸收光谱的发展和应用于高温反应环境温度和组分浓度的测量进行了回顾.对不同的吸收测量策略以及相应的系统组成进行了详细介绍,最后介绍了应用吸收光谱技术研究超声速燃烧火星再入以及空间推进系统的详细结果.

简介：激波作为气体动力学最具特色的基本物理现象之一。表现出强间断与非线性的物理特征.激波能够在超/高超声速气流内部诱导漩涡,生产复杂的气体物理过程;激波能够诱导热化学反应,构成了高温气体力学和凝聚态爆轰动力学的学科基础;激波还能够压缩可燃气体实现其自点火,形成能够以超声速自持传播的燃烧反应带;而激波管则是一种广泛应用的实验技术,发展前途是无限的.

简介：针对甲酸乙酯(H(CO)OCH2CH3)与羟基自由基(OH)的反应动力学展开了理论与实验研究.在理论方面,首先通过量化计算得到了在M06-2x/ma-TZVP水平下准确的反应势能面,随后利用多结构-扭转(multi-stucturetorsionMS-T)方法对转动非谐效应进行了研究,获得了非谐校正系数,最后基于传统过渡态理论并考虑Eckart隧穿效应获得了200~2000K温度范围的反应速率常数.在实验方面,开展了激波管实验来测定H(CO)OCH2CH3与OH的反应速率常数,基于激光吸收光谱技术探测OH自由基306.7nm的吸收线,并对反射激波后高温反应过程的OH浓度变化进行测量,从而获得了900~1321K温度范围的反应速率常数,并论证了理论计算结果的合理性与准确性.