简介:渤海SZ36-1油田具有原油黏度较高、单井注水量较大和储层胶结疏松、非均质性强、渗透率较高等特点,注水开发引起高渗透层岩石结构破坏、突进现象严重,亟待采取液流转向措施。以注入压力、含水率和采收率为评价指标,开展了“堵水+调剖”联合作业增油降水效果及其影响因素的实验研究。结果表明:堵水剂优化组成为“4%淀粉+4%丙烯酰胺+0.036%交联剂+0.012%引发剂+0.002%无水亚硫酸钠”,堵水剂段塞优化组合为“0.05PV前置段塞(淀粉4%)+0.025~0.075PV堵水剂+保护段塞0.025PV(淀粉4%)+顶替段塞0.05~0.10PV(聚合物溶液,CP=1500mg/L)”,调剖剂溶液的组成和段塞组合为“0.05~0.10PV调剖剂(Cr3+聚合物凝胶,CP=3500mg/L)”。随着储层非均质性和原油黏度的增大,采收率增幅增加,这表明“调剖+堵水”联合作业措施具有较强的油藏适应性。
简介:The^Siand^1Hhigh-resolutionliquid-phaseNMRhasbeenusedtoinvestigatethehydrolysisprocessofthetetraethylorthosilicate(TEOS).^1H-NMRspectroscopyshowsthatthehydrolysisofTEOSinTPAisfasterthaninTEA.TheimpactsofTPAandTEAontheTOEShydrolysisprocessanditshydrolyzedproductdistributionhavebeenobservedby^29Si-NMRrespectively.Theinfluencesofwaterandtheisopropylalcoholonhydrolysishavealsobeendiseussed.ThepresenceofTBOTmarksanevidentdifferentiationbetweenTPAandTEAforhydrolysisin^29Si-NMRspectra.
简介:Thispaperhasstudiedthevapor-liquidequilibrium(VLE)forthesalt-containingextractivedistillationofthe1-propanol/watersystem.BinaryVLEdataweremeasuredforthesystemsof1-propanol(1)/KAc(4),ethanediol(3)/KAc(4),and1-propanol(1)/ethanediol(3),withtheVLEdatacorrelatedwiththeNRTLmodelinordertoobtainthemodelparametersofthesebinarysystems.ThebinaryVLEdatacitedintechnicalliteraturewerecorrelatedtoobtainthemodelparametersforotherbinarysystems.VLEdataofternaryandquaternarysystemspredictedbytheNRTLmodelagreedwellwiththeliteraturedata.TheinfluenceofKAc,ethanediol,andtheKAc/ethanediolmixtureonvolatilitybetween1-propanolandwaterwasinvestigatedrespectively.Testresultsshowedthattheabove-mentionedmaterials(KAc,ethanediol)andtheirmixture(KAcandethanediol)havedifferentinfluenceonthevolatility.Whenx3=0.5,andx4=0.05,theazeotropicpointcanbeeliminated.TheNRTLmodelmethodofsalt-containingVLEissimpleandeffectiveforthepredictionofthesystem’sVLEdata.
简介:针对涠洲12-1油田北块断层非常复杂,又属陆相沉积,油层薄,砂体物性横向非均质性强等问题,文中总结出了一套适于复杂岩性油藏勘探与开发的地震技术工作流程,并在涠洲12-1油田北块进行了应用.结果表明,应用三维可视化技术、属性分析技术和方差体技术可以有效解决本区的断层解释问题以及沉积模式及油藏类型等问题;在资料条件有限的情况下,应用全三维解释技术、正演模拟技术和三维地质建模技术可以对含油砂体的空间几何形态进行精细雕刻,预测储层砂体物性的横向变化,并以三维可视化技术为依托获得储层砂体的有效孔隙体积,从而为本区勘探方向的选择、开发储量的计算以及ODP方案的制定奠定了基础.
简介:Theprojectforcatalyticconversionofbiomassinto1,2-propanedioljointlydevelopedbytheCASDalianInstituteofChemicalPhysics(DICP)hasmadegreatstridesaftersuccessfulcommissioningofa100t/apilotplantatthefirstattemptwiththeconversionrateandproductselectivitybothreachingover90%.