简介:ThepreparationoftwotypesofmolecularsievesAlPO4-11andMAPO-11isreported.Theparticlesizeofthelatterishundredsofmicrons,about10timeslargerthanthatoftheformer.TheXRD,IRandDTAspectrahavedemonstratedthatmagnesiumhasbeenintroducedintotheframeworkofAlPO4-11.ThesuccessfulpreparationoflargesinglecrystalofMAPO-11willopenupanewareaforthepreparationoflargemolecularsievescrystalsinthefuture.ThelargeMAPO-11crystalcompoundisapromisinghostforthehost-guestassemblyofcompositematerials.
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简介:134Csabranchingpointins-processpathwhichisshowninFig.1.Thebranchingratioisdefinedasfβ=λβ/(λβ+λn).Itcouldbededucedfromtheabundanceof134Baand136Basince136Bagoesthroughbothdecayandneutroncaptureof134Cswhile134Baonlyexperiencesdecaychannel[1].Duetoboth134Baand134Baarepures-processnuclei,thisbranchingpointisagoodapproachtodeterminethes-processparameters.Withtemperaturedependentβ-decayrateof134Cs,thetemperatureofs-processcouldbededuced.
简介:InstitutionofModernPhysics(IMP)hasdesigned,fabricatedandinstalledthefirstSRFcavityelectropolishingsystemofChina.It’ssizedfor1.3GHzSRFcavities,andalsocanworksformultiplecellcavitieswithfurtherupgradeofstructure.
简介:In2014,theresearchersofTheoreticalPhysicsGroupatIMPhavecarriedouttheirresearchworkonnuclearphysics,heavyionphysicsandhadronphysics.Someimportantresultshavebeenobtained.Thethree-bodyforce(TBF)effectontheoff-shellbehavioroftheneutronandprotonmassoperatorsinasymmetricuclearmatterhasbeeninvestigatedwithintheframeworkoftheextendedBrueckner-Hartree-Fockapproach[1].Athighdensitieswellabovethenormalnuclearmatterdensity,theTBFisshowntoaffectsignificantlytheoff-shellehaviorofboththeprotonandneutronmassoperators.Thedensitydependenceofsymmetryenergyaroundtheuclearsaturationdensityhasbeenstudied[2].Anewapproachhasbeenproposedandappliedtodeterminetheymmetryenergycoefficientofheavynucleibasedontheavailableexperimentalnuclearmassesofheavynuclei.Theobtainedresultisadoptedtoanalyzethedensitydependenceofsymmetryenergyofnuclearmatteraroundtheaturationdensity.TheslopeparameteratthesaturationdensityisdeterminedtobeL=(50.515.5)MeV.
简介:TheprogressofresearchgoingoninGroupofEnergyMaterials(GEM),MaterialResearchCenter,in2014isinthefollowingthreeaspects.1.FacilitydevelopmentInordertopushforwardourstudyonfusionreactormaterials,weupgradedtheirradiationterminal(128#)ofthesectorfocusedcyclotron(SFC)atHIRFL,bydevelopinganewspecimenstagespecificforirradiationwithlow-fluencescatteredions.Sofartheterminaliscapableofirradiationtobothverylowfluences(106ions/cm2)andveryhighfluences(typically1016ions/cm2)forvariousmaterials.SpecimentemperaturecanbereadilycontrolledusingtheL-N2coolingstageorthethehigh-Tstage(upto600oC).Ourrecentinvestigationwithtransmissionelectronmicroscopy(TEM)ofthedefectsproducedbyhigh-energyNeionsinsteelspecimensprovidesaclearevidencethatdefectswereproduceduniformlyalongthedepthinthespecimen,indicatingthattheenergydegraderoftheterminalworkseffectivelytodispersetheionenergyinawiderange.AphotooftheterminaltogetherwithaSRIMestimateofdepthprofilesofdamageinan8%Crreducedactivationferritic/martensiticsteel(RAFMS)isshowninFig.1.
简介:HierarchicalZSM-11microsphereswithintercrystallinemesoporouspropertiesandrod-likecrystalsintergrowthmorphologyhavebeensynthesizedusingaspotoftetrabutylammoniumasasingletemplate.XRD,FTIR,SEM,TEMandN2adsorptionanalysisrevealedthateachindividualparticlewascomposedofnanosizedrodcrystalsinsertingeachotherandtheintercrystallinevoidsexistingamongrodsgaveasignificantmesoporesizedistribution.Steamtreatmentresultdemonstratedtheexcellenthydrothermalstabilityofsamples.Variouscrystallizationmodesincludingconstanttemperaturecrystallization(one-stagecrystallization)andtwo-stagetemperature-varyingcrystallizationwithdifferent1ststagedurationswereinvestigated.TheresultssuggestedthatthecrystallizationmodesweremainlyresponsiblefortheadjustableparticlesizeandtexturalpropertiesofsampleswhilethesmallamountoftetrabutylammoniumbromidewasmainlyusedtodirecttheformationofbothZSM-11frameworkanditsintergrowthmorphology.Furthermore,theperformanceofoptimalZSM-11asanactivecomponentforthecatalyticpyrolysisofheavyoilwasalsoinvestigated.Comparedwiththecommercialpyrolysiscatalyst,thehierarchicalZSM-11catalystexhibitedahighselectivitytodesiredproducts(LPG+gasoline+diesel),aswellasamuchlowerdrygasandcokeyield,plusahighselectivityandyieldoflightolefins(C=3C=4)andverypoorselectivitytobenzene.Therefore,fullyopenmicropore-mesoporeconnectivitywouldmakesuchhierarchicallyporousZSM-11zeolitesveryattractiveforapplicationsincleanpetrochemicalcatalysisfield.