简介:Afugacitymodelwasdevelopedforpredictionofmixedrefrigerantgashydratesformationconditionsbasedonthemoleculecongregationandsolutiontheories.Inthismodel,gashydrateswereregardedasnon-idealsolidsolutioncomposedofwatergroupsandguestmolecules,andtheexpressionsoffugacityofguestmoleculesinhydratephasewasproposedaccordingly.Ithasbeenshownthatthedevelopedmodelcanindicatesuccessfullytheeffectofguest-guestmoleculeinteraction.Theresultsshowedthatthemodelcandescribebetterthecharacteristicsofphaseequilibriumofmixedrefrigerantgashydratesandpredictionsareingoodagreementwithexperimentaldata.
简介:1.ObjectivesAsabout99%ofthenaturalgashydrate(NGH)resourcesarestoredontheseafloor,itisinevitablethatinitsprocessofexplorationandproduction,therewillbegeohazardssuchasmethaneleakage,seabedsubsidence,ecosystemdamageandevenlandslide.Therefore,asetofintegratedsystemsforenvironmentalmonitoringintheprocessofNGHproductionhasbeenproposedintheconsiderationofenvironmentaldisastersthatmayariseintheprocessofhydrateproduction.
简介:Theresultsonadissociationbehaviorofpropanehydratespreparedfrom'drywater'andcontainedunreactedresidualwaterintheformoficeinclusionsorsupercooledliquidwater(watersolutionofgas)werepresentedfortemperaturesbelow273K.Thetemperaturerampingorpressurereleasemethodwasusedforthedissociationofpropanehydratesamples.Itwasfoundthatthemechanismofgashydratedissociationattemperaturesbelow273Kdependedonthephasestateofunreactedwaterinthehydratesample.Gashydratesdissociatedintoiceandgasiftheiceinclusionswereinthehydratesample.Thesamplesofpropanehydrateswithinclusionsofunreactedsupercooledwateronly(withouticeinclusions)dissociatedintosupercooledwaterandgasbelowthepressureofthesupercooledwater-hydrate-gasmetastableequilibrium.