简介:从月亮的采样地点(总计的46sampling地点)的ClementineUVVIS和NIR数据被处理并且过去常精制LeMoueic等的铁决心方法(2000,2002)。我们发现大约21个采样地点是对LeMoueic等不合适“s光谱参数(”斜坡“并且”深度1'')因为他们的1500nm过滤器不能被用作光谱参数“右肩膀并且评估1-μm的深度吸收特征精确地。Weused精制方法的25个采样地点由LeMoueic等开发了的剩余的。(2000,2002)并且获得了我们FeO内容决心的自己的方程。我们测试了我们的自己的方程,和结果是satifactory。在我们的工作,我们也在我们Chang的自己的数据集的科学应用程序获得了一些有用经验“E-1使命。
简介:摘要 本文分析了FeO含量对烧结产量、转鼓强度及冶金性能的影响,通过综合考虑FeO含量与各项指标的关系,确定烧结矿FeO含量适宜值为7.5%~9.0%
简介:TheadsorptionofCOonPtgroupmetals,asamostfundamentalelementaryreactionstep,hasbeenwidelystudiedincatalysisandelectrocatalysis.Particularly,thestructuresofCOonPt(111)havebeenextensivelyinvestigated,owingtoitsimportancetobothfundamentalandappliedcatalysis.Yet,muchlessisknownregardingCOadsorptiononaPt(111)surfacemodulatedbysupportedoxidenanostructures,whichisofmorerelevancetotechnicalcatalysis.Wethusinvestigatedthecoverage-dependentadsorptionofCOonaPt(111)surfacepartiallycoveredbyFeOxnanostructures,whichhasbeendemonstratedasaremarkablecatalystforlow-temperatureCOoxidation.Wefoundthat,duetoitsstrongchemisorption,thecoverage-dependentstructureofCOonbarePtisnotinfluencedbythepresenceofFeOx.But,oxygen-terminatedFeOxnanostructurescouldmodulatethediffusivityofCOattheirvicinity,andthusaffecttheformationoforderedCOsuperstructuresatlowtemperatures.Usingscanningtunnelingmicroscopy(STM),weinspectedthediffusivityofCO,followedthephasetransitionsofCOdomains,andresolvedthemoleculardetailsofthecoverage-dependentCOstructures.OurresultsprovideafullpictureforCOadsorptiononaPt(111)surfacemodulatedbyoxidenanostructuresandshedlightsontheinter-adsorbateinteractiononmetalsurfaces.
简介:基于炉渣结构分子和离子共存理论,建立1273-1733K下的PbO-CaO-SiO2-FeO-Fe2O3渣系氧化铅活度热力学模型,计算PbO活度并绘制等活度曲线,考察炉渣碱度Q、氧化铁比率R和温度T对活度NPbO和活度系数γPbO的影响。结果表明,活度系数γPbO的模型计算值与文献测定值吻合程度高,说明该模型能较好地反映该渣系结构本质;NPbO呈拉乌尔正偏差,且随渣中PbO含量的升高而增大,但受温度的影响不明显;γPbO随Q的升高而增大;对于Q〉0.3的碱性渣,γPbO随R的升高而出现极大值。该研究结果可用于现代炼铅工艺的热力学研究和操作优化。
简介:AnewlayeredCu-basedoxychalcogenideBa3Fe2O5Cu2S2hasbeensynthesizedanditsmagneticandelectronicpropertieswererevealed.Ba3Fe2O5Cu2S2isbuiltupbyalternativelystacking[Cu2S2]2-layersandironperovskiteoxide[(FeO2)(BaO)(FeO2)]2-layersalongthecaxisthatareseparatedbybariumionswithFe3+fivefoldcoordinatedbyasquare-pyramidalarrangementofoxygen.Fromthebondvalencearguments,weinferredthatinlayeredCuCh-based(Ch=S,Se,Te)compoundsthe+3cationinperovskiteoxidesheetprefersasquarepyramidalsite,whilethelowervalencecationprefersthesquareplanarsites.Thestudiesonsusceptibility,transport,andopticalreflectivityindicatethatBa3Fe2O5Cu2S2isanantiferromagneticsemiconductorwithaNe′eltemperatureof121Kandanopticalbandgapof1.03eV.Themeasurementofheatcapacityfrom10Ktoroomtemperatureshowsnoanomalyat121K.TheDebyetemperatureisdeterminedtobe113K.TheoreticalcalculationsindicatethattheconductionbandminimumispredominantlycontributedbyO2pand3dstatesofFeionsthatantiferromagneticallyarrangedinFeO2layers.TheFe3dstatesarelocatedatlowerenergyandresultinanarrowbandgapincomparisonwiththatoftheisostructuralSr3Sc2O5Cu2S2.