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  • 简介:摘要在当前水电站工程建设中,设计变更变更费用管理是当前工程项目建设管理工作中的一个重点内容。我们应该结合当前的变更问题,做好有效控制,避免不合理变更对工程项目的效益产生影响。本文就对当前水电站工程项目设计变更变更费用管理的相关问题进行了分析和探讨。

  • 标签: 水电站 设计变更 变更费用 管理思路
  • 简介:AnAu/ceria(0.44%,massfraction)catalystcontaininggoldionswaspreparedbyamodifieddepositionprecipitationmethod,andtheevolutionofgoldionsinthecatalystanditsinfluenceonthecatalysisofCOoxidationwereinvestigated.Itwasfoundthattheas-preparedcatalystcontaininggoldionswithhighvalencecouldfullyoxidizeCOat–10°CinitiallybutwasdeactivatedgraduallyatlowtemperaturesduringthereactionwithCOortreatmentbyunpurifiedair.ThedeactivationofthecatalystduringCOoxidationortreatmentofitbyunpurifiedairwasindependentandprogressiveatlowtemperatureswhiletheactivityofthecatalystatrelativelyhightemperatureswasmaintainedwell.DuringthereactionwithCOortreatmentbyunpurifiedair,theXPSresultsindicatethatgoldspeciesevolvedfromhighvalencetolowvalenceandthediffusereflectanceUV-Visspectrashowthathighvalencegoldwasreducedtochargedgoldclusters,goldclustersgrewtosmallgoldcrystalsandsmallgoldcrystalsgrewtolargegoldparticles.Accordingly,thehighvalencegoldcorrespondedtotheactivityatlowtemperaturesandthemetallicgoldwasactiveandrelativelystableathightemperatures.Theturnoverfrequencies(TOF)ofthecatalyststreatedbydifferentmethodsat273Kdecreasedwiththeevolutionofgoldspeciesfromhighvalencetolowvalence,nomaximumofTOFwasobservedalthoughgoldparticlesinthecatalystattainedtoabout2―3nmduringthetreatment.AnAu/ceriacatalystwithagoldloadof0.87%(massfraction)maintainedagoodactivityforCOoxidationwithin18hatroomtemperature.Thecatalystswerecharacterizedviatransmittedelectronicmicroscopy(TEM),inductivelycoupledplasmaopticalemissionspectrometry(ICP-OES),X-raydiffraction(XRD)andBETspecificsurfaceareaandUV-VisDRSaswell.

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  • 简介:ThreeseriesofCeO2/CuOsampleswerepreparedbyimpregnationmethodandcharacterizedbyXRD,N2adsorption-desorption,temperatureprogrammedreduction(TPR),XPSandTEMtechniques.IncomparisonwiththesamplespreparedwithCuOasinitialsupport,thesampleswithCu(OH)2asinitialsupporthavehigherreducibilitiesandsmallerrelativeTPRpeakareas,andalsolargerspecificsurfaceareasatcalcinationtemperaturesof400℃–600℃.Asaresult,Cu(OH)2isbetterthanCuOasinitialsupportforpreferentialoxidationofCOinexcessH2(CO-PROX).Thebestcatalyticperformancewasachievedonthesamplecalcinedat600℃andwithanatomicratioofCe/Cuat40%.XPSanalysesindicatethatmoreinterfacelinkagesCe-O-Cucouldbeformedwhenitwascalcinedat600℃.AndtheatomicratioofCe/Cuat40%ledtoaproperreducibilityforthesampleasillustratedbytheTPRmeasurements.

  • 标签: 氧化铜催化剂 选择性氧化 氧化铈 支护效果 二氧化碳 程序升温还原
  • 简介:ThemorphologyeffectofZr-dopedCeO2wasstudiedintermsoftheiractivitiesintheselectiveoxidationofstyrenetostyreneoxideusingtert-butylhydroperoxideastheoxidant.Inthepresentwork,ZrdopedCeO2nanorodsexhibitedthehighestcatalyticperformance(yieldofstyreneoxideandTOFvalue)followedbynanoparticlesandnanocubes.FortheZr-dopedCeO2nanorods,theapparentactivationenergyis56.3kJ/mol,whichismuchlowerthanthevaluesofcatalystssupportedonnanoparticlesandnanocubes(73.3and93.4kJ/mol).Thehighresolutiontransmissionelectronmicroscopyresultsindicatedthat(100)and(110)crystalplanesarepredominantlyexposedforZr-dopedCeO2nanorodswhile(100)and(111)fornanocubes,(111)fornanoparticles.TheremarkablyincreasedcatalyticactivityoftheZrdopedCeO2nanorodsismainlyattributedtothehigherpercentageofCe3+speciesandmoreoxygenvacancies,whichareassociatedwiththeirexposed(100)and(110)crystalplanes.Furthermore,recyclingstudiesprovedthattheheterogeneousZr-dopedCeO2nanorodsdidnotloseitsinitialhighcatalyticactivityafterfivesuccessiverecycles.

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  • 简介:CuO-CeO2catalystswerepreparedbyaureaprecipitationmethodfortheoxidativesteamreformingofethanolatlow-temperature.Thecatalyticperformancewasevaluatedandthecatalystswerecharacterizedbyinductivelycoupledplasmaatomicemissionspectroscopy,X-raydiffraction,temperature-programmedreduction,fieldemissionscanningelectronmicroscopyandthermo-gravimetricanalysis.OverCuOCeO2catalysts,H2withlowCOcontentwasproducedinthewholetestedtemperaturerangeof250–450C.Thenon-noblemetalcatalyst20CuCeshowedhigherH2productionratethan1%Rh/CeO2catalystat300–400Candtheadvantagewasmoreobviousafter20htestingat400C.TheseresultsfurtherconfirmedthatCuO-CeO2catalystsmaybesuitablecandidatesforlowtemperaturehydrogenproductionfromethanol.

  • 标签: CuO-CeO2 catalyst hydrogen production OXIDATIVE steam
  • 简介:一、引言投资是企业最为重要的经济活动之一,提高投资效率一直以来是经济学与管理学研究的热点问题。近年来,我国上市公司非效率投资行为的普遍性引起社会各界的广泛关注,其中,相较于投资不足而言,

  • 标签: 投资行为 实证分析 面板数据 企业 董事会 CEO
  • 简介:HighactiveandstablegoldcatalystssupportedoncrystallineFe2O3andCeO2/Fe2O3werepreparedviathedeposition-precipitationmethod.ThecatalystwithaAuloadof1.0%calcinedat180°CshowedaCOconversionof100%at-8.9°C,whileAu/CeO2/Fe2O3convertedCOcompletelyat-16.1°C.Evenhavingbeencalcinedat500°C,Au/Fe2O3stillexhibitedsignificantcatalyticactivity,achievingfullconversionofCOat61.6°C.ThecatalystwithalowAuloadof0.5%couldconvertCOcompletelyatroomtemperatureandkepttheactivityunchangedforatleast150h.N2adsorption-desorptionmeasurementsshowthatthecrystallinesupportspossessedahighspecificsurfaceareaofabout200m2/g.CharacterizationsofX-raydiffractionandtransmissionelectronmicroscopyindicatethatgoldspecieswerehighlydispersedasnanoorsub-nanoparticlesonthesupports.Evenafterthecatalystwascalcinedat500°C,theAuparticlesremainedinanano-sizeofabout6―10nm.X-rayphotoelectronspectrarevealthatthesupportedAuexistedinmetallicstateAu0.ThemodificationofAu/Fe2O3byCeO2provedtobebeneficialtotheinhibitionofcrystallizationofFe2O3andthestabilizationofgoldparticlesindispersedstate,consequentlypromotingcatalyticactivity.

  • 标签: 金催化剂 CO氧化 氧化铁 Au/Fe2O3 去甲肾上腺素 X射线光电子能谱
  • 简介:根据国家新闻出版总署主编任职条件,中国惯性技术学会聘请刘飞同志任《中国惯性技术学报》第五届编委会主任委员兼主编,原主编刘玉峰同志任第五届编委会副主任委员兼执行主编。

  • 标签: 惯性技术 编委会 中国 学报 人事 任职条件