学科分类
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4 个结果
  • 简介:Anumberofnaphthalenedonorcompoundsthatpossessanadamantanaminebindingmoietyandan(OCH2CH2)n(nn1,2,3,4,6,8)spacerweresynthesized.Thefluorescencequenchingbetweenthesedonorsubstratesandmono-6-O-p-nitrobenzoyl-β-cyclodextrin(pNBCD)andmono-6-O-m-nitrobenzoyl-β-cyclodextrin(mNBCD)wasstudiedindetail.Itwasfoundthatveryefficientfluorescencequenchingcouldoccurinthesesupramolecularsystems.Thisquenchingwasattributedtothephotoinducedelectrontransferinsidethesupramolecularassemblybetweenthenaphthalenedonorsandcyclodextrinacceptors.DetailedStern-VolmerconstantsweremeasuredandtheywerepartitionedintodynamicStern-Volmerquenchingconstantsandstaticbindingconstants.Itwasdemonstratedthatthebindingconstantsbetweenallthenaphthalenecompoundsandcyclodextrinsarethesameastheypossessthesamebindingsite,i.e.,adamantanamine.

  • 标签: 光致电子转移 Host-Guest化合物 2-萘基-(乙烯氧基)n-金钢石 单-6-O-p-硝基苯甲酰基-β-环式糊精 单-6-O-m-硝基苯甲酰基-β-环式糊精
  • 简介:一荧光灯分核derivate,N-allyl-1-pyrenemethylammoniumhydrochloride(APA+),被报导与葫芦形成稳定的hostguest建筑群[8]uril(CB[8]),并且这个性质能被利用到确定CB的纯净[8]经由排放滴定。而且,APA+和CB的1:1建筑群[8]能进一步绑甲基viologen(MV2+),它是广泛地使用的除草剂的主要成分,提供一个好方法检测MV2+,特别在低集中。

  • 标签: 有效成分含量 甲基紫精 CB 荧光测定 检测 顾客
  • 简介:Afacilegreenlow-costcontrollablehydrothermal-thermalconversion(HTC)processfortheuniformhighaspectratioCaSiO3nanowireshasbeendevelopedusingabundantCaCl2·2H2OandNa2SiO3·9H2Oasrawmaterialswithoutanyorganicadditive.Thenanowiresexhibitedatransparentcharacteristicfromtheultraviolettovisibleregion,andtheCaSiO3:1.2%Tb3+nanophosphorswithwellpreserved1DmorphologydemonstratedstronggreenluminescencewithCIEcoordinatesof(x=0.3144,y=0.5912).Thepresentworkdefinitelyrevealsthenanowiresasapromisingstructureandfunctionintegratedhostcandidateforgreen-emittingluminescentmaterialsinlightdisplaysystemsandoptoelectronicdevices.

  • 标签: Calcium SILICATE NANOWIRES Green hydrothermal-thermal conversion