简介:Thepaperrepresentsarigoroustreatmentoftheunderlyingquantumtheory,notjustinwordsbutprovidingtheunderlyingtechnicaldetails,astowhymatteroccupiessolargeavolumeanditsintimateconnectionwiththePauliexclusionprinciple,asmoreandmorematterisputtogether,aswellasofthecontractionorshrinkageof'bosonicmatter',uponcollapse,forwhichthePauliexclusionisabolished.Fromthederivedexplicitboundsofintegralsofpowersoftheparticlenumberdensities,explicitboundsonprobabilitiesoftheoccurrencesoftheeventsjustdescribedareextracted.Theseprobabilitiesleadonetoinferthechangeofthe'size'orextensionofsuchmatter,uponexpansionorcontraction,respectively,astheircontentisincreased.
简介:TheeffectsofSO2,SO3ondenovosynthesisofpolychlorinateddibenzo-p-dioxins(PCDDs)anddibenzofurans(PCDFs)werestudiedusingmodelflyashesincorporatingcopperoxideandactivatedcarbon.ItwasfoundthattheinhibitiveeffectofSO2onPCDD/FsformationissimilartothatofSO3.Toinvestigatetheinhibitionmechanism,CuSO4formationsfrombothCuOandCuCl2wereexamined.TheabilityofSO3toconvertCuCl2andCuOonasilicasupportintosulfateismuchstrongerthanthatofSO2.However,replacingsilicabyactivatedcarbonleadstoamuchhighconversionofCuCl2toCuSO4inthepresenceofSO2.ThepromotionbyactivatedcarbonisexplainedbythereductionofCuCl2toCu2Cl2andtheeventualconversionofCu2Cl2intoCuSO4isthemaininhibitionmechanismofSO2ondenovosynthesisofPCDD/Fs.
简介:<正>Inthisnote.wewillshowthatnononuniformlatticeofSO(3,1)canbethefundamentalgroupofaquasi-compactKhlermanifold.Thus,combiningwiththeresultin[1].onegetsthatanonuniformlatticeinSO(n,1)(n≥3)cannotbeπ1ofanyquasi-compactKhlerianmanifold.
简介:APt-MoO3/Ccatalyst,aimedtoeliminatetheharmfuleffectofsulfurdioxide(SCb)ontheperformanceofPtnanoparticles(NPs)forcatalysisofoxygenreductionreaction(ORR)inprotonexchangemembranefuelcells(PEMFC),isdevelopedandcharacterizedbyTEM,XRDandXPS.TheresultsrevealthatPt-MoO3/Ccatalystexhibitsnotonlyahighercatalyticactivity,butalsoabetterSO2poisoningresistanceandabetterrecoveryperformancethanthecommercialPt/Ccatalystdoes.
简介:TheinfluenceofNa2SO4ontheformationofZnOwhiskerswasinvestigatedinthispaper.ZnOwhiskerswithaspectratiosofupto50weresynthesizedbydissolvingε-Zn(OH)2precursorinNaOH/Na2SO4solutionatroomtemperature,followedbyagingoftheresultingsolutionat140℃for6h.Fouriertransforminfraredspectroscopy,Ramanspectroscopy,andX-rayphotoelectronspectroscopyanalysesrevealedthatSO42-ionswereprimarilyadsorbedonthe(100)planeoftheZnOwhiskersviaanouter-spherecomplexconfiguration(O-H…O),therebypromotingtheone-dimensionalgrowthofZnOwhiskersalongthec-axis.
简介:Weperformfirst-principlecalculationsforthestudyoftheorthorhombicRb2Cd2(SO4)3structure.Electronicenergybands,totalandpartialdensitiesofstatesarereportedandanalysed.Itisfoundthatoxygenatomic2pelectronsstronglyhybridizewithRb/orCd4dandS2pstates,resultingintwo-typeionicgroupswithweakcouplings.Itisshownthatmacroscopicdomainwallsoriginatefromsuchweak-couplingionicgroups,arisingatthecellboundaries.Theasymmetriccationbonds(Rb-OandCd-O)andthesubsequentrotationsoftheS04tetrahedracanleadtothedrivingforceoftheferroelectricbehaviour.Thepredictedpyroelectriccurrenteffectsareobservedexperimentallyintheferroelectricphase.
简介:Kineticsofchloride/sulfate,chloride/nitrateandnitrate/sulfateforwardexchangesandreverseexchangesatsolutionconcentrationsof1N,0.2Nand0.02Non201×7strongbaseanionexchangeresin,respectively,havebeenexaminedat25℃.Itisfoundthattheforwardandthereverseexchangeratesofthetwogivenionsatlowsolutionconcentration,respectively,underidenticalconditionscanbecontrolledbydifferentmechanisms,whilethoseathighsolutionconcentrationareallcontrolledbyparticlediffusion.Theternaryexchangeratesofsulfate/(chloride+nitrate)andnitrate/(chloride+sulfate)havealsobeenexamined.
简介:ThecrystalgrowthprocessofZn(Leu)SO4·0.5H2OformwaterandacetonewasinvestigatedusingaCalvetmicrocalorimeter.Theheatandtherateofheatproductionduringthecrystalgrowthprocessat293.15K,295.15K,298.15Kand300.15Kweremensured.Onthebasisofexperimentalandcalculatedresults,therateconstantandthekineticparameters(theactivationenergies,thepre-exponential)duringthecrystalgrowthprocesswereobtained.Theresultsshowthatthecrystalgrowthprocesswereobtainged.TheresultsshowthatthecrystalgrowthprocessaccordedwiththeBurton-Cabrera-Franddislocationtheory.
简介:ThespinelLiMn2O4-x(SO4)xcompoundcathodematerialsweresynthesizedbysolid-statereactionofthecalculatedamountsofLiOH·H2O,MnO2andMnSO4.Theresultsoftheelectrochemicaltestdemonstratedthatthesematerialsexhbitedexcellentelectrochemicalproperties.Thehighestreversiblecapacityoftheseseriesofcathodematerialswas-120mAh/g,andafter50cycles,thisreversiblecapacitywasstillaround116mAh/gwithnearly100%reversibleefficiency,whichrevealedthatdopedsulfateioncouldimprovethestructuralstabilityofspinel.
简介:Rare-earthcompoundsolidsuperacidSO42-/TiO2/La3+wasprepared.Itscatalyticactivitywasexaminedunderdifferentsyntheticconditionsfortheesterificationofpropanoicacidandn-butylalcoholasprobingreaction.Theoptimumconditionswerealsofound,whichwerethepH=8,thedepositingtimewas24h,themassfractionofLa(NO3)3usedinsolidsuperacidwas5%,theconcentrationofH2SO4was1.25mol/L,thesoakingtimeinH2SO4was16handthecalciningtemperaturewas500°C.TheethyloleatewassynthesizedfromoleicacidandethanolinthepresenceofSO42-/TiO2/La3+.Theoptimumreactionconditionswereobtainedwhichwerethereactiontimewas6h,molarratioofoleicacidtoethanolwas1:4andthemassfractionofcatalystwas4%.
简介:TiO2nanoparticlesweresynthesizedbyahomogeneouscontrolledprecipitationmethodusingindustrialtitaniumsulfate(Ti(SO4)2).TheobtainedpowderswerecharacterizedbyX-raydiffraction(XRD),transmissionelectronmicroscope(TEM),Fouriertransforminfraredspectroscopy(FTIR)andICPplasmaspectrometer.EDTAwasusedascomplexingagenttoimprovethepurityandtheformationofTiO2nanoparticles.Experimentalresultsindicatedthatthehigh-purityTiO2nanoparticleswere20nminmeansizeandnearlymonodispersed.
简介:One-potachievementofethyllevulinatefromcassavawasconductedinethanol-watersystemoverseveralsimplesulfatesaltcatalysts.Al2(SO4)3catalysthadthebestperformanceinsynthesizingethyllevulinatecomparingwiththoseofaseriesofsulfatesalts.Thehighestyieldsofethyllevulinatewasupto39.27%aswellas7.78%levulinateacidwhencassavawascatalyzedinethanolmediumbyadding10wt%water.13Cand1HNMRspectroscopicinvestigationsconfirmedthatisomerizationofglucosetofructoseoverAl2(SO4)3catalystisanimportantstepinproducingethyllevulinateandlevulinateacid.DuetoaggregationsofAl3+underhydrothermalconditions,tinyamountofAl3+weredetectedinfiltrateatthepercentageof0.32%evenifinabsolutewater.BronstedandLewisacidscouldimprovetheyieldofethyllevulinateandlevulinateacidbysynergisticeffect.AllresultssuggestedthatA12(SO4)3wasasimpleandefficientcatalystforethyllevulinateandlevulinateacidproduction.
简介:Theoccurrencemodesofalkaliandalkaline-earthmetals(AAEMs)incoalrelatetotheirreleasebehaviorandashformationduringcombustion.TobetterunderstandthetransformationofAAEMs,thereleasebehaviorofwater-soluble,HCl-soluble,HCl-insolubleAAEMsduringShenmucoal(SMcoal)oxy-fuelcombustioninthepresenceofSO2andH2Oinadrop-tubereactorwasinvestigatedthroughserialdissolutionusingH2OandHClsolutions.TheresultsshowthatthereleaseratesofAAEMsincreasewithanincreaseintemperatureunderthethreeatmospheresstudied.ThehighreleaseratesofMgandCafromSMcoalaredependentonthehighcontentofsolubleMgandCainSMcoal.SO2inhibitsthereleaseratesofAAEMs,whileH2Opromotesthem.TheeffectsofSO2andH2OontheNaandKspeciesaremoreevidentthanthoseonMgandCaspecies.AllthreetypesofAAEMsincoalcanvolatilizeinthegasphaseduringcoalcombustion.TheW-typeAAEMsreleaseexcessively,whereasthereleaseratesofI-typeAAEMsarerelativelylower.DifferenttypesofAAEMmayinterconvertthroughdifferentpathwaysundercertainconditions.BothSO2andH2Opromotethetransformationreactions.TheeffectofSO2wasrelatedtosulfateformationandthepromotionbyH2OoccursbecauseofadecreaseinthemeltingpointofthesolidaswellasthereactionofH2O.