简介:Anewcytotoxicpyrrolidinoindolinediketopiperazinedimer,cristatuminE(1),wasisolatedfromthefermentationbrothofthealgalfungusEurotiumherbariorumHT-2associatedwiththemarinealgae,Enteromorphaprolifera.ThestructurewasdeterminedbyspectroscopicanalysesandMarfey’saminoacidanalysis.CristatuminE(1)showedcytotoxicityagainstK562tumorcelllineandantibacterialactivityagainstEnterobacteraerogenesandEscherichiacoliwithIC50andMICvaluesof8.3,44.0and44.0mmol/L,respectively.
简介:Hightimeresolutionmeasurementsoftheelectrostaticfluctuations,radialelectricfieldErandturbulence-inducedelectronfluxΓehavebeenperformedacrossthetransitionoflowerhybridcurrentdriveimprovedconfinementwithagraphiteLangmuirprobearrayatthelastclosedfluxsurfaceoftheHT-7tokamak.ThedecreaseofΓeisdominatedbythesuppressionoffluctuationlevels,whichfollowsthechangeofEr.AreversalofthepoloidalpropagationdirectionofturbulencedemonstratesthatthepoloidalpropagationisdominatedbyEr×Bφdrift.Theenhancementofpoloidalcoherenceaccompaniesthefluctuationsuppression,whichsuggeststhesubtlevariationofturbulencefeatures.
简介:Inthisstudy,weinvestigatetheinfluenceofdopingonthechargetransferanddevicecharacteristicsparametersinthebulkheterojunctionsolarcellsbasedonpoly(3-hexylthiophene)(P3HT)andamethanofuUerenederivative(PCBM).Organicsemiconductorsarealsoknowntobenotpureandtheyhavedefectsandimpurities,someofthemarebeingchargedandactasp-typeorn-typedopants.Calculationsofthesolarcellcharacteristicsparametersversusthep-dopinglevelhavebeendoneatthreedifferentn-dopings(N_d)thatconsistof5×10~(17)cm~(-3),10~(18)cm~(-3),and5×10~(18)cm~(-3).Weperformtheanalysisofthedopingconcentrationthroughthedrift-diffusionmodel,andcalculatethecurrentandvoltagedopingdependency.Wefindthatatthreedifferentn-dopantlevels,optimump-typedopingisaboutN_p=6×10~(18)cm~(-3).Simulationresultshaveshownthatbyincreasingdopinglevel,V_(oc)monotonicallyincreasesbydoping.CellefficiencyreachesitsmaximumatsomewhathigherdopingasFFhasitspeakatN_p=3×10~(18)cm~(-3).Moreover,thispaperdemonstratesthattheoptimumvalueforthep-dopingisaboutN_p=6×10~(18)cm~(-3)andoptimumvalueforn-dopantisN_d=10~(18)cm~(-3),respectively.Thesimulatedresultsconfirmthatdopingconsiderablyaffectstheperformanceoforganicsolarcells.
简介:Theefficiencyofthepoly(3-hexylthiophene)(P3HT)and[6,6]-phenylC61-butyricacidmethylester(PC61BM)basedorganicsolarcellswasenhancedbyusing1,2,4-trichlorobenzene(TCB)asaprocessingadditivetocontroltheblendmorphology.TheadditionofTCBimprovedthearrangementofP3HTwhichresultedingoodphaseseparatedblendfilms.Correspondingly,theoptimizedsolarcellsshowedapowerconversionefficiency(PCE)of4.17%withafillfactor(FF)of0.69,whichwerehigherthanthoseofcommonthermalannealingdevices(PCE3.84%,FF0.67).Theefficiencywasfurtherimprovedto4.74%bythermalannealingat150°Cfor10minwithahigherFFof0.74.