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简介：以六水合氯化钴（CoCl2·6H2O）和水合三氯化钌（RuCl3·3H2O）为前驱体，采用胶体法制备超级电容器用（RuO2／Co3O4）·nH2O复合薄膜电极材料。用X射线衍射仪以及CHl660C电化学工作站对该复合薄膜的物相结构及电化学性能进行表征。结果表明：当COCl2＇6H20和RuCl3·3H2O的物质的量比n（Co）：n（Ru）为2：1时，于350℃下热处理2．5h制备的复合薄膜电极具有优良的性能，在浓度为0．5mol／L的H2S04电解液中其比电容达到512F／g，500次充放电循环后比电容量保持在充放电循环前的96．1％；充放电电流为0．01A时，内阻为1．2Ω。

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简介：Thesynthesis,compositionoptimization,VUVPhotoluminescence(PL)spectra,andopticalproperties,of(Y,Gd)(V,P)O4∶Eu3+phosphorswereinvestigatedbysynchrotronradiation.TheVUVPLEspectraandthecorrelationamongVUVPLintensity,λem,andEu3+,Gd3+,andP-contentwereestablished.ThePLEspectralstudiesshowedthat(Y,Gd)(V,P)O4∶Eu3+exhibitedsignificantabsorptionintheVUVrange.TheVUVPLintensitywasfoundtoenhancewithPO43-andGd3+-doping.Furthermore,thechromaticitycharacteristicsof(Y,Gd)(V,P)O4∶Eu3+werealsofoundtobe(0.6614,0.3286)andcomparedagainst(Y,Gd)BO3∶Eu3+asareference.Basedonthecharacterizationresults,wearecurrentlyimprovingandevaluatingthepotentialapplicationof(Y,Gd)(V,P)O4∶Eu3+asanewred-emittingPDPphosphor.

简介：Whitelight-emittingYVO_4：1mol.%Dy~（3＋）,xmol.%Eu~（3＋）phosphorpowderswithordermorphologyandwellcrystallizationwerehydrothermallysynthesizedat180°C.Themicrostructure,white-lightemission,andlight-emittingmechanismofthepowderswerecarefullystudiedusingX-raydiffractometry,scanningelectronmicroscopyandphotoluminescencespectra.TheexcitationandemissionspectraofthephosphorpowdersindicatedthecoexistenceofefficientenergytransferfromEu~（3＋）toDy~（3＋）andinefficientenergytransferfromDy~（3＋）toEu~（3＋）besidestheenergytransferfromVO_4~（3–）toEu~（3＋）.IncreasingtheEu~（~（3＋））concentrationinitiallyenhancedandthenweakenedtheluminescentintensityofDy~（3＋）.Thewhite-lightemissionsofYVO_4：1mol.%Dy~（3＋）,xmol.%Eu~（3＋）phosphorpowderswerebothrelatedtotheenergytransferbetweenVO_4~（3–）andDy~（3＋）/Eu~（3＋）,aswellasbetweenEu~（3＋）andDy~（3＋）.TheinefficientenergytransferfromDy~（3＋）toEu~（3＋）wasfirstfound.

简介：采用浓HNO3/浓H2SO4混合酸在60℃超声环境下对T300碳纤维进行表面氧化处理，并以其为增强体制备碳纤维/环氧树脂复合材料。利用X射线光电子能谱仪、拉曼光谱仪、扫描电镜、原子力显微镜对表面氧化前后的碳纤维形态与表面化学性质进行表征，研究氧化时间对纤维的表面形貌与表面性质以及碳纤维/环氧树脂基复合材料力学性能的影响。结果表明，氧化初期，碳纤维表面生成S—、N—含氧基团，以及—OH和—C=O；后期形成—COOH，氧化时间为15min时，—COOH的浓度达到最大值。碳纤维/环氧树脂复合材料的强度随混合酸氧化时间延长而不断增强，氧化15min时强度达到峰值，相比于未氧化处理的样品，复合材料层剪切强度从16.3MPa提高到38.8MPa，抗弯强度从148.3MPa提高到379.7MPa。

简介：Reactionof(MeC5H4)3LnwithHOCH2CH2NMe2intetrahydrofuran(THF)givesthenewcomplexes[(MeC5H4)2Ln(μ-OCH2CH2NMe2)]2(Ln=Sm,Y,Nd)withnitrogenfunctionalizedμ-alkoxideligand.ThecomplexeswerecharacterizedbyelementalanalysisandIR,and[(MeC5H4)2Sm(μ-OCH2CH2NMe2)]2wasstructurallycharacterizedbytheX-raydiffractiontobeadimerformedbytwounsymmetricoxygenbridges.ThecomplexhasatricyclicskeletonwiththeadditionaltwoSm-NbondsviaintramolecularcoordinationofOCH2CH2NMe2.ThecoordinationnumberofthecentralmetalSmisnine.Thetitlecomplexesshowgoodcatalyticactivityforring-openingpolymerizationofε-caprolactone.