简介：Reactionofglycinewithphosphorustrichlorideinpresenceoftriethylaminehasurnishedtheovelspirohydridophosphorane.Itsstructurehasbeencharacterizedbyelementalanalysis,n.m.r.spectraandmassspectrum.Thecompoundreactedwithphenylisothiocyanatetogive2-phenyliminothiazolid-5-one.

简介：Twoseriesofnovelspiropyranderivativescontainingamesogenicgrouphavebeenprepared.Theirphotochromicbehaviorswerefirstinvestigatedwiththeaidofabsorptionspectralmeasurements.

简介：在氧气体的处理以后，包含胺组的小分子能射出荧光。氧化被相信在荧光中心的形成起一个重要作用。比作以前的结果，小分子和大分子可能有一样的荧光中心。

简介：TheNb-bromomethylderivative（2）ofgelsemine,aquaternaryammoniumsalt,wasfoundtoberecalcitranttowardHofmanntypealkalinedegradationwhichhasbeensuccessfulinothercases.Instead,are-distributionoftheN-methylgrouptookplace,givingriseto3a,1,3band3c,indescendingorderofRfvalues.

简介：Sixnewcompounds,α,β-KaHb[GeW9M3(H2O)3O37].xH2O(M=Al,Ga,In;a+b=7)andα-K9H5[Ge2W18Ga6(H2O)3O74].20H2O,weresynthesizedfromthelacunaryprecursorsαandβ-GeW9O3410-andcharacterizedbyelementalanalysis,spectroscopyandelectrochemistry.Tungsten-183NMRspectraofthetitlecomplexesconsistoftwolineswithintensityratio2:1asexpectedfortrisubstitutedheteropolyanions.Theintensityratioofα-Gacompoundis1:2,whichisdifferentfromothers(2:1).WiththehelpofFABmassspectrum,weconcludedthatitisadimerwithD3h,structureinaqueous,andtheothersexistbymonomerswithC3cstructures.

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简介：TheelectrochemicalformationofMg-LialloyswasinvestigatedinamoltenLiCl-KCl(58-42mol%)eutecticmeltat723K.ThecyclicvoltammogramforaMoelectrodeshowedthattheelectroreductionofLi~+proceedsinasinglestepandthedepositionpotentialofLimetalwas-2.40V(vs.Ag/AgCl).ForMgelectrode,theelectroreductionofLi~+takesplaceatlesscathodicpotentialthanthatattheMoelectrodewhichwascausedbytheformationofMg-Lialloys.PhaseofthedepositedMg-Lialloyscouldbecontrolledbytheelectrolysispotential,andthesampleswerecharacterizedbyX-raydiffractionandscanningelectronmicroscopy.Theresultsshowedthatα-Mgandβ-Liphaseswereobtainedat-2.35and-2.55V,respectively.

简介：Itwasfoundthatphosphorylationofsmallpeptidecouldimprovethesensitivityinmassspectrometry.DensityfunctionaltheorycalculationsshowedthattheenergyfortheprotonationofN-(O,O′-dimethyl)phosphorylglycylglycineislowerthanthatofglycylglycine.Thesecouldhelptounderstandingtheexperimentalresults.

简介：ＳＴＵＤＩＥＳＯＮＨＥＴＥＲＯＭＡＣＲＯＣＹＣＬＩＣＰＯＬＹＥＴＨＥＲ（ＸＩＶ）ＴＨＥＳＹＮＴＨＥＳＩＳＯＦＳＥＬＥＮＡＣＲＯＷＮＥＴＨＥＲＷＩＴＨＨＹＤＲＯＸＹＧＲＯＵＰＡＮＤＤＩＳＥＬＥＮＡ－ＡＺＡ－ＣＲＯＷＮＥＴＨＥＲＨａｎＳｈｅｎｇＸｕ；Ｊｕ...

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简介：Arapidandeffectivemethod,solidphaseextractioncoupledwithhighperformanceliquidchromatography(SPE-HPLC),wasappliedtotheseparationandanalysisofginsenosides.WatersOASISHLBwasusedforconcentratingandpurifyingsamplesandAlltimaC_(18)(53mm×7mm,3μm)chromatographycolumnwasusedforseparatingginsenosideRg_1,Re,Rb_1,Rc,Rb_2andRd.Theseginsenosideswereanalyzedwithin20mininourgradientelutionprocessandtheequilibriumtimeofthechromatographycolumncostonly5min.Moreover,therewasnoobviousbaselinedriftinourexperiment.Thismethodwasusedtoanalyzethecontentsofginsenosidesindifferentginsengproductsforqualitycontrol.Fourginsengproductswerestudied,includingtwokindsofcapsules,onekindoftabletandonekindofinjection.Theresultsshowthatthemethoddevelopedinthispaperhadgoodaccuracy,linearityandprecision.Therefore,thismethodcouldbeappliedinqualitycontrolofginsengproducts.

简介：TwospeciesofN-arylpyrazolescontainingactiveaminogroupweresynthesized.AndformylationsofN-arylpyazolescontainingaminoindifferentpositionofpyrazoleringsusingVilsmeier-Haackreactiongaveaseriesofusefulpyrazoleintermediates.Theimportantfeaturesofthisprotocolwerecheapmaterials,easyprocess,mildreactionconditionsandgoodyieldofproducts.

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简介：ＴＨＥＲＥＡＣＴＩＯＮＯＦｐ－ＮＩＴＲＯＰＨＥＮＹＬＳＵＬＦＯＮＹＬＡＣＥＴＯＮＩＴＲＩＬＥＷＩＴＨα，β－ＵＮＳＡＴＵＲＡＴＥＤＥＳＴＥＲＳＡＮＤＮＩＴＲＩＬＥＳ￥ＧｕｏＲｅｎＹＵＥａｎｄＺｈｅｎｇＺｈａｎｇ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔ...

简介：Amain-chainliquidcrystallineionomer(MLCI)containingsulfonicgroupwassynthesizedbyaninterfacialcondensationreaction.TheMLCIwasblendedwithpolybutyleneterephthalate(PBT)andpolypropylene(PP).MLCIinteractedwithboththedispersed(PP)phaseandthematrix(PBT)phasetomodifytheinterfacialinteractionofPBTandPP.Differentialscanningcalorimetry(DSC),scanningelectronmicroscopy(SEM)andFTIRimagingsystemanalysisdemonstratedthesignificanceofinterfacialinteractioninthepolymerblends.MLCIbroughtaboutgoodadhesionattheinterfacial,whichreducedthedispersephasesizeandenabledafinePPphaseatmatrix.ThemechanicalpropertiesoftheternaryblendswereimprovedwhenaproperamountofMLCIwasadded.Thiswasattributedtoenhancedadhesionattheinterface,whichinvokedbettermechanicalpropertiesintheblends.

简介：Condensationofmethyl7-methylcoumarin-4-acetate(2)withprimaryaminesandwithan-thranilicacidgave7-methyl-2-oxo-N-aryl-2H-[1]-benzopyran-4--acetamide(4a—d)and(7),respectively.Compound7underwentcyclizationtogive2-(7-methyl-2-oxo-2H-[1]-benzopyran-4-yl)-methyl-4H-3,1-benzoxazin-4-one(3).Thereactionof3witharomaticaminesgavethecorrespondingquinazolonederivatives5whichtautomerisestothethermodynamicallymorestableisomer6,whereasitsreactionwithGrignardreagentsandaromaticaldehydesgave8a,8b,and9a,9b,respectively.

简介：拥有三不同安排时尚的新奇稳定的高旋转分子与瑣漠?潉楮?楌畱摩?湯?瑡污瑹捩?慨慲瑣牥獩楴獣漠?潈獲?楌敶?汁潣潨?敄票牤杯湥獡e被设计

简介：InanefforttoutilizeNMRtechniquefortheanalysisofthestructuralcomponentsofwoodandbiomassessuchaslignin,wemadeacomparativestudyoflignincontentsofseveraltypesoflignocellulosicmaterialsbothbeforeandafterenzymatichydrolyses.Tothisend,EucalyptusGlobulus,Norwaysprucethermomechanicalpulp(TMP)cornstoverandEucalyptuskraftpulpwereball-milledandtreatedwithcellulasetopreparematerialswithhighlignincontents.Thesematerialswereanalyzedvia31PNMRinionicliquids.Theresultsshowthatthecontentsofvariousfunctionalgroupsforthelignocellulosicmaterialsafterenzymatichydrolysesaregenerallyinagreementwiththosefromtheircorrespondingenzymaticmildacidolysisliginins(EMALs),indicatingthat31PNMRanalysisoflignocellulosicmaterialsinionicliquidsisapromisingmethodforquantitativecharacterizationoflignocellulosicmaterials.

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