简介:Luminescentpolystyrenemicrosphereswereeasilyfabricatedfrompoly(styrene-co-methacrylicacid)andaqueousRE(III)chloridesolution(RE=Eu,Tb)inthepresenceof2,20-bipyridineassecondligand.Thenegativechargesofcarboxylgroupsonthesurfaceofmicrospherescoordinatedwithrareearthionsatfirst,suchascomplexescovalentlylinkedto2,20-bipyridine,resultinginstrongphotoluminescence.Variousmethods,includingtransmissionelectronmicroscope(TEM),scanningelectronmicroscope(SEM),energydispersivespectroscopy(EDS),Fouriertransforminfraredspectroscopy(FT-IR),andfluorescencespectrophotometer,wereusedtocharacterizetheresultantpolystyrenecompositemicrospheres.Thisworkhighlightstheideathatitisfaciletosynthesisluminescentmicrospheresbysurface-modifiedmethoddirectly.
简介:SiC/Si<潜水艇class=“a-plus-plus”>3N<潜水艇class=“a-plus-plus”>4合成是用自我繁殖的高温度的燃烧合成-Si3N<潜水艇class=“a-plus-plus”>4粉末和适当数量原文如此搽粉。两个都,sintering添加剂,系统被使用,它是YAN(Y2O3艾尔2O3AlN)并且YN(Y2O3AlN)。影响在SiC/Si的sintering行为上原文如此满意<潜水艇class=“a-plus-plus”>3N<潜水艇class=“a-plus-plus”>4合成被调查。结果证明有二个sintering添加剂系统的样品的密度,收缩,弯曲力量,坚硬,和破裂坚韧随内容的增加增加第一原文如此然后甚至当原文如此内容不断地增加时,减少。样品的重量损失的趋势是相反的。有最好的机械性质的样品原文如此满意在二个系统是不同的。为YAN系统,当原文如此内容到达10时,样品的最好的机械性质被获得?%,当至于YN系统它是5时?%。YN样品的性质比YAN样品优异。J阶段(2Y2O3吠敨爠畯整漠?灡汰楹杮氠睯瀠敲獳牵?景???慐漠?桴?獡搭獩牰灯牯楴湯瑡摥朠敲湥挠浯慰瑣搠牵湩?桴?敤潳灲楴湯爠'啼礃A慮楴湯瀠潲散獳椠?楳畴栠瑯搠晥牯慭楴湯椠??灳牡?汰獡慭猠湩整楲杮?偓?猠獹整?慣?扯慴湩挠浯汰瑥汥?敲潣扭湩摥丠??洠条敮?楷桴朠潯?湡獩瑯潲祰愠摮洠条敮楴?牰灯牥楴獥?桔?慭楸畭?慭湧瑥捩瀠潲数瑲敩??????汣獡?愢瀭畬?汰獵?慭?猯'T?????鮪徬鞪??极脿???醰鑛??鴿鎘銳????�
简介:BasedonthetechniqueforpreparingLaCl3viadirectpyrolysisofrareearthchloridesolution,ajetpyrolysisreactorwasdesignedandtheintra-reactortemperatureandchemicalreactionswerenumericallysimulatedusingcomputationalfluiddynamics(CFD)technique.Theresultsshowthattheflowratevariationatthefuelinletdoesnotlargelyaffectthetemperatureinthereactor,whiletheincreaseinexternalpressureatthematerialinletrapidlydecreasestheaveragetemperature,Venturitemperature,andoutlettemperature.TheCH4andO2insidethereactorarecombustedcompletely,andwhenthematerialinletpressureis\90Pa,theLaCl3isfullypyrogenated.ThecontentsofCO2,La2O3,andHClfluctuateneartheVenturitubeandfinallystabilize.La2O3contentattheoutletisinatop-to-bottomgradient.
简介:HotcompressionbehaviorofTiC–Al2O3/AlcompositeswasstudiedusingtheGleeble-1500systematatemperaturerangeof300–550°Candatstrainraterangeof0.01–10.00s-1.TheassociatedstructuralchangeswerestudiedbyTEMobservations.Theresultsshowthatstressleveldecreaseswithdeformationtemperatureincreasingandstrainratedecreasing,whichcanberepresentedbyaZener–Hollomonparameterinanexponent-typeequationwithhotdeformationactivationenergyQof172.56kJ·mol-1.Dynamicrecoveryoccurseasilywhenstrainratesarelessthan10.00s-1.Dynamicrecrystallizationcanoccuratstrainrateof10.00s-1.
简介:采用丝印法在铝基板上制备具有低室温电阻率、适中热敏常数的负温度系数BaCo0.02ⅡCo0.04ⅢBi0.94O3/Ba0.5Bi0.5Fe0.9Sn0.1O3复合热敏厚膜。采用数字多用表、吉时利2400和阻抗分析仪对热敏厚膜的电学性能进行表征。结果表明:随着Ba0.5Bi0.5Fe0.9Sn0.1O3含量从0.05增加至0.25,厚膜的室温电阻率、热敏常数和峰值电压均有所增加且分别处于1.47-26.5Ω·cm、678-1345K和18.9-47.0V范围内,厚膜峰值电压对应的电流也有所降低且处于40-240mA范围。阻抗谱测试表明,这些热敏厚膜表现出非正常的异质电学微结构行为,由高阻态的晶粒和较低电阻态的晶界区域构成。由此可知,在BaCo0.02ⅡCo0.04ⅢBi0.94O3中添加Ba0.5Bi0.5Fe0.9Sn0.1O3改善了热敏行为但也恶化了电流特征.
简介:ExtractingB2O3fromcalcinedboronmud(CBM)wasstudied.TheeffectoffactorssuchasreactiontemperatureandNaOH-to-CBMmassratioonB2O3extractionefficiencywasinvestigated.TheresultsshowthatincreasingreactiontemperatureandNaOH-to-CBMmassratioincreasesB2O3extractionefficiency.TherearetwostagesfortheB2O3extractingprocess:0–20ministhefirststage,whichisrapid;20–50ministhesecondstage,whichisslowerthanthefirststage.Theoverallextractingprocessfollowstheshrinkingcoremodel,andthefirstandsecondstagesaredeterminedtoobeythesurfacechemicalreactionmodelandthediffusionthroughtheproductslayermodel,respectively.Theactivationenergiesofthefirstandsecondstagesarecalculatedtobe41.74and15.43kJ·mol-1,respectively.TheB2O3extractingkineticsequationsofthefirstandsecondstagesarealsoobtained.