学科分类
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6 个结果
  • 简介:TheinfluencesofboththevolumeofPS/toluenesolutionintheUbbelohdeviscometerandtheprecisionofthetimemeasuringontheviscositybehaviorindiluteandextremelydiluteconcentrationregionareinvestigatedItwasfoundthattheinfluenceoftheformercanneglect,butthatofthelatterissoprominentthatthedatafluctuatebitterlyandlinearityofthecurveofthereducedviscosityvs.Concentration(ηsp/c~c)becomestoobadtoobeytheHugginsequationdowntotheextremelydiluteregion,despitetheerroroftheflowtimes△t≤0.2s,whichispermittedbytheconventionalmethodofviscositymeasurement.Throughstrictmathematicalanalyses,itwasfoundthatthcerror(E)ofthereducedviscosityisinproportionandinverseproportionto△tandconcentrationc,respectively.Sothelesstheconcentration,themoretheerroris.Consequently,alowestconcentrationlimitcLcorrespondingtogivenexperimentalerrormayexistanditwillbemeaninglessforfurtheroperationbelowcLbecauseofthegreatfluctuationofthedata.Therefore,itneedstoseriouslyreconsidertheapplicationoftheconventionalmethodofUbbelohdeviscositymeasurementintheextremelydilutepolymersolutionundertraditionalconditionsbecauseofthegreatinfluenceoftheexperimentalerror.

  • 标签: 粘性 聚苯乙烯/甲苯溶液 实验误差 粘度计 稀释溶液 物理性质
  • 简介:Associationbehaviorofethylenevinylacetate(EVA)copolymerinfoursolvents1,2-dichloroethane(DCE),cyclohexane(CYH),xylene(XYL)andchloroform(CF)hasbeeninvestigatedbydilutesolutionviscometryThecriticalassociationconcen-tration(CA)wasdeterminedatwhichtheincipientdecreaseinslopeoftheηsp/C~Ccurveinsolutionsatthediluteregime.OurresultsshowedthatwhethertheCAcouldexistdependsonsolventproperty.ThevaluesofCAinDCEincreasewithincreasing,oftemperatureandvinylacetate(VA)contentinEVAanddecreasingofmolecularweightofEVA.

  • 标签: ASSOCIATION DILUTE solution VISCOMETRY
  • 简介:Westudythetransitiontoturbulenceofchannelflowoffinite-sizeparticlesuspensionsatlowvolumefraction,i.e.,Φ≈0.001.ThecriticalReynoldsnumberabovewhichturbulenceissustainedreducestoRe≈1675,inthepresenceoffewparticles,independentlyoftheinitialcondition,avaluelowerthanthatofthecorrespondingsingle-phaseflow,i.e.,Re≈1775.Inthedilutesuspension,theinitialarrangementoftheparticlesisimportanttotriggerthetransitionatafixedReynoldsnumberandparticlevolumefraction.Asinsinglephaseflows,streamwiseelongateddisturbancesareinitiallyinducedintheflow.Ifparticlescaninduceobliquedisturbanceswithhighenoughenergywithinacertaintime,thestreaksbreakdown,flowexperiencesthetransitiontoturbulenceandtheparticletrajectoriesbecomechaotic.Otherwise,thestreaksdecayintimeandtheparticlesimmigratetowardsthechannelcoreinalaminarflow.

  • 标签: 悬浮液 颗粒体积分数 颗粒悬浮 雷诺兹数 粒子轨迹 单相流
  • 简介:Interactionsofthreeheavymetalions,Cu2+,Cd2+,andPb2+,and,forcomparison,Na+withelectrodialyticclayfractions(lessthan2μmindiameter)offourpaddysoilsaswellasayellow-brownsoilasacontrolsoilwereevaluatedbasedonmeasurementsoftheWieneffectindilutesuspensionswithaclayconcentrationof10gkg-1infournitratesolutionsof2×10-4/zmolL-1,wherezisthecationvalence,andanitricacidsolutionof3×10-5molL-1.Fieldstrengthsrangingfrom15to230kVcm-1wereappliedformeasuringtheelectricalconductivities(ECs)ofthesuspensions.Themeanfreebindingenergiesbetweenthevariouscationsandallofthesoilsdeterminedfromexchangeequilibriumincreasedintheorder:Na+Cu2+>Cd2+>Pb2+foralltestedsoils.AcharacteristicparameteroftheREC-fieldstrengthcurves,△REG200,REGatafieldstrengthof200kVcm-1minusthatatthelocalminimumoftheconcavesegmentoftheREC-fieldstrengthcurves,characterizedthestrengthofadsorptionofthecationsstrippedoffbytheappliedstrongelectricalfield,andforallsoilsthevaluesof△REC200weregenerallyintheorder:Na+

  • 标签: 结合能 电导率 磁场强度 重金属 土壤
  • 简介:Researchonnewtypesofcastables,pre-castassemblypartsandthermalinsulationmaterialswithgoodresistancetowear,thermalshockanderosion,andlowthermalconductivity,wasdonetosolveproblemsofhighsystemenergyconsumption,crackingandspallingofpartialliningandmismatchoffurnacetopmaterialandhangingmaterialandsoon,causedbyunreasonabledesignofChina'sAl(OH)3dilutephasefluidizedbedroastingfurnacelining.Severaldifficultproblemssuchasthematchingofdifferentmaterials,preservationofexpansionjointsamongdifferentzonesandreasonablemechanicaldistributionofliningweresolved.'Integratedfurnace'conceptwasestablishedincludingrefractoriesR&D,liningstructuredesign,constructionoptimization,furnacewarmingtechnology,initialoperationandliningmaintenancetechnology.Thekeytechnologiesofhigh-efficiencyandenergy-savingforfurnacesweredeveloped.TheseachievementshavebeenappliedtoChina'sAl(OH)3dilutephasefluidizedbedroastingfurnacestoreduceenergyconsumptionby1000MJpertonalumina,enhancethecapacityandreducetheexhaustgasemission.

  • 标签: AL(OH)3 流化床 能源效率 稀相 烧烤炉 技术