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7 个结果
  • 简介:TheesterificationoflauricacidwithmethanolcouldbeefficientlycatalyzedbyZrOCl2·8H2O,andthisreactionwasstudiedtodevelopagreenmethodforbiodieselproduction.Theinfluencingfactors,suchasamountofcatalyst,reactiontimeandmolarratioofacidtomethanol,wereinvestigated.TheresultsindicatedthattheZrOCl2·8H2Ocatalystshowedhighcatalyticactivity,andgavea97.0%methyllaurateconversionrateunderthefollowingoptimizedconditions,viz.:alauricacid/methanolmolarratioof1:10,acatalystdosageof4%,andareactiondurationof2hatmethanolrefluxingtemperature.Thecatalystcouldbeeasilyrecoveredwhileitsactivitycouldbewellretainedafterthreecycles.TheZrOCl2·8H2Ocatalystalsoexhibitedexcellentcatalyticactivityfortheesterificationofdifferentfreelong-chainfattyacids(includingnonedibleoilswithhighacidvalue)withdifferentshortcarbonchainalcohols.Therefore,theZrOCl2·8H2Ocatalysthasgoodpotentialforthesynthesisofbiodieselfromlow-costfeedstockssuchaswastevegetableoilsandnon-edibleoils.

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  • 简介:30多年前,漂亮秀气的王秀荣在大港油田港西运输学校任教,马宗弟在大港石化公司倒班。、婚后王秀荣一心扑在工作上,年年是先进,马宗弟上24小时班,可以休息3天。他愉快地包揽了所有家务。

  • 标签: 植物 大港油田 石化公司
  • 简介:为应对电子商务支撑环境下的市场提出的新挑战和新需求,广东石油选择了建设了O2O营销模式,取得了成效。本文分析了广东石油建设O2O营销模式的过程和经验,针对经营机制、线下配套服务、大数据应用等问题提出了完善的建议。

  • 标签: 成品油 O2O 市场营销 大数据
  • 简介:TheMoS2catalystswerepreparedfromvariousmolybdateprecursorsincludinginorganicandorganicmolybdatecompounds.ThesulfidationdegreeandmorphologyofactivephasesofMoS2activatedbyvariousmolybdateprecursorsinH2S/H2streamatdifferenttemperatureswerestudiedbyX-rayphotoelectronspectroscopy(XPS)andhigh-resolutiontransmissionelectronmicroscopy(HRTEM).TheorganicmolybdateprecursorsleadtoMoS2catalystswithhighersulfidationdegreeandsmalleractivephasestodemonstratehighercatalyticactivityduringhydrodesulfurizaiton(HDS)of4,6-DMDBT.

  • 标签: 二硫化钼 钼催化剂 硫化度 钼酸盐 形态 高分辨透射电子显微镜
  • 简介:Inthispaper,2-isopropylnaphthalenehasbeensynthesizedbythereactionofnaphthaleneandisopropylbromide,usingtriethylaminehydrochloride-aluminumchlorideionicliquidasthecatalyst.Theeffectofthecatalystcomposition,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratioofthereagentsonthe2-isopropylnaphthaleneyieldwassystematicallyinvestigated.Theoptimalreactionconditionscover:anAlCl3toEt3NHClratioof2.0,areactiontimeof3h,areactiontemperatureof15.0℃,avolumefractionofionicliquidtothemixture(isopropylbromide,n-dodecaneandn-hexane)of9%,andanaphthalene/isopropylbromidemolarratioof4.0.Undertheoptimalreactionconditions,theconversionofisopropylbromidereached98%andtheselectivityof2-isopropylnaphthalenewasequalto80%.ThetestresultsverifiedgoodcatalyticactivityuponusingEt3NHCl-AlCl3ionicliquidasthecatalystforalkylationofnaphthalenewithisopropylbromide.Theactivityoftheionicliquidremainsunchangedafterithasbeenrecycledfor4times.

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  • 简介:鄂尔多斯盆地西仁沟地区延长组长2储层为典型的低渗储层。针对其形成因素复杂、分布规律认识不清等问题,采取微观观察与宏观钻井统计相结合的方法,在大量铸体薄片、扫描电镜、物性及钻井等资料分析的基础上,对该区长2储层砂岩的沉积特征、岩石学特征、孔渗特征、成岩作用类型、孔隙类型及孔隙结构等进行了深入研究。结果表明:形成于分流河道沉积背景下的长2储层砂岩具有沉积物粒度偏细、成熟度较低的岩石学特征,储集空间主要为原生粒间孔隙和次生溶蚀孔隙.圈闭类型主要为构造一岩性圈闭;大量发育的泥质和钙质夹层造成油水纵向分异程度较差,并进一步分隔油层,使单油层层内非均质性增强。总体上西仁沟地区长2储层的宏观展布受局部构造、储层岩性和物性的综合控制,对优质储层的展布具有重要的影响。

  • 标签: 低渗透 成岩作用 非均质性 鄂尔多斯盆地
  • 简介:Throughimprovingtheagingprocessduringsynthesisofthesupport,γ-Al2O3withlargeporevolumeandhighsurfaceareawassynthesizedbyafacilesecondaryreformingmethod.Thesynthesisparameters,suchasthereactiontemperature,thefirstagingtemperatureandthesecondagingtemperature,wereinvestigated.Thetexturalpropertiesofγ-Al2O3werecharacterizedbymeansofN2adsorption-desorptionisotherms,X-raypowderdiffractometry(XRD),scanningelectronmicroscopy(SEM),Fouriertransforminfrared(FTIR)spectroscopyandthermogravimetry(TG).TheexperimentalresultsindicatedthatAACHandamorphousAlOOHweretheprecursorsofalumina,whichwereformedviaprecipitationfromsolutionsafterreactionofaluminumsulphatewithammoniumhydrogencarbonate.Theprecursornanocrystallitesgrewandre-assembledduringthesecondaryreformingprocess,whichresultedinanincreasedporesizeandporevolumeandadecreasedbulkdensity.Theas-synthesizedγ-Al2O3materialsfeaturedmeso/macroporosity,largeporevolume(2.175cm3/g),highsurfacearea(237.8m2/g),andlowbulkdensity(0.284g/mL).

  • 标签: 高表面积 氧化铝 合成 转化方法 介观结构 傅里叶变换红外光谱