简介:ThispaperpresentstheeffectofmineralizationonchalcopyritechemicalleachinginverysimpleH2SO4solutionsystemsatpH1.0,with5%chalcopyriteconcentrateat65℃.Thecopperextractionsafter12daysleachingofmarinevolcanicandporphyrychalcopyritewere85.7and66.6%,respectively.ItwasfoundthatsulphurelementformedonthesurfaceoftwosamplesasaresultofXRDandSEM-EDAX,whichwasveryporousthatdidnotinhibitchemicalleachingreaction.Meanwhile,(Cu,Fe)12As4S13formedonthesurfaceofporphyrytypechalcopyrite,whichmaycauselowleachingratioofporphyrytypechalcopyriteaspassivation.(Cu,Fe)12As4S13maybeonekindofthepolysulphidecompounds.
简介:macroporous的吸着性质为La3+离子的弱酸树脂(D113)被化学分析和红外系列学习。试验性的结果显示D113树脂在pH=为La3+有一个好吸附能力6.0在HAc-NaAc媒介。静态地浸透的吸附能力是273.3mg/g。La3+/Ce3+,La3+/Gd3+,La3+/Er3+,和La3+/Y3+的分离系数分别地是2.29,3.64,4.27,和0.627。吸附的明显的激活精力,Ea是吸着的18.4kJ/mol,热力学参数H,S,和G是4.53kJ/mol,61.8J/(mol.K),?13.9kJ/mol分别地。为La3+的D113的吸附行为服从Freundlich等温线。在树脂上吸附的La3+能是由2.0mol/LHCl份量上的eluted。
简介:Themultilayered7XXXseriesaluminumalloywasimpactedby7.62mmogivalprojectilesatvelocitiesrangingfrom787to851m·s~(-1).Thedeformedmicrostructureundervariousimpactingvelocitiesandfracturesurfacesofdifferentsectionswereinvestigatedatdifferentphysicalscalestodeterminetheprocessoffailure.Opticalmicroscopy(OM),electronback-scattereddiffraction(EBSD)andscanningelectronmicroscopy(SEM)wereusedintheinvestigation.Theresultsshowthatcraterisconstrainedinthe7B52frontlayerandtwotypesofadiabaticshearbandswhicharetransformedbandsanddeformedbandsanddifferenttypesofcracksareobserved.Spallfractureisthesignificantfailuremodeof7B52frontlayer,andtheresultingdelaminationleadstothepresenceofbendingtensilefractureinsteadoftheshearplugging.Theductile7A01layerbluntsanddeflectsthespallcracktips,preventingthetargetsfromfullspall,andinducesaconstraintof7A52rearlayer.Theleveloftheconstraintdeterminesdifferentfracturemodesof7A52layer,accountingfortheasymmetryofdamage.
简介:Theflotabilityandmechanismofthecompositetantalite-niobitemineralswhichhavedifferentcontentoftheTa,Nb.Fe,Mnwithstyrenephosphonicacid(SPA)ascollectorareinvestigatedanddiscussed.Someimportantflotationparametersarefoundasfollows:SPAisabettercollectorforflotatingniobite-tantalitemineralthanother,theoptimumpHvalueinpulpislessthan5,theflotabilityofthosemineralsvarieswiththedifferentcontentofmineralcomposition,theflotabitityofthemineralswithhigherNb2O5contentisbetterthanthatwithhigherTa205content.HereweemphasizethatinwiderangeofpHinsolu-tiontheFe,Mnonthemineralsurfacesarethemainactivespeciesforflotationoftheseminerals.Inadditiontothis,someofre-searchworkbyusingAugerelectronspectroscopy,infraredspectroscopyandultravioletspectroscopyfordeterminingthesurfaceconditions,pretreatedbyacidornot,hasbeendone.ThecharacteristicsofadsorptionofSPAonthemineralsurfacesareexam-inedanddiscussed.ItisindicatedthattheSPAinteractswithFe,Mnionsonmineralsurfacesbythechemicalbondforce.Butonthewholeouterlayerofcollector,whichisnon-uniformmultilayer,itmaybesaidthattheadsorptionofSPAonthemineralsur-faceisbothchemico-adsorptionandphysico-adsorption,butthechemico-adsorptionispredominant.
简介:Al-5Ti-0.5C-8Sr(集体部分,%)主人合金用一个melt反应方法被准备。微观结构和主人合金的合成过程被光显微镜学,X光检查衍射,扫描电子显微镜学和X光检查调查精力散的光谱。结果证明主人合金由组成一(艾尔),TiAl3,TiC,Al4Sr和Al-Ti-Sr分阶段执行。主人合金的合成机制如下:TiAl3通过在K2TiF6和艾尔之间的反应被形成在基础材料的部分融化层融化在850个C粒子与同类地分布式的加强在超声的行动和一张契约下面被变成液体filler在团结以后被获得。体积部分原文如此,在契约的粒子能被改变以铜锌金焊接的温度改变。最大值原文如此,契约材料的粒子体积部分在brazi到达了37%?
简介:ByaddingmixtureofZrO2andcarbon,aZr-enhancedcompositecoatingwasproducedontoanAISI1045substratebylasercladding.Themicrostructureandphaseformation,microhardnessandwearresistanceofthecompositecoatingwerestudied.Theexperimentalresultsindicatethatthecompositecoatingwithmetallurgicalbondingtosubstrateconsistsof7-Ni,massiveceramicparticlesofZrC,NiZra,NiTZr〉(Fe,Ni)23C6andF%C.Theinsitu-synthesizedZrCparticlesareuniformlydispersedincompositecoating,whichrefinesthemicrostructureofcompositecoating.WithdifferentZrO2andcarbonaddi-tions,thepropertiesareimproveddifferently.Finally,thefineinsituZrCparticlesimprovethemicrohardnessofcompositecoatingtoHVo.2650,whichisnearly2.7timesthatofNi25coating.Also,thecompositecoatinghasanadvantageinwearresistance;itoffersbetterwearresis-tancewhenmoremixtureofZrO2andcarbonwasaddedinnickelalloys.
简介:Thecreepmechanismofas-castMg-6Al-6Ndalloywasstudied.Thestressexponentforcreepis5.8undertheappliedstressesof50-70MPaat175°C.Theactivationenergyforcreepis189kJ·mol-1undertheappliedstressof70MPaintherangeof150-200°C.Thetruestressexponentandthresholdstressforcreeparecalculatedas4.96and10.2MPa,respectively.Thetruestressexponentindicatesthatitscreepmechanismbelongstothedislocationclimb-controlledcreep,whichisinagreementwiththemicrostructurechangesbeforeandaftercreep.ThehighvalueforstressexponentisattributedtotheinteractionofAl11Nd3phasewithdislocations.Theactivationenergyismorethantheself-diffusionactivationenergyofMg,whichisattributedtotheloadtransfertakingplacefromthematrixtoAl11Nd3phaseduringcreep.
简介:Nb-bearingslagfromBaotouhotmetalwaschlorinatedinthesolidstatewithmoltenCaCl2undervacuum,96~98%MnOorFeObeingthusvolatilized.Byreducingthechloridizedresidueunderadditionofflux,ferroniobiumwithabout60%Nbwassuccessfullymade.KineticstudyofchlorinationofsyntheticMnO-Nb2O5-SiO2andFeO-Nb2O5-SiO2slagsystemswasconducted,andanon-reactingcoremodelforthedemanganificationwithfreeuseofactivitywasformulatedandtherate-controllingstepwasexplained.
简介:Anovelstar-likesingle-crystalZnOstructurewassynthesizedbyasimplesolvothermalmethod.Theas-preparedproductswerecharacterizedbyXRD,SEMandTEM.Thestar-likeZnO,whichshowssixfoldsymmetry,wasconstructedbysixuniformarmsdistributingsymmetricallyaroundthe[0001]zoneaxis.Itisalsofoundthatthearmsarenotperpendiculartothe[0001]zoneaxisandeacharmisgrownatacertainanglewiththe[0001]direction.CBEDpatternandcorrespondingsimulationdemonstratethattheconvexpartofthestar-likeZnOisO-terminated(000-1)planeandtheconcavepartisZn-terminated(0001)plane.H2Splaysacrucialroleinthesynthesisprocess.Theanisotropicgrowthhabitalong[0001]and[000-1]resultsintheformationofstar-likestructure.
简介:扔的near-liquidus准备的6061件半固体铝合金化工物品借助于Gleeble-3500热机械的模拟器处于半固体状态被压缩。在在不同温度和紧张率的真压力和真紧张之间的关系与70%的变丑度被学习。微观结构在变丑过程期间被描绘。半固体合金的变丑机制和形成thixo性质被分析。结果证明同类并且6061Al合金由扔技术的near-liquidus生产了的半固体的非树突微观结构能与对与通过再热的最容易溶解的作文在球形附近的谷物和液体阶段镇静的形成thixo合适的微观结构被转变成半固体状态过程。变丑温度和紧张率显著地影响山峰压力而非稳定流动应力。到处于半固体状态的变丑的抵抗随变丑温度的增加和紧张率的减少减少。在稳定的thixotropic变丑舞台,thixotropic性质是一致的,并且主要变丑机制是在稳固的粒子和稳固的粒子的塑料变丑之间旋转或滑动。
简介:ThecoercivitymechanismofNd-Fe-Bbasedmagnetspreparedbyanewtechniqueofstripcastingwasinvestigated.Differentfromthetraditionalmagnets,α-FephasesaredifficulttobefoundinNd-Fe-Bmagnetspreparedbystripcasting.Meanwhile,therich-Ndphasesoccurnotonlynearthegrainboundariesofmainphases,butalsowithinthemain-phasegrains.Investigationonthemagnetizingfielddependenceofthecoercivityforthe(Nd0.935Dy0.065)14.5Fe79.4B6.1magnetandthetemperaturedependenceofthecoercivityfortheNd14.5Fe79.4B6.1magnethavebeendone.Resultsshowthatcoercivitiesforstripcastingmagnetsarecontrolledbythenucleationmechanism.
简介:ElectrocrystallizationMechanismofTungsteninMoltenKF-B_2O_3-K_2WO_4WenZhenhuanandLiGuoxun文振环,李国勋(GeneralResearchInstiiuteforNo...
简介:TheeffectofyttriaonthesolidreactionmechanismofaCaHPO4·2H2O+CaCO3systematdifferenttemperatureswasexperimentallystud-ied.Thesampleswithandwithoutyttriaweresubjectedtothermogravimetric/differentialscanningcalorimetrymeasurement.ThesampleswereheattreatedatthetemperaturescorrespondingtothepeaksontheDSCspectra,andtheresultedphasecompositionswereidentifiedbyX-raydiffraction.Thetransformationmechanismwasdeducedbycomparingthephasesobtainedatdifferenttemperatures.Theresultsshowthatthetransformationsatbelow1073Karenotaffectedbyyttria,butallthoseatabove1073Karecompletelyaltered.Theformationtem-peratureofhydroxyapatitedecreasesby134K,andthedecompositiontemperatureincreasesby38K.ThepolymorphoustransformationofCa3(PO4)2fromβphasetoαphaseincreasesby47K.Thethermodynamicpropertiesofthetransformationsatabove1073Karealsomodi-fiedbytheadditionofyttria;thatis,theendothermalpeaksaresubstitutedbyexothermalpeaks.
简介:TheeffectsoftheintroductionofCetoLa_(1-x)Ce_xFe_(11.5)Si_(1.5)alloyson1:13phaseformationmechanism,thefirst-ordermagneticphasetransitionstrengtheningcharacteristics,andmagnetocaloricpropertywerestudied,respectively.Theresultsshowthattheformationmechanismsof1:13andLaFeSiphasesinLa_(1-x)Ce_xFe_(11.5)Si_(1.5)alloysarethesameasthoseofCe_2Fe_(17)andCeFe_2phasesinCe–Febinarysystem,respectively.ThesubstitutionofCein1:13phasewhichislimitedcanmakethefirst-ordermagneticphasetransitioncharacteristicsstrengthen,whichcanmakethermalandmagnetichysteresisincrease,thetemperatureintervaloftemperatureinducedphasetransitiondecrease,andthecriticalmagneticfieldoffield-inducedmagneticphasetransition(HC)increase,respectively.Owingtothelatticeshrinkof1:13phasewiththeincreaseinCecontent,theCurietemperatures(TC)showalineardecrease.Themaximumchangeinmagneticentropygraduallyincreasesduetothedecreaseintemperatureintervaloftemperature-inducedphasetransition,buttherelativecoolingcapacitiesareallabout80Jákg-1atmagneticfieldof2T.
简介:Inthisstudy,C_f/AlcompositesandTiAlalloyswerejoinedbyanewmethodnamedlaser-ignitedselfpropagatingsynthesis(SHS).Mixedpowdersof63.0Ni-31.9Al-5.1Ti(wt%)wereusedasjoininginterlayer.Perfectjointwasgot.ThemicrostructureevolutionandformationmechanismoftheSHSjointwereinvestigatedbyscanningelectronmicroscopy(SEM),energy-dispersivespectroscopy(EDS)andX-raydiffraction(XRD).Resultsshowthatlocalizedmeltingoccursonbothsides.Oneγ-Ni_(0.35)Al_(0.30)Ti_(0.35)andtwoNi-Alreactionlayersform,respectively,intheTiAl/interlayerandC_f/Al/interlayerinterfaces.ThecombustionofNi-Al-TiinterlayerbeginswiththesharpreactionofNiandAl.TheinterlayerproductisaeutecticorganizationofNiAlandAl-richγ.
简介:做Al的LiVPO4F阴极材料LiAlxV1-xPO4F被反应基于carbothermal减小(CTR)处理的二拍子的圆舞准备。做Al的LiVPO4F的性质被X光检查衍射(XRD)调查,扫描电子显微镜学(SEM),和电气化学的大小。XRD研究证明做Al的LiVPO4F有象undopedLiVPO4F的一样的三斜晶系的结构(空间组p1)。做Al的LiVPO4F的粒子尺寸比undopedLiVPO4F的小并且最小的粒子尺寸仅仅是大约1m的SEM图象展览。做Al的LiVPO4F为第二等的锂电池作为阴极材料被评估,并且展出了改进可逆性和cycleability,它可以被稳定三斜晶系的结构归因于Al3+离子的增加。