学科分类
/ 25
500 个结果
  • 简介:

  • 标签:
  • 简介:AbinitiomolecularorbitalcalculationsofdoublynegativechargedB16H162-(D2)andneutralB16H16(Td)havebeendoneattheHF/6-31Glevel.TheyarepredictedtobechemicallyandkineticallystablebyvibrationalanalysesontheirrespectiveenergyhypersurfaceoftheHF/6-31Glevel.ThegeometricalstructureofthespeciesB16H1622-(D2)wasdiscussed.

  • 标签: Closo BORON hydrides ab INITIO MOLECULAR
  • 简介:Aseriesof2’-purineandpyrimidinederivativesof1’,4’-anhy-dro-2’-deoxy-D-arabitol(1)and1’,4’-anhydro-2’-deoxy-D-altritol(2)weresynthesizedregio-andstereo-selectivelyfromD-sorbitolthroughsomeconversioninhighyields.

  • 标签: STEREOSELECTIVE SYNTHESIS 2’-isonucleosides D-sorbitol
  • 简介:

  • 标签:
  • 简介:The2Dplanegasflowunderheating(withnonentityboundarycondition)hasbeendiscussedbytheanalyticalapproachinthispaper.Theapproximateanalyticalsolutionshavebeenobtainedfortheflowpassingvariouskindsofheatsources.Solutionsdemonstratethethermaldisplacementphenomenaarestronglydependontheheatingintensity.

  • 标签: 热流体流 热位移 解析解
  • 简介:Cavitationisoneofthetroublesomeproblemsinrocketturbopumps,andsincemostofhigh-efficiencyrocketpropellantsarecryogenicfluids,socalled'thermodynamiceffect'becomesmoreevidentthaninwater.Inthepresentstudy.numericalandexperimentalstudyofliquidnitrogencavitationin2DLavalnozzlewascarriedout,sothattheinfluenceofthermodynamiceffectwasexamined.Itwasrevealedthattemperatureandcavitationhavestronginter-relationshipwitheachotherinthermo-sensitivecryogenicfluids.

  • 标签: 计算流体力学 CFD 喷流 两相流 空化 低温
  • 简介:设α是正实数,[α0;α1,α2。…]是α的简单连分数;d是非平方整数,d1、d2是适合d1d2=d,1≤d1<d2,gcd(d1,d2)=1的正整数,本文证明了:当且仅当α=(d2/d1)(1/2)时,α=[α0α1,…αn-1,2α0],其中α0>0,αi=αn-1(i=1…,α-1).

  • 标签: 简单连分数 正整数 渐近分数 当且仅当 定理 引理
  • 简介:Solutionstoapiezoelectrichalf-planewithafixedconductorsurfaceelectrodesubjectedtotwogeneralizedsingularities(linedislocationand/orlineforceandfreecharge)arepresented.Coulombforcesactingonthesingularitiesduetotheboundarypolarizationchargesofmediumandtheinductioncharg-esofconductorelectrodeareanalyzedindetail.Theinteractionbetweenthetwosingularitiesisalsoanalyzednumerically.ResultsshowthatCoulombforceswillbecomeimportantasthefreechargeapproachestheboundaryortwosingularitiesmoveclosely.

  • 标签: Green’s FUNCTIONS COULOMB FORCES LINE DISLOCATION
  • 简介:Thedipole-length,velocityandaecelerationabsorptionoscillatorstrengthsforthe1s^22p-ls^2nd(3_2=11to20arecalculatedusingtheenergiesandthemulticonfiguratloninteractionwavefunctionsobtainedfromafullcorepluscorrelationmethod.Theagreementbetweenthef-valuescalculatedfromthelength,velocityandaccelerationformulaeisexcellent.Ourresultsagreecloselywiththeexperimentaldataavailableintheliterature.Combiningthesediscreteoscillatorstrengthswiththesingle-channelquantumdefecttheory,thediscreteoscillatorstrengthsforthetransitionsfrom1s^22pstatetohighlyexcitedstates(n_>10)andtheoscillatorstrengthdensitiescorrespondingtothebound-freetransitionsareobtained.

  • 标签: 类锂系统 振荡器 量子缺陷 电离化原子系统 原子物理学
  • 简介:PhaseShiftingAndLogicalMoire(PSALM)isakindofcomputerimageprocessingmethodwhichcanbeusedinphasemeasurementandtoobtaintheshape,deformationandstraindistributionofanobject.Thispaperpresentsthestructureandworkingprocedureofa2DphasemeasurementPSALM2Dprogramanditsapplication.Whenanalyzingmoireinterferometricfringes,wecanobtain2Ddistributionofdisplacementandstrain.Whenitisusedinreflectionmoirewecanmeasuretheslopeofaspecimen.SatisfactoryvisualizationandquantitativeresultsaregivenbyPSALM2D.

  • 标签: logical MOIRE phase SHIFTING IMAGE PROCESSING
  • 简介:DistributionofmetalsonPd-SnO2/D3520catalystsandstateofthecatalystswrerstudiedwithSEM,XRD.TheinteractionbetweenmetalsandsupportorbetweenPdandSnorPbwerestudiedbyIR,XPS.Inaddition,therelationshipoftheactivityforcatalytichydrogenationoftheolefinsandouterlayervalenceelectrondensityofPdwasdiscussed.Theresultsshowedthatthesecatalystshadsuitablesurfacestate,themetalswereuniformlydispersedonthesurfacelayerofthesupport.Therewerenotobviousinteractionbetweenthemetalsandthesupport.TherewasstronginteractionbetweenPdandSn(orPb)inthecatalysts.ThecatalyticactivityforhydrogenationwasrelatedtoouterlayervalenceelectrondensityofPd.

  • 标签: 结构 D3520催化剂 二氧化锡
  • 简介:DistributionofmetalsonPd-SnO2/D3520catalystsandstateofthecatalystswerestudiedwithSEM,XRD.TheinteractionbetweenmetalsandsupportorbetweenPdandSnorPbwerestudiedbyIR,XPS.Inaddition,therelationshipoftheactivityforcatalytichydrogenationoftheolefinsandouterlayervalenceelectrondensityofPdwasdiscussed.Theresultsshowedthatthesecatalystshadsuitablesurfacestate,themetalswereuniformlydispersedonthesurfacelayerofthesupport.Therewerenotobviousinteractionbetweenthemetalsandthesupport.TherewasstronginteractionbetweenPdandSn(orPb)inthecatalysts.ThecatalyticactivityforhydrogenationwasrelatedtoouterlayervalenceelectrondensityofPd.

  • 标签: 结构特征 二氧化锡 D3520催化剂
  • 简介:Theboundaryelementmethodisusedforthemodalanalysisoffreevibrationof2-Dcompositestructuresinthispaper.Sincetheparticularsolutionmethodisusedtotreatthetermsofbodyforces(inertialforces)intheequationofmotion,onlystaticfundamentalsolutionsareneededinsolvingtheproblem.Foranisotropiccantileverbeam,thenumericalresultsobtainedbyusingtheBEMpresentedinthispaperareingoodagreement,withthoseofusingFEMorotherBEM,butthisBEMcanalsobeusedtoanalyzeproblemsforanisotropicmaterials.Forsimplysupportedcompositelaminatedbeams,thecomparisonsofthenumericalresultsobtainedbythismethodwiththeanalyticalresultsobtainedby1-Dlaminatedbeamtheoryindicatethatiftheratiooflength/thicknessisgreaterthan20,theresultsofthetwomethodsareingoodagreement,butiftheratiooflength/thicknessislessthan20,bigerrorswilloccurfor1-Dlaminatedbeamtheory.

  • 标签: COMPOSITE structure BOUNDARY ELEMENT METHOD particular
  • 简介:AfiniteelementmethodforthesolutionofOseenequationinexteriordomainisproposed.Inthismethod,acircularartificialboundaryisintroducedtomakethecomputationaldomainfinite.Then,theexactrelationbetweenthenormalstressandtheprescribedvelocityfieldontheartificialboundarycanbeobtainedanalytically.Thisrelationcanserveasanboundaryconditionfortheboundaryvalueproblemdefinedonthefinitedomainboundedbytheartificialboundary.Numericalexperimentispresentedtodemonstratetheperformanceofthemethod.

  • 标签: Artificial BOUNDARY EXTERIOR DOMAIN Oseen equation.
  • 简介:Asimplemethodisappliedtocalculatingtheisotopeshifts(ISs)on5S1/2→4D3/2,5/2transitionsof87,88Sr+.FirstwehavecalculatedtheISsoflowertransitionsonaseriesofalkali-likesystemssuchasB2+,Ca+andBa+,whichareinagreementwithotherworks.ThentheISson5S1/2→4D3/2,5/2transitionsof87,88Sr+,whichareusefultostudytheSr+opticalfrequencystandard,areevaluated.

  • 标签: 原子物理 同位素位移 5S1/2→4D3/2 5/2 精细结构