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23 个结果
  • 简介:New[1+1]and62-membered[2+2]Schiffbasemacrocyclescontaininga2,6-diamidopyridinesubunithavebeensynthesizedbycondensationreactionoftheprecursorspyridine-2,6-dicarboxamideand1,10-bis(20-formylphenyloxy)decaneinthepresenceofphosphoricacidviaaone-potprocess.Thecyclocondensedproductswereeffectivelyisolatedbygelcolumnchromatographyandcharacterizedby~1HNMR,FTIR,massspectrometryandX-rayanalysis.Thetwomacrocycleshaveatwistedstructure,andnotanopen‘circular’conformationinthesolidstate.

  • 标签: 大环化合物 一锅法合成 凝胶柱层析 X射线分析 反应合成 FTIR
  • 简介:Anticipatedbackwardstochasticdifferentialequation(ABSDE)studiedthefirsttimein2007isanewtypeofstochasticdifferentialequations.Inthispaper,weestablishageneralcomparisontheoremforABSDEs.

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  • 简介:AseriesofnovelN-(3-furan-2-yl-1-phenyl-1H-pyrazol-5-yl)amidesderivativesweredesignedandsynthesized.Theirstructureswereconfirmedby1HNMR,13CNMRandHRMS.Alltitlecompoundswereevaluatedfortheirherbicidalandantifungalactivities.Preliminarybioassayresultsindicatedthatthetitlecompoundsshowedgoodtomoderateherbicidalactivityat1000mg/L.Compound6qpresentedthebestactivityagainstDigitariasanguinalis(L)Scop.,AmaranthusretroflexusL.andArabidopsisthalianawithaninhibitiondegreeoffive.Compound6dalsoshowedaninhibitiondegreeoffiveagainstD.sanguinalis.Inaddition,at50mg/L,mostcompoundsexhibitedgoodinvitroantifungalactivityagainstSclerotiniasclerotiorum,withcompound6cshowingover90%antifungalactivityagainstS.sclerotiorumandPelliculariasasakii.

  • 标签: 酰胺衍生物 生物活性 设计合成 除草活性化合物 抗真菌活性 油菜菌核病
  • 简介:Thephotonpolarizationtensorcarriesthefundamentalinformationofmagnetizedvacuumormedium[1{5].Acompletedescriptionofthevacuumpolarizationtensorisparticularlycomplicatedtoapproach,sincethevacuumphotonpolarizationtensorisexpressedintermsofadoublesummationofinfiniteserieswithrespecttotwoLandaulevelsoccupiedbyvirtualchargedparticles.MostworkswerefocusingonthestrongfiledlimitwithanassumptionofLowestLandauLevel(LLL)[2,6]InRef.[7]weobtainedafulldescriptionofvacuumpolarizationtensorinresponsetoalltheLandaulevelsatanyfieldstrengthofBforthefirsttimebeyondLLLapproximation,andwefoundoutthattheimaginarypartofthephotonpolarizationtensorξΠbecomesnonzeroatthetimelikemomentaregionQ2>4(M2+2neB)atT=0,i.e..,theLLLapproximationisanalyticallysatisfied[3,7].

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  • 简介:TheGroupofNuclearStructureResearchatIMPhasdevotedmuchefforttothestudyofin-beam-rayspectroscopyandγ-decayspectroscopy.Oneterminalforin-beam-rayspectroscopyhasbeennewlybuiltupin2016.Asforγ-decayspectroscopy,twopointsneedtobeemphasized.Inordertostudythein-beam-rayspectroscopy,aballwasplacedattheterminalofnewTL2beamline.Threequadrupolemagnetsfollowingthedipolemagnetarethemainbuildingblocksalongthebeamline.Theballconsistsof8cloverand16HPGedetectorswithaCsIballinsidetoselectthechargedparticlechannel.Awallisolatingtheballfromthequadrupoleswasusedtoshieldtheradiationproducedbytheacceleratoranddepositingenergyinthedetectors,whichmayresultinahighbackground.Theinstallationwasfinishedin2016andtheexperimentforin-beam-rayspectroscopyisexpectedtoperformin2017.

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  • 简介:Inthispaper,weusecontractionmappingprinciple,operator-theoreticapproachandsomeuniformestimatestoestablishlocalsolvabilityoftheparabolic-hyperbolictypechemotaxissystemwithfixedboundaryin1-dimensionaldomain.Inaddition,localsolvabilityofthefreeboundaryproblemisconsideredbystraighteningthefreeboundary.

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  • 简介:Basedontherangespaceproperty(RSP),theequivalentconditionsbetweennonnegativesolutionstothepartialsparseandthecorrespondingweightedl_1-normminimizationproblemarestudiedinthispaper.Differentfromotherconditionsbasedonthesparkproperty,themutualcoherence,thenullspaceproperty(NSP)andtherestrictedisometryproperty(RIP),theRSPbasedconditionsareeasiertobeverified.Moreover,theproposedconditionsguaranteenotonlythestrongequivalence,butalsotheequivalencebetweenthetwoproblems.First,accordingtothefoundationofthestrictcomplementaritytheoremoflinearprogramming,asufficientandnecessarycondition,satisfyingtheRSPofthesensingmatrixandthefullcolumnrankpropertyofthecorrespondingsub-matrix,ispresentedfortheuniquenonnegativesolutiontotheweightedl_1-normminimizationproblem.Then,basedonthiscondition,theequivalenceconditionsbetweenthetwoproblemsareproposed.Finally,thispapershowsthatthematrixwiththeRSPoforderkcanguaranteethestrongequivalenceofthetwoproblems.

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  • 简介:采用UMP2/6-311+G(3df)方法研究了一系列化合物M_(n+1)F_n(n=1,2;M=Na,K)体系的几何构型及非线性光学性质(NLO).结果表明:这些体系均为超价化合物,均拥有较大的第一超极化率(β_0).尤其是Na_3F_2体系中结构2c的β_0值为29.16×10~(-49)C~3·m~3·J~(-2),是已知超价化合物Li_3F_2的2c结构的β_0值2.22×10~(-49)C~3·m~3·J~(-2)的13.1倍.

  • 标签: 从头算 超价化合物 非线性光学性质
  • 简介:雷纳兹应力(RS)上的积极偏爱的效果和它在边血浆的光线的狂暴的运输上的效果(r/a?=?0.9)并且在tokamak的血浆的擦去层(太阳)区域被调查。光线并且poloidal电场(Er,Ep)和离子浸透电流(我s)被多种用途的探查(MPP)测量。这根探针在IR-T1tokamak第一次被制作并且构造。这根探针的大多数优点是Er和Ep能在单个射击在不同半径被测量。因此不同半径的信息能与高精确相比。偏爱电压在V偏爱?=?200V和它与在r/a被修理的limiter偏爱被使用了?=?0.9。而且,之间的阶段差别光线并且MPP检测的RS光谱的poloidal电场,和时间的进化被计算。边上的RS大小(r/a?=?0.9)多于它在太阳的价值(r/a?=?1.02)。与应用偏爱200V,RS和Er和Ep被增加,当光线的狂暴的运输同时被减少时。因此,RS影响光线的骚乱,这能被结束。RS光谱的时间的进化证明RS的频率在r/a被增加并且到达它的最高的价值?=?0.9面对偏爱。

  • 标签: 雷诺兹应力 外加偏压 多功能 托卡马克等离子体 探针 装置
  • 简介:Ithasbeenproposedthatfusionreactionsbetweenneutron-richlightnuclei,forexample24C,24Oand28Ne,maycontributetoachievingtheignitiontemperatureforexplosivecarbonburningprocessduringsuperbusrsts[1,2].Studiesoffusionreactionsinvolvingneutron-richnucleiarebeyondordinaryexperimentaltechniques,sincetheintensityofradioactivebeambecomelowforthesemeasurements[3].TheactivetargettechniqueusingTPC(TimeProjectionChamber),withpropertiesofmulti-sampling,highefficiencyandlowbackground,isasuitablesolutiontotheproblem.

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  • 简介:Inthispaper,themodifiedextendedtanhmethodisusedtoconstructmoregeneralexactsolutionsofa(2+1)-dimensionalnonlinearSchr¨odingerequation.WiththeaidofMapleandMatlabsoftware,weobtainexactexplicitkinkwavesolutions,peakonwavesolutions,periodicwavesolutionsandtheir3Dimages.

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  • 简介:Nitricoxidehasplayedanimportantroleinmanyphysiologicalandpathologicalprocessesasakindofimportantgassignalmolecules.Inthiswork,anewfluorescentprobeLysoNO-NaphfordetectingNOinlysosomesbasedon1,8-naphthalimidewasreported.LysoNO-Naphhassub-groupsofo-phenylenediamineasaNOreactionsiteand4-(2-aminoethyl)-morpholineasalysosome-targetablegroup.Thisprobeexhibitedgoodselectivityandhighsensitivity(4.57mmol/L)towardNOinawidepHrangefrom4to12.Furthermore,LysoNO-NaphcanbeusedforimagingNOinlysosomesinlivingcells.

  • 标签: 活细胞成像 荧光探针 一氧化氮 溶酶体 气体信号分子 NAPH
  • 简介:针对1点RANSAC(RandomSampleConsensus)单目视觉EKF(ExtendedKalmanFilter)算法中的滤波发散问题,分析了滤波发散的产生原因,提出了一种基于渐消记忆滤波的1点RANSAC单目视觉姿态估计算法。该算法通过在EKF滤波方程中引入加权因子,逐渐加大当前数据的权重,相应地减少旧数据的权重,有效地扼制了算法中的滤波发散问题。最后通过两组验证性实验验证说明了算法的有效性。实验结果表明:该算法能够有效地解决1点RANSAC单目视觉EKF算法中的滤波发散问题,具有更高的精度。第一组双轴联动实验,航向角的平均误差减小2.4158?,俯仰角平均误差减小0.1782?;第二组偏航轴大角度转动实验,摄像机航向角的估计误差一直保持在1.5?以内。

  • 标签: 1点RANSAC算法 渐消记忆滤波 单目视觉 滤波发散
  • 简介:本文讨论随机环境两性分支过程中以条件均值增长率的上界作为规范化因子的L^1一收敛问题,给出了L^1一收敛的对数判别准则的充要条件.

  • 标签: 随机环境 两性分枝过程 L^1一收敛
  • 简介:Cobaltandnickelcomplexes(1a-1dand2a-2d,respectively)supportedby2-imidate-pyridineligandsweresynthesizedandusedfor1,3-butadienepolymerization.ThecomplexeswerecharacterizedbyIRandelementanalysis,andcomplex1awasfurthercharacterizedbysingle-crystalX-raydiffraction.Thesolidstatestructureofcomplex1adisplayedadistortedtetrahedralgeometry.Uponactivationwithethylaluminumsesquichloride(EASC),allthecomplexesshowedhighactivitiestoward1,3-butadienepolymerization.Thecobaltcomplexesproducedpolymerswithhighcis-1,4contentsandhighmolecularweights,whilethenickelcomplexesdisplayedlowcis-1,4selectivityandtheresultingpolymershadlowmolecularweights.Thecatalyticactivitiesofthecomplexeshighlydependedontheligandstructure.Withtheincrementofpolymerizationtemperature,thecis-1,4contentandthemolecularweightoftheresultingpolymerdecreased.

  • 标签: 1 3-BUTADIENE Late-transition metal Cis-1 4-polybutadiene Pyridine-2-imidate
  • 简介:利用水热工艺,选用有机配体3,3’,5,5’-四甲基-4,4’-联邻二氮杂茂(H2X)和CuCl2·2H2O为起始原料,合成了1个新的多酸基杂化化合物[Cu2(H2X)2(Mo6O19)]·2H2O被合成.采用X-射线单晶衍射、红外光谱、元素分析和热重分析等手段对该化合物的结构进行了表征.单晶测试结果表明该化合物为1D链状化合物,属于三斜晶系,P-1空间群,晶胞参数a=0.9469(3)nm,b=0.9544(3)nm,c=2.0599(6)nm,α=90.717(4)°,β=93.518(5)°,γ=102.802(4)°,V=1.8112(9)nm3,Z=4,R1=0.0829,wR2=0.1512.

  • 标签: 杂化化合物 水热合成 晶体结构 联邻二氮杂茂