简介:ThepaperdescribestheeffectofadditivesAl,Si,SiCandB4ContheexpansionofMgO-ZrO2-Cmaterialafterbeingcoked.TheresultsindicatethatAlandSicannotincreaseitshotandcoldstrength.AlandSiwereoxidizedtoformAl2O3andSiO2respectively,andthenreactedwithCaZrO3orstabilizerinc-ZrO2toformcalciumaluminate,spinel(MA),dicalciumsilicate(C2S)andforsterite(M2S).Meanwhile,α-C2Swastransformedtoγ-C2Sandc-ZrO2tom-ZrO2whentemperaturechanged.AlltheabovereactionsresultedinthedecreaseoftheamountofAl4C3andSiCandtheincreaseinbulkvolume,whichcausedthestructureofMgO-ZrO2-Cmaterialdestroyed.Hence,contrarytotheMgO-Cmaterial,whenaddingAl.andSi,theMgO-ZrO2-Cmaterialwouldbestructurallydeterioratedafterheat-treatmentanditsstrengthandcorrosionresistancedecreased.
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简介:Inthis,phasecompsitionandthermalexpansionbehaviourofCaOStabilisedrefractorieswerestudied,Specialattentionwaspaidtotheexpasionbehaviourofthreematerialswithdifferentphasecomposition,TheresearchresultsindicatedthattheexpansionbehaviourcouldbeimprovedbymodifyingthestabilizationofZrO2,whichthusleadstotheincreaseinthethermalshockresistanceandpossiblyeroionresistaceofas-obtainedCaOstabilisedZrOmaterial.
简介:探讨用等离子体喷涂方法制备降低较高强度材料与U-Nb合金之间的摩擦性能的减磨层的可行性以及这些减磨层的摩擦特性。选用Sn为软涂层,ZrO2为硬涂层。采用SulzerMETCO9M等离子体喷涂机制备了Sn单层、ZrO2单层、Sn/ZrO2双层、Sn+ZrO2混合层等4种涂层。利用CSEM型销盘型摩擦磨损试验机分析了半径为3mm的U-Nb合金对偶销在涂层上滑动时的干摩擦特性,滑动速度分别为0.42,6.4,26.16cm/s。涂层为典型的等离子体喷涂涂层形貌。表面为Sn的涂层颗粒熔合状况和致密性比ZrO2单层好,其粗糙度低,Sn+ZrO2混合涂层表面形貌与ZrO2单层相近。Sn和ZrO2分别以bcc结构的Sn和四方结构ZrO2结构存在。
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简介:ThisworkstudiedthecharacteristicsofSiO2distributionandstructureofsilicatephasesinMgO-ZrO2compositessynthesizedbyrawmaterialsoflightfiredmagnesitendzircon,Theresultsindicatethat30wt%-40wt%SiO2contentinthesystemisexistedintheformofcrystallineofforsterite(M2S),theremainderingofSiOcontent(60wt%0-70wt%)isexistedintheglassphase,Thechemicalcompositionofglassphaseiswellagreedwiththechemicalcompositionofmonticellite(CMS).
简介:O'-sialon-ZrO2compositebasedonthecheapcommercialavailablezirconandsiliconasrawmaterialscanbeachievedbyusingreac-tionnitridationmethod,Moreattentionwasgiventothenitridingprocessandtheeffectofadditivesonit.Theexperimentalresultsshowthattherearetwonitridationpaths:oneisthedirectnitridationofsiliconpowderandtheotheristhroughthereactionbetweenthemedi-umcompoundZrSi2andthenitrogen.Theeffectsofadditionofcalciaandtheincorpora-tionofBNonthenitridingreactionwerealsoinvestigated,theprimitiveexperimentalresultsdemonstratedthatbothofcalciaandBNcoulddeterioratethenitridingdegree.
简介:Anewmicromechanicsconstitutivemodelforpuredilatanttransformationplasticityofstructureceramicsisproposedinthispaper.Basedonthethermodynamics,micromechanicsandmicroscalet→mtrans-formationmechanismanalysisoftheTZPandPSZZrO2-containingceramics,ananalyticexpressionsoftheHelmholtzandcomplementaryfreeenergyoftheconstitutiveelementforthecaseofpuredilatanttransforma-tionisderivedforthefirsttimeinaself-consistentmanner.Bytheanalysisofenergydissipationinthefor-wardandreversetransformations,themieromechanicsconstitutivelawisderivedintheframeworkofHill-Rice’sinternalvariableconstitutivetheory.
简介:Inthepaper,theauthorsanalysetherela-tionshipbetweentheelectricalconductivityσofZrO2andthecontentofdopedstabilizingagentbythePositronAnnihilationTechnique,andexplainthechangetendencyofσwiththecontentofstabilizingagent.Theresearchshowsthat"numberofeffectivevacancy"inmaterialisadecisivefactorcausingchangeofσ.
简介:利用XRD、TPR和EXAFS等手段考察了焙烧温度对Cu/MnO2/ZrO2催化剂性能影响,结果表明,随着焙烧温度增加,铜的配位环境发生变化,铜和锰之间相互作用增强,有效地防止铜组分在还原及反应过程中聚集长大,从而使催化剂活性显著增加,当催化剂经过高温焙烧,催化剂活性由于ZrO2结晶和铜的聚集而降低。
简介:MicrostructureandgrainboundarycharacterofhotpressedbinaryAl2O3(mullite,ZrO2)-SiCompositesandquaternaryAl2O3-mullite-ZrO2-SiCcompositewerestudiedbyelectronmicroscopyandmicroanalysis,ResultssuggestthatthereexistgrainboundarysolidsolutionsduetoelementaldiffusionnearSiCandmatrixoxidesgrainboundaries.
简介:采用Nb2O3、Y2O3复合稳定剂,制得了高韧性、高强度的四方相ZrO2陶瓷材料,发现在Y2O3-ZrO2材料中加入0.5~1molNb2O3,可使材料在保持原有抗弯强度的同时,一定程度上改善了断裂韧性和相组成。