简介:EffectofMnsubstitutionforFeincubicLavesZr0.1Tb0.9(Fe1-xMnx)2andY0.1Tb0.9(Fe1-xMnx)2com-poundsispresented.Similarresultsinbothsystemsareobtained:ThestructureandthemagnetismofTbFe2arebothinfluencedslightlybyasmallamountofYorZrsubstitutionforTb;Withincreasingxvalue,thelatticeconstantincreasesmonotonously;theCurietemperaturedecreaseslinearly;whilesaturationmagnetizationincreaseslinearly.ForthesmallamountofMnsubstitutionforFeinbothsystems,magnetostrictionissignificantlylargerthanthatinthepureironalloys.Thelargestmagnetostrictionof|γ‖-|γ|=2200×10-6atmagneticfieldof2×107/4πA/misobtainedforY0.1Tb0.9(Fe0.95Mn0.052.
简介:Improvingthegalvanizabilityofhighsiliconadvancedhighstrengthsteels(AHSS)isapracticaltechnicalchallenge.Inthisstudy,spotdefectsonanindustrialhotdipgalvanized(GI)sheetofanAHSSwith1.5%Sihasbeenstudiedin-depth.ThesurfacemorphologiesofspotdefectsbeforeandafterpartialandcompleteremovaloftheZnlayer,aswellastheinterfacebetweentheoutermostcoatinglayerandthesheetsubstratewerecharacterizedusingopticalmicroscopy(OM),scanningelectronmicroscopy(SEM),a3-Dopticalprofiler,energydispersivespectroscopy(EDS)andfocusedionbeam(FIB)analysis.Themostoutstandingspotdefectonthenormallycoatedareaofthesteelsheethasadiameterofapproximately500μm,withthefollowingcharacteristics.Inthecentralregionofthespotdefect,ZnisbarelycoatedandthesheetsubstrateiscoveredbyathinsiliconoxidefilmwithdispersedZn-Feintermetallics.Attheperipheryofthespotdefect,aburststructureofZn-Feintermetallicsformsonthesheetsubstrate.OutsidethespotdefectwheretheZnlayerisnormallycoated,thereisacontinuousFe2Al5inhibitionlayerbetweentheZncoatingandthesheetsubstrate.Theseresultsindicatethatasiliconoxidefilmformsonthesubstrateduringannealingpriortohotdipping,thuspreventingtheformationoftheFe2Al5inhibitionlayerduringhotdipping.ThiscausesspotdefectsonhighSiAHSSsheets.
简介:Anisotropicstructures,nanoneedles,andnanospindlesofrareearthhydroxychloride(RE(OH)2Cl)andoxychloride(REOCl)(rareearth=EuandTb)weresynthesized.Therareearthhydroxychloridenanostructureswereformedviaathermallyassistedhydrolysisoftherare-earthsesquioxidenanocrystals.Themorphologicalevolutionofthenanostructureswasstudiedusinghigh-resolutiontransmissionelec-tronmicroscopyandscanningelectronmicroscopy,whilethestructuralevolutionwasinvestigatedusingX-raydiffractiontechniques.Thethermalstabilityoftherareearthhydroxychlorideswasinvestigatedusingthermogravimetricanalysis.Therareearthoxychloridenanospin-dlesweresynthesizedviaasimpleheat-treatmentofrareearthhydroxychloridenanospindles.
简介:一系列混血儿与色氨酸基于做Tb的Zn-Al分层的双氢氧化物(Tb-LDHs)结合了(此后作为尝试弄短)被软化学药品的方法综合。Tb-LDH/Try混血儿的作文,结构,和荧光被各种各样的描述分析。当Tb-LDH分别地与0.05,0.1,和0.25mol/L尝试答案反应了时,组合分析显示在混血儿在场的色氨酸的内容逐渐地增加了。XRD结果表明新思考出现在Tb-LDH/Try混血儿。Tb-LDH/Try混血儿的TGA曲线与Tb-LDH和尝试的不同。表明的红外系列混血儿的IR系列尝试和Tb-LDH是特征的。荧光灯系列建议绿排放由于5D47Tb3+的F5转变极大地减少了然而并非熄灭,并且归因试一试的排放显然增加了。同时荧光灯Tb-LDH/Try混血儿的系列在可见区域介绍了宽广连续乐队。
简介:InordertosensitizetheluminescenceofEu3+ionsinheavymetalglass,zincleadborateglasssamplescontainingvariousconcentrationsofEu3+andTb3+ionswerepreparedtostudytheTb3+toEu3+non-radiativeenergytransferphenomena.EnergylevelstructuresofTb3+andEu3+ionswereplottedtoshowtheexcitationandenergytransferroutes.EfficientenergytransferfromTb3+toEu3+wasobservedandstudiedqualitativelyintermsofdopingconcentrations.Thesensitizationturnedouttobelesseffectivethanexpected.FurtherstudiestocharacterizetheoxidationofTb3+intotetravalentstateandtoexaminethemechanismofenergytransferareproposed.
简介:ThemagneticpropertiesandthephasestructureofTb1-xPrxFe1.96(x=0,0.1,...,0.7)werestudied.ItisfoundthatthesaturationmagnetizationoneasyaxisisdecreasedwithincreaseofPrcon-tent,from77.24Am^2·kg^-1forx=0,reducestominimumvalueof11.84Am^2·kg^-1forx=0.5,andreturnesto37.14Am^2·kg^-1forx=0.7.Thenon-cu-bicphasesappearbeyondx=0.2andthematrixchangesfrom1:2phaseforx=0to1:3phaseforx=0.4,atlastto2:17phaseforx=0.7.Thecom-poundsstructurewouldturnmorecomplexasthePrcontentincreases.
简介:Advancedhighstrengthsteel(AHSS)hasbeenwidelyusedintheautomobileindustry.TheresistancespotweldingperformanceofDP980andQ&P980steelswasstudiedthroughcomparingthetwosteels'weldingcurrentrange,tensileshearstrength(TSS),crosstensionstrength(CTS),weldspots'microhardness,etc.Thefollowingconclusionswereachieved:ItiseasyforbothDP980andQ&P980steelstogetanuggetsizebiggerthan4mm,theyallhaveweldingcurrentrangesexceeding2kAandhighweldstrength.
简介:Ternarycomplexesofeuropiumandterbiumwithbenzoicacidand1,10-phenanthroline[RE(BA)3phen](BA=benzoatephen=1,10-phenanthroline)wereintroducedintoasilicamatrixbysol-gelmethod.Thethermalstabilityandluminescencebehaviorofthecomplexesinsilicagelswerestudiedincomparisonwiththecorrespondingsolid-statecomplexesbythermaldecomposition,excitationandemissionspectra.Thethermalstabilityofthecomplexesisenhancedinsilicagelmatrixandtheluminescenceremainesunchanged.