简介:Er^3+-dopedSrBi4Ti4O15-Bi4Ti3O12(SBT-BIT-xEr^3+,x=0.00,0.05,0.10,0.15and0.20)inter-growthceramicsweresynthesizedbythesolid-statereactionmethod.Structural,electricalandup-conversionpropertiesofSBT-BIT-xEr^3+wereinvestigated.Allsamplesshowedasinglephaseoftheorthorhombicstructure.RamanspectroscopyindicatedthattheEr^3+substitutionforBi^3+atAsitesofthepseudo-perovskitelayerincreasesthelatticedistortionofSBT-BIT-xEr^3+ceramics.ThesubstitutionofBi^3+byEr^3+leadstoadecreaseofdielectriclosstanδandanincreaseofconductivityactivationenergy.Piezoelectricconstantd33wasslightlyimproved,butdielectricconstantwasdecreasedwiththeEr^3+doping.TheSBT-BIT-xEr^3+ceramicwithx=0.15exhibitstheoptimizedelectricalbehavior(d33~17pC/N,tanδ~0.83%).Moreover,twobrightgreen(532and548nm)andonered(670nm)emissionbandswereobservedunderthe980nmexcitation.Optimizedemissionintensitywasalsoobtainedwhenx=0.15fortheSBT-BIT-xEr^3+ceramic.Therefore,thiskindofceramicsoughttobepromisingcandidatesformultifunctionaloptoelectronicapplications.
简介:Na5+xYAlxSi4-xO12superionicconductorsarerhombohedralR3cspacegroup.Theirstructuresarecharacterizedby(Alx/4Si1-x/4)O4tetrahedralinkedtoformpuckered(Al3xSi4-x)4O35ringsparalleltothebasalplaneofthehexagonalcell.Theserings,separatedbypartsofsodiumoxygenpolyhedron,arestackedtoformlargerigidcolumsparalleltocaxis.Thecolumnsarelinkedby[YO6]octahedratoformathree-dimensionalFrameworkwithlargechannelsbetweentherings.PartsofNaionslocatedinthecoresofthecolumnsaremovable.Intermsoftheconductionmechanism,theconcentrationofconductingNa+ionswascarriedoutandcomparedwiththeexperimentalresults.Itwasfoundthatthetheoreticalvaluesaccordwiththeexperimentalresults.
简介:Withpositronannihilationradiationonedimensionangular-correlationdevice,itismeasuredthatpositronannihilationradiationonedimensionangular-correlationcurvesofpolycrystalsodiumionconductorNa5Y1-xCrxSi4O12(NYCS)system.Afterelectronmomentumdistributioncurvesarenormalized,linearparametersarecalculated.TheparametersH,WandSshowthechangeofNa+ionvacancyconcentrationinNYCSseriessamples.TheresultsshowthatparametersH,WandSofonedimensionangular-correlationcurvesofthosesamplesvarygreatlywithCr2O3contents.WithCr2O3contentincreasing,HandSparametersincrease,butWdecreases,andreachesextremesatx=0.05;thenwithCr203addingcontinually,parametersHandSdecreasegradually,parameterWincreasesgradually.Thisshowsthat,inaddtiontoCr2O3,theconductivityhascloserelation
简介:TechnologicalprocessofrareearthsealinganodizedLY12(2024)alloyisintroduced.Corrosionbehaviorofthefilmwasstudiedbypolarizationcurvesandelectrochemicalimpedancespectroscopy(EIS).Theresultsshowedthatthecoatingremainedpassivityatthepotentialrangefromtheopencircuitpotential(-780mV)to-250mVinNaClsolution.Whenthepotentialexceeded-200mV,corrosionreactionhappenedonthecoating.theresultsofElSanalysiswasconsistentwiththeresultsofpolarizationcurves.
简介:Themicrostructuralevolutionsofadvanced9-12%Crferrite/martensiteheat-resistantsteelsusedforpowergenerationplantsarereviewedinthisarticle.Despiteofthesmalldifferencesinchemicalcompositions,thesteelssharethesamemicrostructureoftheas-temperedmartensite.Itisthethermalstabilityoftheinitialmicrostructurethatmattersthecreepbehavioroftheseheat-resistantsteels.Themicrostructuralevolutionsinvolvedin9-12%Crferriteheat-resistantsteelsareelabo-rated,including(1)martensiticlathwidening,(2)disappearanceofprioraustenitegrainboundary,(3)emergenceofsubgrains,(4)coarseningofprecipitates,and(5)formationofnewprecipitates,suchasLaves-phaseandZ-phase.Theformerthreemicrostructuralevolutionscouldberetardedbyproperlydisposingthelattertwo.Namelyimprovingthestabilityofprecipitatesandoptimizingtheirsizedistributioncaneffectivelyexertthebeneficialinfluenceofprecipitatesonmicrostructures.Inthissense,themicrostructuralstabilityofthetemperedmartensiteisinfactthestabilityofprecipitatesduringthecreep.Manyattemptshavebeencarriedouttoimprovethemicrostructuralstabilityof9-12%Crsteelsandseveralpromisingheat-resistantsteelshavebeendeveloped.
简介:在电的运输性质上评估Ni替换的影响,p类型skutteruditesRyFe3NiSb12(R=Ba,Nd和Yb)系统地从2.5K被调查到800K。由小心地修改三fillers,Ba,Nd和Yb的充满的部分,搬运人集中精确被调整,它按比例改变到数统治的原子价计算的名字的价值。活动性和Seebeck系数的搬运人集中依赖表示在原子价乐队的二乐队贡献,和为热电的性能的优化搬运人集中在之间(5–9)×1020厘米−3。样品的热电导率用稀土元素的元素(Nd和Yb)填满的格子作为与相比显著地更低充满Ba,由于更低的反响的频率并且部分充满。与公司替换相比,Ni替换趋于关上乐队差距,它为RyFe3NiSb12。然而由于状态的密度的改进,当搬运人集中是类似的时,RyFe3NiSb12比RyFe2公司2在更低的温度范围的Sb12。0.73的ZT价值为Yb0.77Fe3在600K的NiSb12。
简介:四氧化四银(Tetrasilvertetxoxide,Ag4O4)是一种具有活跃电子、反磁性和半导电性的分子晶体,可与表面裸露的蛋白质-N基(-NH,-NH2)和-S基(S-S,-SH)发生热力学吸附并触发氧化还原反应,改变微生物蛋白质构象而起到抑菌效果,具有潜在应用价值。为了开发基于纳米高价银氧化物的生物医用材料,采用软化学方法制得Ag4O4,并利用扫描电镜、纳米粒度与电位分析仪、X射线衍射仪、热分析仪和激光显微拉曼光谱仪对其理化性质进行了表征,利用抑菌圈法和液体光电比浊法对其抗茵性能进行了评价。结果表明,实验制备的四氧化四银性质完全符合预期,抗茵性能优良,为进一步研制抗菌性能良好的医用材料提供了有益借鉴。