简介:AbinitiomolecularorbitalcalculationsofdoublynegativechargedB16H162-(D2)andneutralB16H16(Td)havebeendoneattheHF/6-31Glevel.TheyarepredictedtobechemicallyandkineticallystablebyvibrationalanalysesontheirrespectiveenergyhypersurfaceoftheHF/6-31Glevel.ThegeometricalstructureofthespeciesB16H1622-(D2)wasdiscussed.
简介:Aseriesof2’-purineandpyrimidinederivativesof1’,4’-anhy-dro-2’-deoxy-D-arabitol(1)and1’,4’-anhydro-2’-deoxy-D-altritol(2)weresynthesizedregio-andstereo-selectivelyfromD-sorbitolthroughsomeconversioninhighyields.
简介:The2Dplanegasflowunderheating(withnonentityboundarycondition)hasbeendiscussedbytheanalyticalapproachinthispaper.Theapproximateanalyticalsolutionshavebeenobtainedfortheflowpassingvariouskindsofheatsources.Solutionsdemonstratethethermaldisplacementphenomenaarestronglydependontheheatingintensity.
简介:Cavitationisoneofthetroublesomeproblemsinrocketturbopumps,andsincemostofhigh-efficiencyrocketpropellantsarecryogenicfluids,socalled'thermodynamiceffect'becomesmoreevidentthaninwater.Inthepresentstudy.numericalandexperimentalstudyofliquidnitrogencavitationin2DLavalnozzlewascarriedout,sothattheinfluenceofthermodynamiceffectwasexamined.Itwasrevealedthattemperatureandcavitationhavestronginter-relationshipwitheachotherinthermo-sensitivecryogenicfluids.
简介:Solutionstoapiezoelectrichalf-planewithafixedconductorsurfaceelectrodesubjectedtotwogeneralizedsingularities(linedislocationand/orlineforceandfreecharge)arepresented.Coulombforcesactingonthesingularitiesduetotheboundarypolarizationchargesofmediumandtheinductioncharg-esofconductorelectrodeareanalyzedindetail.Theinteractionbetweenthetwosingularitiesisalsoanalyzednumerically.ResultsshowthatCoulombforceswillbecomeimportantasthefreechargeapproachestheboundaryortwosingularitiesmoveclosely.
简介:Thedipole-length,velocityandaecelerationabsorptionoscillatorstrengthsforthe1s^22p-ls^2nd(3_
简介:PhaseShiftingAndLogicalMoire(PSALM)isakindofcomputerimageprocessingmethodwhichcanbeusedinphasemeasurementandtoobtaintheshape,deformationandstraindistributionofanobject.Thispaperpresentsthestructureandworkingprocedureofa2DphasemeasurementPSALM2Dprogramanditsapplication.Whenanalyzingmoireinterferometricfringes,wecanobtain2Ddistributionofdisplacementandstrain.Whenitisusedinreflectionmoirewecanmeasuretheslopeofaspecimen.SatisfactoryvisualizationandquantitativeresultsaregivenbyPSALM2D.
简介:DistributionofmetalsonPd-SnO2/D3520catalystsandstateofthecatalystswrerstudiedwithSEM,XRD.TheinteractionbetweenmetalsandsupportorbetweenPdandSnorPbwerestudiedbyIR,XPS.Inaddition,therelationshipoftheactivityforcatalytichydrogenationoftheolefinsandouterlayervalenceelectrondensityofPdwasdiscussed.Theresultsshowedthatthesecatalystshadsuitablesurfacestate,themetalswereuniformlydispersedonthesurfacelayerofthesupport.Therewerenotobviousinteractionbetweenthemetalsandthesupport.TherewasstronginteractionbetweenPdandSn(orPb)inthecatalysts.ThecatalyticactivityforhydrogenationwasrelatedtoouterlayervalenceelectrondensityofPd.
简介:DistributionofmetalsonPd-SnO2/D3520catalystsandstateofthecatalystswerestudiedwithSEM,XRD.TheinteractionbetweenmetalsandsupportorbetweenPdandSnorPbwerestudiedbyIR,XPS.Inaddition,therelationshipoftheactivityforcatalytichydrogenationoftheolefinsandouterlayervalenceelectrondensityofPdwasdiscussed.Theresultsshowedthatthesecatalystshadsuitablesurfacestate,themetalswereuniformlydispersedonthesurfacelayerofthesupport.Therewerenotobviousinteractionbetweenthemetalsandthesupport.TherewasstronginteractionbetweenPdandSn(orPb)inthecatalysts.ThecatalyticactivityforhydrogenationwasrelatedtoouterlayervalenceelectrondensityofPd.
简介:Theboundaryelementmethodisusedforthemodalanalysisoffreevibrationof2-Dcompositestructuresinthispaper.Sincetheparticularsolutionmethodisusedtotreatthetermsofbodyforces(inertialforces)intheequationofmotion,onlystaticfundamentalsolutionsareneededinsolvingtheproblem.Foranisotropiccantileverbeam,thenumericalresultsobtainedbyusingtheBEMpresentedinthispaperareingoodagreement,withthoseofusingFEMorotherBEM,butthisBEMcanalsobeusedtoanalyzeproblemsforanisotropicmaterials.Forsimplysupportedcompositelaminatedbeams,thecomparisonsofthenumericalresultsobtainedbythismethodwiththeanalyticalresultsobtainedby1-Dlaminatedbeamtheoryindicatethatiftheratiooflength/thicknessisgreaterthan20,theresultsofthetwomethodsareingoodagreement,butiftheratiooflength/thicknessislessthan20,bigerrorswilloccurfor1-Dlaminatedbeamtheory.
简介:AfiniteelementmethodforthesolutionofOseenequationinexteriordomainisproposed.Inthismethod,acircularartificialboundaryisintroducedtomakethecomputationaldomainfinite.Then,theexactrelationbetweenthenormalstressandtheprescribedvelocityfieldontheartificialboundarycanbeobtainedanalytically.Thisrelationcanserveasanboundaryconditionfortheboundaryvalueproblemdefinedonthefinitedomainboundedbytheartificialboundary.Numericalexperimentispresentedtodemonstratetheperformanceofthemethod.
简介:Asimplemethodisappliedtocalculatingtheisotopeshifts(ISs)on5S1/2→4D3/2,5/2transitionsof87,88Sr+.FirstwehavecalculatedtheISsoflowertransitionsonaseriesofalkali-likesystemssuchasB2+,Ca+andBa+,whichareinagreementwithotherworks.ThentheISson5S1/2→4D3/2,5/2transitionsof87,88Sr+,whichareusefultostudytheSr+opticalfrequencystandard,areevaluated.