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  • 简介:Nanowireshaveattractedmoreandmoreinterestinrecentyearsduetotheiruniquepropertiescomparedtobulkmaterials[1].Thequitedifferentpropertiespossessedbynanowiresaremainlycausedbytheirhighsurface-tovolumeratio[2].Behaviorsofnanowiresunderirradiationconditionshavealsoattractedintensiveattentionintheseyears[3??5].Ithasbeenproposedthatnanowiresmayberadiationresistancebecausetheirlargesurface-to-volumeratio,andmeanwhilethesurfacearetheperfectsinksfordefectscreatedintheradiationprocess[3].

  • 标签: Molecular Dynamics STUDY
  • 简介:Rotation in Reaction 19F+51VRotationinReaction19F+51V¥WangQi;LuJun;XuHushan;LiSonglin;ZhuYongtaiandZhangYuhuIndLssi...

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  • 简介:19-DITERPENOIDALKALOIDSOFDELPHINIUMMOLLIPILUM¥SuoMingZHANG;QingYuOu(LanzhouInstituteofChemicalPhysics,ChineseAcademyofSci?..

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  • 简介:Anewμ3-Otriiron(Ⅲ)complex[Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2(HOBZ=benzoicacid)hasbeensynthesized,itsstructurehasbeendeterminedandvariabletemperaturemagneticsusceptilityhasalsobeenmeasured.Inthemolecule,threeironatomsformedanequilateraltrianglewithu3-Oincenter.ThefittingtothemagneticsusceptibilityshowedthatanintramolecularantiferromagneticexchangeinteractionoccurredbetweenironatomswithJ=-25.51cm-1,andaweakerintermolecularantiferromagneticexchangeinteractionoccurredwithzJ’=-2.30cm-1.

  • 标签: Crystal STRUCTURE MAGNETIC exchange triiron complex.
  • 简介:留声机诞生于1877年.世界上第一个发明留声机的人就是誉满全球的发明大王——爱迪生.当时爱迪生发明的留声机轰动了整个纽约,各家报馆的新闻记者,像潮水般地涌来报道这一特大新闻.“一台会说话的机器”“一台会收藏声音的机器”,激起当时社会急速而巨大的狂热,外界舆论把留声机称之为19世纪的奇迹,即将开幕的巴黎世界博览会立即把它作为时新展品展出,就连当时美国总统海斯也在留声机旁转了两个多小时.

  • 标签: 留声机 发明 世界博览会 新闻记者 美国总统 爱迪生
  • 简介:合成了六铝酸盐SrNiAl11O19并用XRD、UVDRS、TGDTA和TEM等技术对其进行了表征。在750℃于SrNiAl11O19上进行的甲烷与二氧化碳重整反应表明,这类催化剂较Ni/SrAl12O19具有较大活性和低积碳能力,在催化反应过程中可有效地抑制Ni颗粒的增大。

  • 标签: 六铝酸盐甲烷重整Ni催化剂
  • 简介:Pureandneodymium-dopedgadoliniumcalciumoxoboratecrystalsofhighqualityweregrownbytheCzochralskimethod.Theorientationofcrystalwaspreciselydetermined,andthesamplesformeasurementswereprepared.Throughsynchrotronx-raytopographyandhigh-resolutionx-raydiffractometry,thetwinstructurewasdiscovered.Somepropertiessuchasthefigureofmeritvalue,anddielectric,piezoelectric,andelasticconstantsweremeausuredalongwithadiscussionoftheanisotropyofthelaserproperties.

  • 标签: GdCa4O(BO3)3晶体 钕掺杂 硼酸盐晶体 Nd:GdCa4O(BO3)3晶体 晶体生长 形貌学
  • 简介:我们在一个Y3Ga5O12(YGG)主人系统调查Bi3+和RE3+(RE=Tb或Eu)的光性质。Bi3+的另外的做能在这位主人提高Tb3+或Eu3+的光。到Tb3+和Eu3+的从Bi3+的精力转移被观察,精力转移的机制被调查。自从Bi3+排放乐队或Eu3+刺激乐队,转移能作为电的多极相互作用被解释的精力的机制重叠,当Tb3+或Eu3+的紧张随Tb3+或Eu3+集中的增加增加时,Bi3+排放紧张减少。因此,Bi3+离子是到在Y3Ga5O12主人的Tb3+和Eu3+使活跃之物的一种有效sensitizer。

  • 标签: 发光光谱 发光特征 能量传递
  • 简介:At-hyperwheel(t≥3)oflengthl(orW(t)lforbrevity)isat-uniformhypergraph(V,E),whereE={e1,e2,...,el}andv1,v2,...,vlaredistinctverticesofV=∪eii=1lsuchthatfori=1,...,l,vi,vi+1∈eiandei∩ej=P,j∈/{i1,i,i+1},wheretheoperationonthesubscriptsismodulolandPisavertexofVwhichisdifferentfromvi,1≤i≤l.Inthispaper,theminimumcoveringproblemofMCλ(3,W(3)4,v)isinvestigated.DirectandrecursiveconstructionsonMCλ(3,W(3)4,v)arepresented.Thecoveringnumbercλ(3,W(3)4,v)isfinallydeterminedforanypositiveintegersv≥5andλ.

  • 标签: 最小覆盖问题 一致超图 递归结构 Tgt 直接和 覆盖数
  • 简介:Europium(Ⅲ)-dopedYF3ispreparedbyahydrothermalprocessat200℃.X-raydiffraction(XRD)patternidentifiestheformationofYF3phasewithoutdetectableimpurity.Environmentscanningelectronmicroscopy(ESEM)imageshowstheevensizedistributionofthesampleswithcubicmorphology.TheexcitationandemissionspectraoftherareearthionsdopedYF3areinvestigatedbyfluorescencespectrophotometer.Theexcitationspectrumfor591nmemissionhasseveralexcitationbandsat320,365,386,397and467nm,andthemainpeakvaluewas397nm.TypicalEu3+emissionpeaksat591nm(5D0→7F1)and612nm(5D0→7F2)areobservedwhenexcitedby397nm,andthestrongestemissionis591nm,demonstratingthattherareearthionsoccupythecentrosymmetricalsitesinYF3.

  • 标签: HYDROTHERMAL synthesis RARE earth ion YF3
  • 简介:Ca3Y2(BO3)(4):Eu3+黄磷被高温度solid-statereaction方法综合,并且光特征被调查。排放光谱在相应于电的dipoleD-5(0)的613和621nm展出二强壮的红排出物在365nm刺激下面的Eu3+的-F-7(2)转变,原因是Eu3+代替forY3+在Ca3Y2(BO3)(4)的水晶结构占据非中心对称的位置。为613nm的Theexcitation光谱显示黄磷能是有效地激动的由紫外(紫外)(254nm,365nm和400nm)并且蓝色(470nm)光。Ca3Y2(BO3)(4)的排放紧张上的Eu3+集中的效果:Eu3+黄磷被测量,排放紧张与增加Eu3+集中增加的结果表演,然后减少。Ca3Y2(BO3)(4)的CIE颜色坐标:Eu3+黄磷是(0.639,0.357)在15mol%Eu3+。

  • 标签: 发光特征 高温 固体 光谱
  • 简介:[Co3(1,2-S2C6H4)3(PPh3)3][CoBr3(DMF)].sol(1,sol=CHCl3,O(C2H5)2,H2O)wasobtainedfromthereactionofCoBr(PPh3)3withNa2(S2C6H4)inchloroform.TheCo3coreinthecationof1exhibitsametal-metalbondedisoscelestriangle,inwhichthetwolongerCo-CobondsarebothbridgedbyS2C6H4ligandsontwosidesofthetriangleplanerespectively,whilethebottomshortCo-CobondisbridgedbythethirdbidentateS2C6H4ligand.Aseriesofpolynu-clearcobaltclustercompoundswithphosphine,thiolateand/orsulphurligandswerepreparedbylowoxidationstateCo+withthiolatesinorganicsolvents.Thesetri-,tetra-,hexa-,heptanuclearclustercompounds1-8withvarioustypesofcrystalstructurescanbeviewedasthecondensedpolynuclearcobaltcomplexesthatthecobaltatomframeworkswithsulphurbridgedwerebuiltthroughthesmalltriangularunitsof[Co3S3nL3](n=1,2)withorwithout[CoL](L=PR3,Br,Cl,5-C5H5)fragments.

  • 标签: POLYNUCLEAR cobalt THIOLATE PHOSPHINE structure.
  • 简介:Thebaryonspectrumandthebaryoncouplingsaretwoofthemostimportantissuesinhadronicphysicsandtheyareattractingmuchattention.Bothontheexperimentalandtheoreticalsides,thenucleonexcitedstatesbelow2.0GeVhavebeenextensivelystudied[1].However,thecurrentinformationforthepropertiesofstatesaroundorabove2.0GeVisscarce.Ontheotherhand,inthisenergyregion,manytheoreticalapproacheshavepredictedmissingNstates,whichhavenotbeensofarobserved.Hence,thestudyofthepossibleroleplayedbythe2.0GeVregionnucleonresonancesintheavailableaccuratedataistimelyandcouldshedlightintothecomplicateddynamicsthatgovernsthehighexcitednucleonspectrum.

  • 标签: PHOTON HADRONIC Productions
  • 简介:LECR4isthefirstECRionsourceusingevaporativecoolingtechnologyintheworld.Itsuniquefeatureisthatthesolenoidsweremadefromsolidsquarecopperwires(3.32mm×5.77mmwithinsulation),andthatallthecoilsareentirelyimmersedintheroomtemperaturecoolant.Thecoilscanproduceamaximumaxialmagneticfieldupto2.5T.LECR4aimstoprovideintensemultiplechargestateionbeamsforSSC-Linacproject-anewLinearinjectorfortheSeparatedSectorCyclotron(SSC).Presently,someionbeamswithdifferentM/QratiohavebeenacceleratedsuccessfullywiththeRFQandDTL,suchas200eμAof16O^5+,200eμAof40Ar^8+,50eμAof209Bi^30+etc.ThemeasuredtransmissionefficiencyofRFQisupto90%.ThelayoutofLECR4ionsourceandtheLEBTisshowninFig.1.

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