简介:Non-transferreddcarcplasmageneratorsarewidelyusedinmaterialsprocessing.Theyaregenerallyconsideredsteadily-operatingdevises.However,unsteadyphenomenadoexistinthem,andmaycausenon-idealeffectsinprocesseswhichrequirehighcontrollabilityandreproducibility.Theseunsteadyphenomenacancauseparameterfluctuationsinthearcandtheplasmajet,someofwhichhavebeenstudiedinrecentyears.Severaltypesandmechanismsofthesephenomenahavebeenidentified.Thispaperreviewst...
简介:Yttria-stabilizecl-zirconia(YSZ)hollowspheresarewidelyutilizedfortheirnovelphysicalandchemicalproperties.However,developingasimpleandlow-costmethodforpreparingsuchhollowspheresstillremainsagreatchallenge.Inthispaper,anatmosphericplasmaspray(APS)methodisintroduced,andtheformationmechanismofhollow7YSZ(ZrO2-7wt%Y2O3)spheresispresented.Thehollowspheremorphologywasobservedbyscanningelectronmicroscopy(SEM)whenagglomeratedandsintered7YSZpowderswereused.Additionally,additivecompositionchanges,phasetransformations,andthethermalbehaviorof7YSZpowderswereanalyzedbyenergydispersivespectroscopy(EDS),X-raydiffractometry(XRD),thermogravimetricanalysis(TG)anddifferentialscanningcalorimeteranalysis(DSC).Furthermore,thephasetransformationsofagglomeratedandsintered7YSZpowders,7YSZhollowspheresthatannealedatvarioustemperaturesfordifferenttimesareanalyzed.
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简介:Siliconnitridenanoparticlesweresynthesizedbyradio-frequency(RF)plasmachemicalvapordeposition(PCVD)usingsilicontetrachlorideandammoniaasprecursors,andargonascarriergas.Byassumingchemicalthermodynamicequilibriuminthesystem,acomputerprogrambasedonchemicalthermodynamicswasusedtocalculatethecompositionsofthesystematdifferentinitialconcentrationsandfinaltemperatures.Atfirst,fiveelementsandthirty-fourspecieswereconsidered.Theeffectsoftemperatures,andconcentrationsofammonia,hydrogenandnitrogenontheequilibriumcompositionswereanalyzed.Itwasfoundthattheoptimalreactiontemperaturerangeshouldbe1200to1500KtoobtainthehighestconversionandyieldofSi3N4.Theinletpositionofammoniashouldbelowerthanthatofsilicontetrachloride,andbothshouldbelocatedatthetailoftheplasmatorch.Thebestmoleratioofammoniatosilicontetrachloridewasfoundtobeabout6.Later,theinfluencesofwater(andoxygen)wereconsidered,and17additionalspecieswereincludedinthecomputations.ItwasfoundthatoxygenorwatercontentintherawmaterialsshouldbeaslowaspossibleinordertohavehighnitridecontentintheproducedSi3N4.Nitrogenorhydrogenmightbeusedtoreplacesomeorevenalltheargontoimprovetheyieldofsiliconnitrideandreducethecost.Theratioofammoniatosilicontetrachlorideshouldbehighenoughtoobtainhighconversion,butnotexcessivelyhightoreducetheoxygencontentduetotheexistenceofwaterinammonia.Thesimulatedresultswereverifiedbyexperiments.
简介:Lithium-aluminum-cobalt-nickeloxideLiAlxCoyNi1xyO2particles,generallyusedascathodeoflithiumbattery,werepreparedbychemicalcoprecipitationfromanaqueoussolutionofLiOH,Al(NO3)3,Co(NO3)2andNi(NO3)2withNH4OH.XRD,SEMandFTIRwereusedtoexaminetheeffectofnickelcontentontheproduct.FTIRpatternsshowedthatincreaseinnickelcontentdecreasedtheabsorptionstrengthofthepeakofspinelstructureoftheproduct,attributedtotheoccupationbynickelinthealuminumsites.Particlesizeandelectricalpropertiesofthelithium-aluminum-cobalt-nickeloxide(abbreviatedasLACNO)particleswerealsodetermined.
简介:The(2+1)-dimensionalBKPequationintheHirotabilinearformisstudiedduringthiswork.WronskianandGrammiantechniquesareappliedtotheconstructionofWronskianandGrammiansolutionsofthisequation,respectively.ItisshownthatthesesolutionscanbeexpressedasnotonlyPfaffiansbutalsoWronskiansandGrammians.
简介:The1/3subharmonicsolutionfortheDuffing'sequationisinvestigatedbyusingthemethodsofharmonicbalanceandnumericalintegration.Thesensitivityofparametervariationforthetransientprocessandthetransientprocessfortheperturbanceinitialconditionsarestudied.Overandabove,theprecisionofnumericalintegrationmethodisdiscussedandthenumericalintegrationmethodiscomparedwiththeharmonicbalancemethod.Finally,asymptoticalstabilityofthepuresubharmonicoscillationselementisinspected.
简介:Inthispaper,ahigh-orderfinite-volumeschemeispresentedfortheone-dimensionalscalarandinviscidEulerconservationlaws.TheSimpson’squadratureruleisusedtoachievehigh-orderaccuracyintime.TogetthepointvalueoftheSimpson’squadrature,thecharacteristictheoryisusedtoobtainthepositionsofthegridpointsateachsub-timestagealongthecharacteristiccurves,andthethird-orderandfifth-ordercentralweightedessentiallynon-oscillatory(CWENO)reconstructionisadoptedtoestimatethecellpointvalues.Severalstandardone-dimensionalexamplesareusedtoverifythehigh-orderaccuracy,convergenceandcapabilityofcapturingshock.
简介:在现在的纸,包含三个任意的函数为的一个一般解决方案概括(2+1)维的KdV-mKdV方程,它被导出从概括(1+1)维的KdV-mKdV方程,首先借助于Wiess被介绍,小鼓,Carnevale(WTC)截断方法。然后有考虑的几条能量守恒定律的multisymplectic明确的表达被介绍为概括(2+1)维的KdV-mKdV方程基于桥的multisymplectic理论。随后,源于以便以Jacobi椭圆形的功能的合理功能模仿周期的波浪答案一般答案,一个半含蓄的multi-symplectic计划被构造那等价于Preissmann计划。从数字实验的结果,我们能断定multi-symplectic计划能精确地模仿周期的波浪答案概括(2+1)维的KdV-mKdV方程当时近似保存能量守恒定律。
简介:AhighlyefficientH1-Galerkinmixedfiniteelementmethod(MFEM)ispresentedwithlineartriangularelementfortheparabolicintegro-differentialequation.Firstly,somenewresultsabouttheintegralestimationandasymptoticexpansionsarestudied.Then,thesuperconvergenceoforderO(h2)forboththeoriginalvariableuinH1(π)normandthefluxp=uinH(div,π)normisderivedthroughtheinterpolationpostprocessingtechnique.Furthermore,withthehelpoftheasymptoticexpansionsandasuitableauxiliaryproblem,theextrapolationsolutionswithaccuracyO(h3)areobtainedfortheabovetwovariables.Finally,somenumericalresultsareprovidedtoconfirmvalidityofthetheoreticalanalysisandexcellentperformanceoftheproposedmethod.
简介:针对1点RANSAC(RandomSampleConsensus)单目视觉EKF(ExtendedKalmanFilter)算法中的滤波发散问题,分析了滤波发散的产生原因,提出了一种基于渐消记忆滤波的1点RANSAC单目视觉姿态估计算法。该算法通过在EKF滤波方程中引入加权因子,逐渐加大当前数据的权重,相应地减少旧数据的权重,有效地扼制了算法中的滤波发散问题。最后通过两组验证性实验验证说明了算法的有效性。实验结果表明:该算法能够有效地解决1点RANSAC单目视觉EKF算法中的滤波发散问题,具有更高的精度。第一组双轴联动实验,航向角的平均误差减小2.4158?,俯仰角平均误差减小0.1782?;第二组偏航轴大角度转动实验,摄像机航向角的估计误差一直保持在1.5?以内。
简介:Perovskite-typeLa1-xCexMnO3(x=0-10%)catalystswerepreparedbyflamespraypyrolysisandtheiractivitiesduringthecatalyticoxidationofbenzenewereexaminedoverthetemperaturerangeof100-450℃.ThestructuralpropertiesandreducibilityofthesematerialswerealsocharacterizedbyX-raydiffraction(XRD),N2adsorption/desorption,H2temperature-programmedreduction(H2-TPR)andX-rayphotoelectronspectroscopy(XPS).TheincorporationofCewasfoundtoimprovethebenzeneoxidationactivity,andtheperovskiteinwhichxwas0.1exhibitedthehighestactivity.Phasecompositionandsurfaceelementalanalysesindicatedthatnon-stoichiometriccompoundswerepresent.TheincorporationofCehadanegligibleeffectonthespecificsurfaceareaoftheperovskitesandhencethisfactorhaslittleimpactonthecatalyticactivity.IntroductionofCe44+resultedinmodificationofthechemicalstatesofbothB-siteionsandoxygenspeciesandfacilitatedthereducibilityoftheperovskite.ThesurfaceMn4+/Mn3+ratiowasincreasedasaresultofCe4+substitution,whileadecreaseinthesurface-adsorbedO/latticeO(Oads/Olatt)ratiowasobserved.Therelationshipbetweenthesurfaceelementalratiosandcatalyticactivitywasestablishedtoallowabetterunderstandingoftheprocessbywhichbenzeneisoxidizedoverperovskites.
简介:阴极材料李[CoxNiyMn1?x?y]为锂的O2第二等的电池被一条新线路作为一位先锋用分层的双氢氧化物(LDH)准备了。结果有-NaFeO2结构的分层的阶段在菱形的系统结晶,与有到0.47nm的夹层间距结束的空格组R-3m。X光检查光电子光谱学(XPS)被用来测量公司,Ni和Mn的氧化状态。在结构和李的电气化学的性质上改变Co/Ni/Mn比率的效果[CoxNiyMn1?x?y]O2被X光检查衍射和电气化学的测试调查了。产品表明了相当稳定的骑车行为,与为有Co/Ni/Mn=1/1/1的分层的材料的118mAh/g的一个可逆能力。
简介:立方星的姿态测量与控制系统常采用磁测磁控结合偏置动量轮的方案,整星剩磁干扰力矩是影响姿态控制精度的重要因素之一。提出了一种利用磁强计实现剩磁矩在轨辨识与利用磁力矩器实现剩磁矩主动补偿的新方案:基于磁强计输出和卫星姿态动力学建立了剩磁矩在轨辨识模型,并利用采样滤波器(UKF)提高单磁强计条件下的辨识效果;把控制对象简化成线性定常系统,分析了剩磁干扰力矩对姿态的影响数学模型,并针对磁力矩器和磁强计分时工作的特点,基于叠加性原理提出了基于角速度的剩磁矩主动补偿算法。仿真研究表明,在1000s内剩磁矩在轨辨识精度为0.001A×m~2量级,主动补偿后,偏航角、滚动角与俯仰角控制误差分别从4.3°、4.6°与2.1°均减少至0.4°以内。提出的方法为类似配置卫星减少剩磁干扰力矩的影响提供了一种新思路。