简介:TheXRPD(X-raypowderdiffractometry)patternsofsiliconpowderwithaunitcellstructureofdiamondweredeterminedfrom298to1473K.LatticeparametersofSilinearlyincreasewithtemperature.Thethermalshiftsofthepositionsofallreflectionpeaksarelinearlycorrelatedwiththetemperature.Thecoefficientsoftheintrinsiclinearthermalexpansionandvolumetricthermalexpansionweredeterminedas3.87×10-6/Kand1.16×10-5/Krespectively.ItindicatesthatSiisstillasuitablestandardintheXRPDmethodathightemperatures.
简介:Widegapbrazing(WGB)experimentsusingthebuttedspecimenwitha1.5mmgapwerecarriedoutfortherepairofthefailedK418Bsuperalloylow-pressureturbinevanes.Thehightemperaturecreeprupturestrengthsofthebrazedjointsweretested,andthemicrostructuresandfracturesurfacesofthejointswereobserved.TheresultsshowthatthemicrostructureofK418Balloyjointiscomposedofdenseequiaxedgrain,smallanddiscretecompoundswithafewmicro-pores.Duringthecreeprupturetest,thecracksinitiatepreferentiallyatthemicro-poreorthegrainboundary,thenpropagatealongthegrainboundarytillthefracturehappens.Thecreeprupturestrengthat700℃ofthebrazedjointswith50%brazemetalintheworkingpartcouldexceed90%thatoftheK418Bsuperalloy,andthejointswith100%brazemetalintheworkingpartachieve70%to80%ofthecreeprupturestrengthsfortheK418Bbasemetal.
简介:多晶的La1?xKxCoO3(0x0.2)稀土元素cobaltates被一个答案燃烧方法作为燃料用glycine综合了。综合陶器的材料被粉末X光检查衍射(XRD)描绘,扫描电子显微镜学(SEM),Fourier变换红外线的光谱学(FTIR),和磁性的大小并且为物理性质学习了,例如photocatalytic活动。与XRD一起的FTIR大小证明在做的10%K以外的阶段被杂质的小数量伴随。化学滴定为系统的Co3+-Co4+混合原子价显示出Co4+和报道的存在。父母LaCoO3在低温度显示出纺纱眼镜转变,而做的样品从纺纱眼镜行为显示出转变到在K的进步的做上的顺磁的订。这些陶艺的混合售票员自然作为稳固的氧化物的可行候选人放他们燃料房间(SOFC)应用。
简介:Anewtechnology,thetwo-steptransientliquidphasediffusionbonding(TLP-DB)technologyforcobalt-basedK640superalloy,wasinvestigated.Themethodconsistsofashort-timehightemperatureheatingtomeltinterlayerfollowedbyisothermalsolidificationofliquidphaseatalowertemperaturethanthatoftheconventionalTLP-DB.Theresultindicatesthatthetwo-stepTLP-DBcanreliablyproduceanidealjointwithuniformchemicalcomposition,whichissuperiortothejointweldedbyconventionalTLP-DBinmicrostructureandmechanicalproperties.Bondingparametersofnewprocessare1250℃for0.5hand1180℃for3h.Thehigh-temperaturetensilestrengthofthejointbytwo-stepTLP-DBreaches74%ofthatofthebasematerialonanequalbasis,butthehigh-temperaturetensilestrengthofthejointbyconventionalTLP-DBisonly58%ofthatofthebasematerial.
简介:ElectrocrystallizationMechanismofTungsteninMoltenKF-B_2O_3-K_2WO_4WenZhenhuanandLiGuoxun文振环,李国勋(GeneralResearchInstiiuteforNo...
简介:Inthispaper,thebrazingmechanismofLY12aluminumalloyatmiddlerangetemperaturewaspresented.TheCsF-AlF3non-corrosivefluxwasutilizedtoremovethecomplexoxidefilmonthesurfaceofLY12aluminumalloy.TheresultsrevealedthattheoxidefilmwasremovedbytheimprovedCsF-AlF3fluxaccompaniedwiththeoccurrenceofreactionaswellasdissolutionandthecompoundsCsFplayedanimportantroletoremovetheoxidefilm.Actually,thehighactivityofflux,say,theabilitytoremovetheoxidefilm,wasduetothepresenceofthecompounds,suchasNH4F,NH4AlF4andcompositemoltensalt.TheproductionofHFwasthekeyissuetoacceleratethereactionandenhancetoeliminatetheoxidefilmbydissolution.ItwasfoundthattherareearthelementLaatsmallpercentagewasnotenrichedattheinterface.Moreover,therareearthfluorideenhancedthedissolutionbehavior.
简介:Ni-basedsuperalloyK465isbrazedwithBNi-2fillermetalbyvacuumelectronbeambrazing(VEBB).InprocessofVEBB,effectsofprocessingprimaryparametersonshearstrengthofjointsareinvestigated.MicrostructureofthebrazedjointwithBNi-2fillermetalisstudiedbymeansofscanningelectronmicroscopy(SEM),energydispersivespectroscopy(EDS)andX-raydiffraction(XRD).TheresultsshowthatthestructureofbrazedseamconsistsofalargeamountofNi-basedγsolidsolution,Ni3Al(γ′),Ni3B,WB,CrB,andasmallquantityofWC,NbC.Themaximumshearstrengthofthejointis398MPawhenthebeamcurrentofweldingis2.6mA,heatingtimeis480sandfocusedcurrentis1800mA.