学科分类
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6 个结果
  • 简介:Thestrategyofsequentiallyspin-coatingaperovskitefilmfromtheperovskiteprecursorandanelectrontransportinglayerof[6,6]-phenyl-C71-butyricacidmethylester(PC71BM)isdevelopedtosimplifythefabricationprocedureofperovskitesolarcells.X-raydiffractionandscanningelectronmicroscopyindicatethatPC71BMfilmonperovskitelayercanretardtheevaporationofdimethylsulfoxide(DMSO)efficiently,thusprolongingthetransformationofintermediatephasetoperovskitecrystals,leadingtoahighqualityperovskitethinfilm.Thesolarcellswiththestructureofindiumtinoxides(ITO)/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)/CH3NH3PbI3/PC71BM/bathocuproine(BCP)/Agmadefromthissimplifiedmethodexhibitahigherefficiency(12.68%)thanthosefromtheconventionalone-stepmethod(9.49%).

  • 标签: Perovskite 太阳能电池 简化准备过程 结晶化
  • 简介:Threepolymericadsorbentswithhydrogenbondingacceptors,methylamine,N-methyl-acetamideandaminotri(hydroxymethyl)methanemodifiedresinsaresynthesizedfromchloromethylatedX-5resin.AdsorptionisothermsofphenolandtheophyllineontothethreemodifiedresinsandtheoriginalX-5resinfromaqueoussolutionaremeasured.TheresultsshowthatadsorptionofcompoundswithhydrogenbondingdonorontomethylamineandN-methylacetamidemodifiedresinsisenhancedascomparedwiththatontoX-5resin,andadsorptionmechanismbetweentheadsorbentsandtheadsorbatesismainlybasedonhydrogenbondingandhydrophobicinteraction.Whileadsorptionofcompoundswithhydrogenbondingdonorontoaminotri(hydroxymethyl)methanemodifiedresinisloweredascomparedwiththatontoX-5resin,andadsorptionmechanismbetweentheadsorbentandtheadsorbatesismainlybasedonhydrophobicinteraction.

  • 标签: 甲胺 N-甲基乙酰胺 氨基三(羟甲基)甲烷 X-5树脂 改性 吸附剂
  • 简介:Thetransitionsandmorphologyofaseriesofmain-chainliquidcrystallinepolymerwithX-shapedmesogenswerestudiedbymeansofDSC,SALSandpolarizingmicroscopytechniques.Aneven-oddeffectwasobservedforsampleswithdifferentsizeofthesubstituentsonthemesogenends.Theisotropizationprocesswassimilartothatofmain-chainpolymerswithrod-likemesogens.Nocrystallizationwasdetectedforspecimenscoolingdownfromtheirisotropicmeltstate.Howevertwoofthesamplesmaycrystallizeincoolingprocessdirectlyfromtheliquidcrystallinestate.

  • 标签: Liquid crystalline polymer X-shaped MESOGEN Transition
  • 简介:Thecopolymersofchloroethylmethacrylate(CMA),glycidylmethacry-late(GMA),andmethylmethacrylate(MMA)weresynthesizedinbenzenesolution.Theirbreadthsofthemolecularweightdistributionsare2.1and2.3,respectivelyThether-malstabilityofP(GMA-CMA)issuperiortothatofP(CMA-MMA).TheresolutionsofP(CMA-MMA)andP(GMA-CMA)photoresistswerefoundtobe0.1~0.16μmand0.17~0.2μm,respectively.

  • 标签: Copolymer X-RAY PHOTORESISTS SUBMICRON Resolution
  • 简介:BymeansoftheintensitytheoryofX-rayscatteringandthetwo-phaseconceptofhighpolymer,thebasicformulaofthecrystaUinityinblockcopolymershasbeenproposedafterthecorrectionsofatomic,temperature,absorption,Lorentzandpolarizationfactor.Applicationofthismethodtodifferenttypepoly(oxyethylene-styrene)blockcopolymersandthesametypeblockcopolymerswithdifferentEOcontentsindicatesthatthecrystallinityinpoly(oxyethylene-styrene)blockcopolymersincreaseswiththeincreaseoftheEOcontentanddecreasesintheorder:PEO-PS-PEO>PEO-PS>PS-PEO-PS.

  • 标签: CRYSTALLINITY formula X-ray DIFFRACTION Block COPOLYMERS